Results 31 to 40 of about 309 (131)

Synthesis of a Metalla[2]catenane, Metallarectangles and Polynuclear Assemblies from Di(N‐Heterocyclic Carbene) Ligands

Angewandte Chemie, Volume 136, Issue 39, September 23, 2024.
The fluorenone‐bridged di‐NHC precursor H2‐1(PF6)2 reacts with Ag2O in CH3CN to give the [2]catenane [Ag4(1)4](PF6)4, which disintegrates in DMF into two metallarectangles [Ag2(1)2](PF6)2. Substitution of the imidazo[1,5a]pyridinium NHC precursors in H2‐1(PF6)2 for imidazolium groups yields di‐NHC precursors H2‐L(PF6)2 which react with Ag2O to yield ...
Jin‐Ping Chang, Ya‐Wen Zhang, Li‐Ying Sun, Le Zhang, F. Ekkehardt Hahn, Ying‐Feng Han   +5 more
wiley   +2 more sources

Encapsulation of a guest molecule in a strained form: an extended 36-membered dodecanuclear manganese metallamacrocycle that accommodates a cyclooctane in the S-4 symmetry conformation [PDF]

, 2014
An extended 36-membered dodecanuclear manganese metallamacrocycle with S12 symmetry has been synthesized using the ligand N-cyclohexanoylsalicylhydrazide (H3chxshz) by a self-assembly that accommodates a cyclooctane of conformationally strained S4 ...
Moon, Dohyun, John, Rohith P., Lah, Myoung Soo, Park, Jaejoon, Lee, Kyungjin   +4 more
core   +1 more source

Steric Control of a Bridging Ligand for High-Nuclearity Metallamacrocycle Formation:  A Highly Puckered 60-Membered Icosanuclear Metalladiazamacrocycle [PDF]

, 2016
A novel S4-symmetric icosanuclear manganese metalladiazamacrocycle was synthesized using a pentadentate ligand, N-3-phenyl-trans-2-propenoylsalicylhydrazide (H3L), that has a rigid and bulky terminal N-acyl group.
Dohyun Moon (1406428), Myoung Soo Lah (1493182), Kyungjae Lee (2525959), Byoung Jin Suh (1742023), Rohith P. John (2415787), Ghyung Hwa Kim (2337112)   +5 more
core   +3 more sources

Pyridinethiolate Titanocene Metalloligands and Their Self-Assembly Reactions To Yield Early–Late Metallamacrocycles [PDF]

Organometallics, 2016
New titanocene pyridinethiolate compounds [(RCp)(2)Ti(4-Spy)(2)] (R = H (1), Me (2); Cp = cyclo-pentadienyl; 4-Spy = pyridine-4-thiolate) and [Cp2Ti(2-Spy)(2)] (3; 2-Spy = pyridine-2-thiolate) have been prepared by reaction of the corresponding Li(Spy) salt with the appropriate compound [(RCp)(2)TiCl2].
Ferrer García, Montserrat, Gomez-Bautista, Daniel, Gutiérrez i Currius, Albert, Orduña Marco, Guillermo, Oro, Luis A., Pérez Torrente, Jesús J., Rossell Alfonso, Oriol, Ruiz Sabín, Eliseo   +7 more
openaire   +3 more sources

A 2D Layered Metal-Organic Framework Constructed by Using a Hexanuclear Manganese Metallamacrocycle as a Supramolecular Building Block [PDF]

, 2008
The hexanuclear manganese metallamacrocycle [Mn(6)-(Haahz)(6)(dmso)(6)] (1) was prepared by using a new pentadentate ligand, N-acetylaminobenzhydrazide (H(4)aahz), and a manganese ion as primary building blocks in dimethyl sulfoxide (dmso).
Moon, Dohyun, Choi, Jeungwook, Lah, Myoung Soo, Dohyun Moon, Park, Mira, Jeungwook Choi, Mira Park, Myoung Soo Lah, Park, Jaejoon, Jaejoon Park, ���������   +10 more
core   +1 more source

Structural and Magnetic Properties of a {GdCu5}2 Metallacrown Dimer with a Disulfonate Linker

European Journal of Inorganic Chemistry, Volume 27, Issue 5, February 12, 2024.
Linkage of two {GdCu5}3+ 15‐metallacrowns‐5 with rigid disulfonate resulted in a discrete dimer with adjacent metallamacrocycles arranged in “edge‐to‐edge” manner. χMT vs. T data reveal presence of both antiferromagnetic and ferromagnetic exchanges and can be fitted with two‐J model for Gd–Cu and Cu–Cu exchange interactions in {GdCu5}3+ unit.
Anna V. Pavlishchuk, Matthias Zeller, Luca M. Carrella, Eva Rentschler, Jasleen K. Bindra, Naresh Dalal, Jared Kinyon, Kuluni Perera, Vitaly V. Pavlishchuk, Anthony W. Addison   +9 more
wiley   +1 more source

Steric control of a bridging ligand for high-nuclearity metallamacrocycle formation: A highly puckered 60-membered icosanuclear metalladiazamacrocycle [PDF]

, 2014
A novel S4-symmetric icosanuclear manganese metalladiazamacrocycle was synthesized using a pentadentate ligand, N-3-phenyl-trans-2-propenoylsalicylhydrazide (H3L), that has a rigid and bulky terminal N-acyl group.
Kim, Ghyung Hwa, Suh, Byoung Jin, Moon, Dohyun, John, Rohith P., Lah, Myoung Soo, Lee, Kyungjae   +5 more
core   +1 more source

A dodecanuclear metallamacrocycle having a multidentate bridging ligand in two different binding modes [PDF]

, 2008
The reaction of Mn(OAc)2??4H2O with 2,6-dimethoxybenzoylsalicylhydrazide (H3dmbshz) leads to a dodecanuclear manganese metallamacrocycle [Mn12(dmbshz) 12(EtOH)6], 1.
Kim, Ghyung Hwa, Lah, Myoung Soo, Ri, Hyeong-Cheol, Liu, Xinfang, Park, Mira, Liu, Wenlong, Lee, Kyungjin, ���������   +7 more
core   +1 more source

Selective Complexation of Li⁺ in Water at Neutral pH Using a Self-Assembled Ionophore [PDF]

, 2016
A trinuclear metallamacrocycle was obtained by assembly of a tridentate ligand and a ruthenium complex in water at neutral pH.
Kay Severin (1403713), Rosario Scopelliti (1328478), Zacharias Grote (2531599), Marie-Line Lehaire (2640688)   +3 more
core   +3 more sources

Self-assembly of a highly stable, topologically interesting metallamacrocycle by bridging gold(I) ions with pyridyl-2,6-diphenyl 2- and diphosphanes [PDF]

, 2006
(Figure Presented) A Möbius arrangement of the bonds directly attached to a metallamacrocycle was observed for the AuI complex [Au 3(CNC)(μ-Ph2PCH2PPh2) 2]+, which was self-assembled by treating the lithium salt of pyridyl-2,6-diphenyl2- (CNC) with ...
Huang, JS, Zhu, N, Steven C. F. Kui, Che, CM, Nianyong Zhu, Chi‐Ming Che, Kui, SCF, Sun, RWY, Jie‐Sheng Huang, Raymond Wai‐Yin Sun   +9 more
core   +1 more source