Results 61 to 70 of about 716 (160)

Inclusion of chirality in the copper(II) 12-metallacrown-4 framework and the construction of two-dimensional networks.

, 2001
Metallacrowns are metallamacrocyclic analogs of crown ethers that contain an (-M-N-O-) repeat unit {M = transition metal ion} in place of the (-C-C-O-) repeat typically found in organic crowns.
Bodwin, Jeffrey John
core   +5 more sources

Design of 2D Porous Coordination Polymers Based on Metallacrown Units [PDF]

, 2016
A 12‐metallacrown‐4 (MC) complex was designed and employed as the building block in the synthesis of coordination polymers, one of which is the first permanently porous MC architecture.
MARCHIO', Luciano, Chun Y. Chow, Pecoraro, Vincent L., Vincent L. Pecoraro, Tegoni, Matteo, Luciano Marchiò, Atzeri, Corrado, Kampf, Jeff W., Marchiò, Luciano, Matteo Tegoni, Corrado Atzeri, Jeff W. Kampf, Chow, Chun Y., Pecoraro, Vincent L   +13 more
core   +1 more source

Relaxometric study of copper [15]metallacrown-5 gadolinium complexes derived from alpha-aminohydroxamic acids

, 2005
Proton nuclear magnetic relaxation dispersion (NMRD) profiles were recorded between 0.24 mT and 1.4 T for lanthanum(III)- and gadolinium(III)-containing [15]metallacrown-5 complexes derived from alpha-aminohydroxamic acids and with copper(n) as the ring ...
Meyer, Gerd, Pacco, A., Muller, Robert N., Parac-Vogt, Tatjana, Elst, L.V., Laurent, S., Muller, R.N., Wickleder, M., Parac-Vogt, T.N., Wickleder, Mathias, Laurent, Sophie, Binnemans, Koen, Meyer, G., Nockemann, Peter; id_orcid, Binnemans, K., Pacco, Antoine, Nockemann, Peter, Vander Elst, Luce   +17 more
core   +1 more source

Metallacrowns: A new class of metal binding agents [PDF]

Journal of Inorganic Biochemistry, 1991
Peer Reviewed ; http://deepblue.lib.umich.edu/bitstream/2027.42/29189/1/0000242 ...
Pecoraro, Vincent L., Lah, Myoung Soo, Kessissoglou, Dimitris P., Kampf, Jeffrey W., Gibney, Brian   +4 more
openaire   +2 more sources

Inter-conversion of 15-MC-5 to 12-MC-4 manganese metallacrowns: structure and bioactivity of metallacrowns hosting carboxylato complexes

Journal of Inorganic Biochemistry, 2005
Interaction of manganese with salicylhydroxamic ligands (shi) in methanol, in the presence of pyridine, leads to the formation of a series of 15-membered metallacrown (MC) Mn(II)(L)2[15-MCMn(III)N(shi)-5](py)6 or 7, (L=formato, benzoate or alkanoato ligand, py=pyridine).
Dendrinou-Samara, Aikaterini, Papadopoulos, A. N., Malamatari, D., Tarushi, A., Raptopoulou, C., Terzis, A., Samaras, E., Kesisoglou, Dimitrios   +7 more
openaire   +3 more sources

Slow Relaxation of the Magnetization in Dysprosium–Aluminum Metallacrowns

ACS Omega
A series of DyIII-AlIII metallacrowns (MC) with the ligand salicylhydroxamic acid (H3shi) were investigated for magneto-structural interactions. The four MCs demonstrate that slight variations in reaction conditions and molecular components can lead to different classes of MCs.
Chicco S., Garlatti E., Cugini F., Rheam R. E., Travis J. R., Hess A. M., Zeller M., Solzi M., Carretta S., Zaleski C. M.   +9 more
openaire   +2 more sources

Visible and near-infrared emitting heterotrimetallic lanthanide–aluminum–sodium 12-metallacrown-4 compounds: discrete monomers and dimers

, 2022
International audienceThe luminescence properties of two types of heterotrimetallic aluminum-lanthanide-sodium 12-metallacrown-4 compounds are presented here, LnNa(ben)4[12-MCAl(III)N(shi)-4] (LnAl4Na) and {LnNa[12-MCAl(III)N(shi)-4]}2(iph)4 (Ln2Al8Na2),
Eliseeva, Svetlana, Nagy, Sarah, Smihosky, Alyssa, Foley, Collin, Petoud, Stéphane, Kauffman, Abigail, Travis, Jordan, Zaleski, Curtis, Stéphane Petoud, Alyssa M. Smihosky, Curtis M. Zaleski, Sarah G. Nagy, Abigail C. Kauffman, Svetlana V. Eliseeva, Jordan R. Travis, Collin M. Foley   +15 more
core   +1 more source

Thermodynamics of binding of carboxylates to amphiphilic Eu(3+)/Cu(2+) metallacrown.

, 2009
The binding constants of acetate and benzoate to a Pheha-based 15-metallacrown-5 have been determined by a fluorimetric indicator displacement assay demonstrating on a thermodynamic basis the stabilization effect arising from complexation of the less ...
TEGONI, Matteo, MARCHIO', Luciano, TROPIANO M, Tegoni, M, Luciano Marchiò, Tropiano, Manuel, Matteo Tegoni, Marchiò, L, Manuel Tropiano   +8 more
core   +1 more source

Synthesis, NMR Characterization, and Cation Binding of Metallacrown Ethers with Asymmetric Bis(phosphinite) and Bis(phosphite) Ligands Derived from 2-Hydroxy-2‘-(1,4,7-trisoxo-9-nonanol)-1,1‘-biphenyl

, 2016
Chlorodiphenylphosphine and 2,2‘-biphenylylenephosphorochloridite react with 2-hydroxy-2‘-(1,4,7-trisoxo-9-nonanol)-1,1‘-biphenyl to yield the new α,ω-bis(phosphorus-donor)polyether ligands Ph2PO(CH2CH2O)3-2-C12H8-2‘-OPPh2 and (2,2‘-O2C12H8)P(CH2CH2O)3-2-
Jennifer M. Butler (2117254), Michael J. Jablonsky (356333), Gary M. Gray (85941)   +2 more
core   +2 more sources

Polyoxometalatocrown ether: A new type of metallacrown ether based on polyoxometalate

Polyoxometalates
Using chain-like polyethers consisting of two terminal –NH2 groups and (TBA)4[α-Mo8O26] as starting materials, two polyoxometalatocrown ethers were prepared by a cyclization reaction through the formation of Mo≡N triple bonds: (TBA)2[Mo6O17N(o-C6H4OCH2 ...
Fengping Xiao, Xianggao Meng, Longsheng Wang, Jian Hao, Chunlin Lv, Yongge Wei   +5 more
doaj   +1 more source