Results 61 to 70 of about 1,728 (185)

From Cages to Sheets: Computational Elucidation of Methylaluminoxane Structure and Reactivity

ChemPlusChem, Volume 91, Issue 8, August 2026.
Methylaluminoxane (MAO), the dominant cocatalyst in metallocene‐based olefin polymerization, has resisted structural characterization for decades. This review traces the computational journey from early cage and nanotube proposals to the identification of two‐dimensional aluminoxane sheets as the thermodynamically preferred motif, and how this ...
Mikko Linnolahti, Perttu Hanhisalo, Aleksi Vähäkangas   +2 more
wiley   +1 more source

Organic Photodetectors and Sensors for Low‐Light and Infrared Applications

Electron, Volume 4, Issue 3, August 2026.
This mini review highlights recent advances in organic photodetectors and sensors for low‐light and infrared applications, emphasizing molecular design, device architectures, and interface engineering that improve charge transport, detectivity, speed, and spectral selectivity.
Swarup Biswas, Hyeok Kim
wiley   +1 more source

metallocenes

, 2014
Citation: 'metallocenes' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.M03865 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
openaire   +1 more source

Metal‐Based Materials for Redox Modulation in Biomedicine

Rare Metals, Volume 45, Issue 8, August 2026.
ABSTRACT Metal materials have become increasingly important in modulating biological redox networks for therapeutic and diagnostic purposes, owing to their distinctive electronic properties and adaptable reactivity. This review synthesizes recent developments across various metal‐based materials, including elemental metals, metal oxides, coordination ...
Yan Fan, Jing Zhang, Ning Sun, Mengjie Chen, Li Sun, Jie Lin, Kang Chen, Haishan Zhang   +7 more
wiley   +1 more source

Deactivation Pathways in 2‐Ferrocenylmethyl‐5‐Aminoxazoles Synthesized via Ugi–Zhu Reaction: A Dewar–Chatt–Duncanson‐Type Interaction

ChemistrySelect, Volume 11, Issue 29, 3 August 2026.
The synthesis and full characterization are reported of 15 new ferrocenyl‐containing oxazoles via the Ugi–Zhu reaction, which is a special kind of MCR versatile to synthesize different types of heterocycles and polyheterocycles, and the DFT‐based study is performed using a high level of theory to rationalize the reactivity of synthesized compounds ...
Carlos E. Garduño‐Albino, Roberto E. Blanco‐Carapia, Ricardo Alfredo Luna‐Mora, Humberto Laguna‐Galindo, Eduardo González‐Zamora, Alejandro Islas‐Jácome   +5 more
wiley   +1 more source

Bis(cobaltocenium) tetrachloridocobaltate(II) dichloromethane 1.2-solvate

IUCrData, 2018
The structure of bis(cobaltocenium) tetrachloridocobaltate(II) dichloromethane 1.2-solvate, [Co(C5H5)2]2[CoCl4]·1.2CH2Cl2, has been determined at 100 K. The title compound crystallizes in the space group P\overline{1} and is an example of an unusual Z′ =
Michael J. Shaw, Nan Xu, Ian E. Caveny, Erwin G. Abucayon, Anthony R. Ramuglia, George B. Richter-Addo   +5 more
doaj   +1 more source

Near‐Armchair‐Enriched Growth of Single‐Walled Carbon Nanotubes via W‐Containing Fe‐Based Catalyst Systems in Mist FC‐CVD

Small, Volume 22, Issue 46, 18 August 2026.
A mist‐based floating catalyst chemical vapor deposition (mist FC‐CVD) strategy allows the use of non‐volatile precursors and multi‐component catalyst delivery in a continuous process. Through catalyst composition control, it generates near‐armchair‐enriched single‐walled carbon nanotubes (SWCNTs) and uncovers key factors governing chiral‐angle ...
Hirotaka Inoue, Takamasa Onoki, Akira Takakura, Anastasios Karakassides, Hua Jiang, Toshihiko Fujimori, Esko I. Kauppinen   +6 more
wiley   +1 more source

Acyclic Hydrocarbon α,ω‐Dienes: From Biomass and Plastic Upcycling to Carbocycles, Precision Polymers, and Cross‐Linked Elastomers

ChemSusChem, Volume 19, Issue 14, 29 July 2026.
Hydrocarbon α,ω‐dienes are mainly produced from steam‐cracking derivatives, but high costs, complexity, and environmental impact limit their use. This review highlights sustainable paths from biomass and plastic upcycling, and surveys catalytic transformations into carbocycles and specialty polymers, emphasizing their role as modular building blocks ...
Rosa Villaccio, Giuseppe Leone
wiley   +1 more source

Computational Investigation of Ionization Energies and Absorption Spectra of Metallocenes: Effect of the Metal Center on Electronic Properties

Inorganics
Since the synthesis of ferrocene in 1951, metallocenes have attracted attention, making the accurate prediction of their electronic structure and ionization energy crucial for understanding their photophysical and electrochemical behavior in materials ...
Christina Eleftheria Tzeliou, Konstantinos P. Zois, Demeter Tzeli   +2 more
doaj   +1 more source

Metallocene Hydrides: Their Didactic Value for Teaching Organometallic Chemistry

CHIMIA
Metallocene hydrides, Cp2MHn (n=1-3), are complexes known for elements of Groups 3 to 8. Their properties can be understood by the use of a common qualitative MO diagram.
Antonio Togni
doaj   +1 more source