Results 91 to 100 of about 12,941 (225)
Modeling and Optimization of propylene polymerization with branching [PDF]
, 2014 A kinetic model has been proposed to fit the experimental data (2003) available from the open literature for branched propylene polymerization system. The present system considered is a binary catalyst system, in which the first catalyst produces the ...
Majumdar, S +2 more
core +2 more sources
, 2003 The past 15 years have witnessed tremendous advances in the design and use of organometallic complexes as precatalysts for olefin polymerization. Most recently, an intense search has been started in next-generation single-site catalysts. New approaches have been taken to ligand design.
openaire +1 more source
International Journal of Energy Research, Volume 2026, Issue 1, 2026.This study presents a sustainable approach for mitigating greenhouse gas emissions by converting methane (CH4) and carbon dioxide (CO2) into syngas using nickel‐based catalysts supported on hexagonal boron nitride (hBN), synthesized through chemical vapor deposition (CVD).
Benyamin M. Garmejani +3 more
wiley +1 more source
A Redox‐Tunable Carborane Crown: Toward Highly Selective Electrochemical Lithium Capture
Chemistry – A European Journal, Volume 31, Issue 72, December 23, 2025.Electrochemical reduction transforms a new carborane–crown into a potent 2e− reduced nido anion with a redox‐tunable cavity that captures Li⁺ selectively over Na⁺ and K⁺. The coupling of electronic control and size‐matched binding offers a blueprint for selective, rapid lithium recovery for next‐generation direct lithium extraction. Abstract Lithium is
Shannon Heinrich +6 more
wiley +1 more source
Kinetic resolution of racemic {alpha}-olefins with ansa-zirconocene polymerization catalysts: Enantiomorphic site vs. chain end control [PDF]
, 2006 Copolymerization of racemic {alpha}-olefins with ethylene and propylene was carried out in the presence of enantiopure C1-symmetric ansa metallocene, {1,2-(SiMe2)2({eta}5-C5H-3,5-(CHMe2)2)({eta}5-C5H3)}ZrCl2 to probe the effect of the polymer chain end ...
Bercaw, John E., Byers, Jeffery A.
core +1 more source
Synthesis, characterization of a new carbonylated zirconium metallocene using a dichloro-zirconocene derived from partially alkylated s-indacene [PDF]
, 2009 Indexación: ScieloThis work describes the synthesis and characterization of new organometallic species, an unprecedented mononuclear zirconium complex bearing a tetraalkylated s-indacene ligand, and secondly, its respective dicarbonyl complex obtained by
Adams, C. +7 more
core +1 more source
Correlation Between Vinyl Content of Recycled HDPE and Polymer Degradation: An NMR Approach
Journal of Applied Polymer Science, Volume 142, Issue 47, December 15, 2025.The degradation behavior of high‐density polyethylene (HDPE) during recycling depends on its vinyl group content. This study shows that 1H NMR spectroscopy enables accurate assessment of vinyl groups unlike FTIR. Changes in melt flow and molecular weight with multiple processing are linked to vinyl content which could enable tailor‐made re‐additivation
Kim Hao Ng +3 more
wiley +1 more source
Polímeros, 2001 O monômero eteno foi polimerizado através dos sistemas catalíticos Cp2ZrCl2/SiO2 e Cp2ZrCl2/MAO/SiO2. Foi elaborado um planejamento estatístico de experimentos a fim de se identificar as melhores condições de preparo dos catalisadores heterogêneos.
Anunciata Conte +1 more
doaj +1 more source
THE LICENSING DILEMMA: UNDERSTANDING THE DETERMINANTS OF THE RATE OF LICENSING [PDF]
Licensing entails a tradeoff: licensing payments net of transaction costs (revenue effect) have to be balanced against the lower price-cost margin and/or reduced market share that the increased competition (profit dissipation effect) from the licensee ...
Andrea Fosfuri
core
Synthesis, reactivity, and catalytic activity of triangular ZrM2 (M = Rh, Ir) early-late heterobimetallic complexes [PDF]
, 2016 Reactions of the zirconium−sulfide metallocene anion [Cptt2ZrS2]2- (Cptt = η5-1,3-di-tert-butylcyclopentadienyl) with [{M(μ-Cl)(diolefin)}2 gave the d0−d8 complexes [Cptt2Zr(μ3-S)2{M(diolefin)}2] (M = Rh, diolefin = 2,5-norbornadiene (nbd) (1), 1,5 ...
Ciriano, Miguel A. +6 more
core +1 more source