Synthesis of (Ind)2ZrCl2 Catalyst for Copolymerization of Ethylene and Propylene: Parameters Effect on Productivity [PDF]
علوم و تکنولوژی پلیمر, 2010 Bis(indenyl)zirconium dichloride as a catalyst was synthesized using a modified method at the room temperature. Polymerization of ethylene and copolymerization of ethylene and propylene were carried out by this metallocene catalyst. Ethylene propylene (P/
S. Ahmadjo +4 more
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Zirconium and titanium complexes supported by tridentate LX2 ligands having two phenolates linked to furan, thiophene, and pyridine donors: precatalysts for propylene polymerization and oligomerization [PDF]
, 2008 Zirconium and titanium complexes with tridentate bis(phenolate)-donor (donor = pyridine, furan and thiophene) ligands have been prepared and investigated for applications in propylene polymerization.
Agapie, Theodor +4 more
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Direct protonation of the W–H bonds of Bis(pentamethylcyclopentadienyl)tungsten dihydride [PDF]
, 1989 Protonation of (C_5Me_5)_2 WH_2 to give [(C_5Me_5)_2WH_3]+ is proposed to occur by attack at both W–H bonds rather than by direct attack at the d^2 metal ...
Bercaw, John E., Parkin, Gerard
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Gas phase polymerization of ethylene with a silica-supported metallocene catalyst: influence of temperature on deactivation [PDF]
, 1997 Ethylene was polymerized at 5 bar in a stirred powder bed reactor with silica supported rac-Me2Si[Ind]2ZrCl2/methylaluminoxane (MAO) at temperatures between 40°C and 80°C using NaCl as support bed and triethylaluminium (TEA) as a scavenger for impurities.
Meier, G.B. +5 more
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Electronic structure and magnetic properties of metallocene multiple-decker sandwich nanowires
, 2011 We present a study of the electronic and magnetic properties of the multiple-decker sandwich nanowires ($CP-M$) composed of cyclopentadienyl (CP) rings and 3d transition metal atoms (M=Ti to Ni) using first-principles techniques.
C. Morari +6 more
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Hybrid materials based on polyethylene and MCM-41 microparticles functionalized with silanes: catalytic aspects of in situ polymerization, crystalline features and mechanical properties [PDF]
, 2016 New nanocomposites based on polyethylene have been prepared by in situ polymerization of ethylene in presence of mesoporous MCM-41. The polymerization reactions were performed using a zirconocene catalyst either under homogenous conditions or supported
A. Bento +70 more
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The charge percolation mechanism and simulation of Ziegler–Natta polymerizations Part III. Oxidation states of transition metals [PDF]
Journal of the Serbian Chemical Society, 2006 The oxidation state of the transition metal (Mt) active centre is the most disputable question in the polymerization of olefins by Ziegler–Natta (ZN) and metallocene complexes.
BRANKA PILIC +5 more
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Uranium(III) coordination chemistry and oxidation in a flexible small-cavity macrocycle [PDF]
, 2015 U(III) complexes of the conformationally flexible, small-cavity macrocycle trans-calix[2]benzene[2]pyrrolide (L)2–, [U(L)X] (X = O-2,6-tBu2C6H3, N(SiMe3)2), have been synthesized from [U(L)BH4] and structurally characterized. These complexes show binding
Arnold P. L. +22 more
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Materials Research, 2001 Polypropylene with special properties can be obtained by metallocenic catalysts. These catalytic systems represent the beginning of a new age in polyolefins technology. In this work, the influence of the addition of a syndiotactic polypropylene (s-PP) on
Maria de Fátima V. Marques +2 more
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Molecules, 2021 Homogeneous olefin polymerization catalysts are activated in situ with a co-catalyst ([PhN(Me)2-H]+[B(C6F5)4]− or [Ph3C]+[B(C6F5)4]−) in bulk polymerization media. These co-catalysts are insoluble in hydrocarbon solvents, requiring excess co-catalyst (>3
Hyun-Ju Lee +7 more
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