Results 41 to 50 of about 1,728 (185)

Synthesis, Characterization, and Cytotoxicity Studies of N-(4-Methoxybenzyl) Thiosemicarbazone Derivatives and Their Ruthenium(II)-p-cymene Complexes

Molecules, 2022
The reaction of [Ru2Cl2(μ-Cl)2(η6-p-cymene)2] with two thiosemicarbazones obtained by the condensation of N-(4-methoxybenzyl) thiosemicarbazide and 1,4-hydroxy-3-methoxyphenyl)ethan-1-one (HL1) or 2-fluoro-4-hydroxybenzaldehyde (HL2) was studied.
Mónica Martínez-Estévez, Soledad García-Fontán, Saray Argibay-Otero, Inmaculada Prieto, Ezequiel M. Vázquez-López   +4 more
doaj   +1 more source

Dinuclear Group 4 Metallocene Catalysts of the Type [(Cp2M)2(μ‐Me)(μ‐C2R)]: Structure‐Activity Relationships in Ethylene Polymerization

Chemistry – A European Journal, EarlyView.
Homo‐ and heterodinuclear group 4 metallocene complexes of the type [(Cp2M)2(μ‐Me)(μ‐C2R)] (M = Ti, Zr) are active catalysts for the polymerization of ethylene in the presence of aluminium‐free activators. The catalytically active species are proposed to have dinuclear character and depending on the type of activator, unique reactivity was observed ...
Hanan Al Hamwi, Mirko Rippke, Anke Spannenberg, Michal Horáček, Jiří Pinkas, Vojtěch Varga, Martin Lamač, Fabian Reiß, Torsten Beweries   +8 more
wiley   +1 more source

(μ-Di-tert-butylsilanediolato)bis[bis(η5-cyclopentadienyl)methylzirconium]

Acta Crystallographica Section E: Crystallographic Communications, 2019
The reaction of t-Bu2Si(OH)2 with two equivalents of Cp2Zr(CH3)2 produces the title t-Bu2SiO2-siloxide bridged dimer, [Zr2(CH3)2(C5H5)4(C8H18O2Si)] or [Cp2Zr(CH3)]2[μ-t-Bu2SiO2] (1), where one methyl group is retained per zirconium atom. The same product
David J. Berg, Leah Gajecki, Hunter Hill, Brendan Twamley   +3 more
doaj   +1 more source

Coated and Immobilized Polysaccharides‐Based Stationary Phases for Planar Metallocenes Enantioseparation in Liquid Chromatography

ELECTROPHORESIS, EarlyView.
This study examined 21 new ferrocene and ruthenocene derivatives, including those with planar and central chirality. Their stereochemical behavior was examined using UV‐detected normal‐phase liquid chromatography. Under fixed conditions, eight polysaccharide‐based chiral stationary phases were tested using n‐heptane combined with either 2‐propanol or ...
Florine Wartelle, Rose Leblond, Lisa Bonin, Alina Ghinet, Emmanuelle Lipka   +4 more
wiley   +1 more source

Enantioselective Synthesis of a New Class of Stable and Functionalized Cyclopentadienes via CuH‐Catalysis

Angewandte Chemie, Volume 138, Issue 32, 3 August 2026.
Cyclopentadienes (CpHs) are fundamental building blocks with widespread applications in chemistry. However, their inherent acidity and isomeric instability have long limited access to chiral variants in an asymmetric fashion. Here, we introduce a CuH‐catalyzed asymmetric transformation that provides an unprecedented entry into a new class of ...
Piero Soppelsa, Riccardo Bellin, Besma Boulila, Francesco Vaghi, Manuel Orlandi   +4 more
wiley   +2 more sources

Research progress on flexible MXene‐based materials in advanced energy storage devices: From preparation strategies to device applications

FlexMat, EarlyView.
This review summarizes MXene synthesis and flexible electrode fabrication for FESDs, highlighting their potential owing to high conductivity and flexibility, and outlines future research directions. Abstract The rapid development of wearable and portable electronics has created demand for flexible energy storage systems (FESDs) that not only exhibit ...
Nanxi Miao, Ying Lu, Xing Gao, Lingzi Pan, Meng Gao, Chenxi Zhang, Ming Liu, Shizhong Wang, Zhongyu Weng, Huan Pang, Huijie Zhou   +10 more
wiley   +1 more source

Potential of Thermoset Polyolefins for FRP Concrete Reinforcing Bars

Polymer Composites, EarlyView.
Overview of XLPO and pDCPD resins for FRP reinforcing bars, highlighting resin chemistry, key performance characteristics, fiber sizing interactions, and principal degradation mechanisms in concrete environments. ABSTRACT Although thermoset polyolefins offer resistance to hydrolytic degradation and favorable processing characteristics, their potential ...
Osama Omar, Farzaneh Mahmoudi, Leonidas G. Bachas, Francisco De Caso, Brahim Benmokrane, Antonio Nanni   +5 more
wiley   +1 more source

Rheological Characterization of a Low‐Concentration Water‐Based Collagen Dispersion Under Extensional, Shear, and Oscillatory Deformation

Polymer Engineering &Science, EarlyView.
Combined capillary and oscillatory rheology provided complementary insights into the linear, nonlinear, and extensional flow behavior of a 3 wt% collagen dispersion, improving the understanding of its processing‐relevant rheological characteristics. ABSTRACT This study presents an investigation of the extensional, shear, and oscillatory rheological ...
Fadi Alzarzouri, Xiaohe Xu, Manfred Wilhelm, Jan Skočilas   +3 more
wiley   +1 more source

Pressure‐Decay Kinetic Modeling of Homogeneous Ethylene Polymerization with Et(Ind)2ZrCl2/TIBA‐Borate Catalyst System in a Batch Reactor

Polymer Engineering &Science, EarlyView.
A kinetic model comprising both propagation and deactivation functions was developed for metallocene‐catalyzed ethylene polymerization in a batch reactor. The model predicted polymer yields very close to the experimental ones. The polymer molecular weight increased with ethylene pressure and decreased with temperature.
Narendra Singh Choudhary, Sanjib K. Patra, Narayan C. Pradhan   +2 more
wiley   +1 more source

An Integrated AHP-PROMETHEE Method for Selecting the most Suitable Ethylene Propylene Diene Termonomer [PDF]

Journal of Petroleum Science and Technology, 2016
This paper considers the problem of selecting the most appropriate ethylene propylene diene monomer (EPDM), which is a polyolefin with a variety of usages in different areas.
Ali Sibevei, Zahra Naji Azimi, Saied Ahmadjo, Mohammad Mahdi Mortazavi   +3 more
doaj   +1 more source