Results 21 to 30 of about 1,728 (185)

Synthesis and Application of Bis[1,2-(4-aryl-2-alkyl-1H- inden-1-yl)]Ethane as an Efficient`Ligand for Preparation of Olefin Polymerization Catalysts [PDF]

open access: yesJournal of Sciences, Islamic Republic of Iran, 2019
In this study, a class of bis-1,2-(4-aryl-2-alkyl-1H- inden-1-yl) ethane was synthesized and characterized by spectroscopic methods such as 1HNMR, 13CNMR, melting point and FTIR.
v. Lotfi   +3 more
doaj   +1 more source

Comparative Analysis of Ethylene/Diene Copolymerization and Ethylene/Propylene/Diene Terpolymerization Using Ansa-Zirconocene Catalyst with Alkylaluminum/Borate Activator: The Effect of Conjugated and Nonconjugated Dienes on Catalytic Behavior and Polymer Microstructure

open access: yesMolecules, 2021
The copolymerization of ethylene‒diene conjugates (butadiene (BD), isoprene (IP) and nonconjugates (5-ethylidene-2-norbornene (ENB), vinyl norbornene VNB, 4-vinylcyclohexene (VCH) and 1, 4-hexadiene (HD)), and terpolymerization of ethylene-propylene ...
Amjad Ali   +9 more
doaj   +1 more source

Temperature-Dependent Growth of 36 Inner Nanotubes inside Nickelocene, Cobaltocene and Ferrocene-Filled Single-Walled Carbon Nanotubes

open access: yesNanomaterials, 2021
We have investigated the effects of temperature, diameter and metal catalyst type on the growth of inner nanotubes inside metallocene-filled single-walled carbon nanotubes (SWCNTs).
Marianna V. Kharlamova   +1 more
doaj   +1 more source

Synthesis and characterization of a tert-butyl ester-substituted titanocene dichloride: t-BuOOCCp2TiCl2

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2020
Bis[η5-(tert-butoxycarbonyl)cyclopentadienyl]dichloridotitanium(IV), [Ti(C10H13O2)2Cl2], was synthesized from LiCpCOOt-Bu using TiCl4, and was characterized by single-crystal X-ray diffraction and 1H NMR spectroscopy.
Jackson S. McCarthy   +3 more
doaj   +1 more source

IN SITU SILICA SUPPORTED METALLOCENE CATALYSTS FOR ETHYLENE POLYMERIZATION [PDF]

open access: yesJournal of Petroleum Science and Technology, 2014
Bis(2-R-ind)ZrCl2 (R: H or phenyl) was supported on different types of silica by in situ impregnation method and used for ethylene polymerization.
saeid ahmadjo   +6 more
doaj   +1 more source

Heterobimetallic Janus Catalysts for the One‐Pot Synthesis of Polar‐Apolar Block Copolymers

open access: yesAngewandte Chemie, EarlyView.
Heterobimetallic Janus catalysts act as bifunctional initiators, combining two distinct polymerisation mechanisms in one pot to deliver well‐defined apolar‐polar block copolymers. Combining Earth abundant Ti and Al catalysts for respective α‐olefin and lactone polymerisation, the orthogonal activity is enabled by unprecedented initiation from a Ti ...
Raju Chambenahalli   +2 more
wiley   +2 more sources

Titanium‐Catalyzed Defluorination of Poly(Vinyl Fluoride) and Poly(Vinylidene Fluoride) Under Friedel–Crafts Conditions

open access: yesAngewandte Chemie, EarlyView.
Cationic titanium sandwich catalysts display exceptional activity in the hydrodefluorination of Csp3─F bonds, in the presence of silanes and aromatic solvents (turnover numbers up to 3000). As a result, they can be used to defluorinate challenging fluoropolymers, such as poly(vinyl fluoride) (PVF) or poly(vinylidene fluoride) (PVDF).
Louis Le Moigne   +9 more
wiley   +2 more sources

Advantages of Group 4 Metallocene Bis(trimethylsilyl)acetylene Complexes as Metallocene Sources Towards Other Synthetically used Systems

open access: yesChemistryOpen, 2019
Active species for synthetic and catalytic applications are formed from well defined complexes or mixtures of compounds. For group 4 metallocenes, three pathways for the formation of the reactive complex fragment [Cp′2M] are known: (i) reductive mixtures
Prof. Dr. Uwe Rosenthal
doaj   +1 more source

Photooxidation of Some Metallocenes in a Polymer Matrix

open access: yesMolecules, 2005
The changes in the electronic absorption spectra (UV-Vis) of some metallocene-doped poly(methyl methacrylate) (PMMA) thin films containing chloroform molecules as impurities were studied after photoexcitation in the nitrogen atmosphere.
B. Mallik
doaj   +1 more source

Synthesis of (Ind)2ZrCl2 Catalyst for Copolymerization of Ethylene and Propylene: Parameters Effect on Productivity [PDF]

open access: yesعلوم و تکنولوژی پلیمر, 2010
Bis(indenyl)zirconium dichloride as a catalyst was synthesized using a modified method at the room temperature. Polymerization of ethylene and copolymerization of ethylene and propylene were carried out by this metallocene catalyst. Ethylene propylene (P/
S. Ahmadjo   +4 more
doaj   +1 more source

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