Results 51 to 60 of about 1,728 (185)

A novel n‐type dimer dopant for semiconducting polymers

open access: yesPolymer International, EarlyView.
A novel molecular n‐type dopant (1) with superior capacity to dope conjugated polymers is introduced. After charge transfer the product (2) remains in the polymer. Abstract Efficient and stable doping of organic semiconductors is crucial for adjusting their electrical properties.
Andreas Opitz   +4 more
wiley   +1 more source

Adsorption of Metallocenes on Silica

open access: yesChemistry – A European Journal, 2016
AbstractThe adsorption of the metallocenes ferrocene, doubly deuterated ferrocene, cymantrene and nickelocene, as well as molybdenum hexacarbonyl, proceeds in the absence of a solvent. Large single pieces of silica gel were placed in contact with the solid metallocenes and the adsorption process was visualized on a macroscopic scale and the maximal ...
Kyle J, Cluff, Janet, Blümel
openaire   +3 more sources

The influence of long chain branches of LLDPE on processability and physical properties

open access: yesPolímeros, 2015
Two polyethylene-based on single-site metallocene catalyst (mLLDPE) were selected to characterize the effect of long chain branching (LCB) on blown film processability, optical and mechanical properties.
Paula Cristina Dartora   +2 more
doaj   +1 more source

Photoelectron spectra of metallocenes

open access: yesJournal of Electron Spectroscopy and Related Phenomena, 1980
Abstract The He(II) spectra of the unsubstituted metallocenes {M(η-C5H5)2}, M  V, Cr, Mn, Fe, Co, Ni and Ru, and of {Mn(η-C5H4Me)2} are reported; both He(I) and He(II) spectra of some decamethylmetallocenes {M(η-C5Me5)2}, where M  Mg, V, Cr, Mn, Fe, Co and Ni, are also given.
Cauletti, C   +6 more
openaire   +2 more sources

Crystal structures of 1′-aminocobaltocenium-1-carboxylic acid chloride monohydrate and of its azo dye 1′-[2-(1-amino-2,6-dimethylphenyl)diazen-1-yl]cobaltocenium-1-carboxylic acid hexafluoridophosphate monohydrate

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2019
1′-Aminocobaltocenium-1-carboxylic acid chloride, [Co(C5H6N)(C6H5O2)]Cl·H2O, (3), and its azo derivative 1′-[2-(1-amino-2,6-dimethylphenyl)diazen-1-yl]cobaltocenium-1-carboxylic acid hexafluoridophosphate, [Co(C13H14N3)(C6H5O2)]PF6·H2O (5) were obtained ...
Markus Jochriem   +3 more
doaj   +1 more source

Effect of Immobilization Methods on the Production of Polyethylene-cellulose Biocomposites via Ethylene Polymerization with Metallocene/MAO Catalyst

open access: yesBulletin of Chemical Reaction Engineering & Catalysis, 2020
Polyethylene-cellulose biocomposites were synthesized here via the ethylene polymerization with metallocene as a catalyst along with methylaluminoxane (MAO) as a cocatalyst.
Praonapa Tumawong   +2 more
doaj   +1 more source

Das fehlende Glied der Ferrocenophan‐Chemie: Isolierung eines Carba[1]Ferrocenophans

open access: yesAngewandte Chemie, Volume 138, Issue 34, 17 August 2026.
Die Synthese und Isolierung eines kristallinen Carba[1]Ferrocenophans wird berichtet. Ein einzelnes Kohlenstoffatom ist das bislang kleinste Verbrückungsmotiv, das in ein Ferrocenophan eingebaut werden konnte. Dies resultiert in einem Diederwinkel der Ebenen der Cyclopentadienylringe von 36.7°, was entsprechend die größte Abwinkelung relativ zu ...
Aylin Feuerstein   +5 more
wiley   +1 more source

Alargamento da distribuição de massa molar de polímeros sintetizados com catalisadores metalocênicos dual-site Broadening of molecular weight distribution of polymers synthesized by metallocene-based dual-site catalysts

open access: yesQuímica Nova, 2008
The main topics related to the use of dual-site catalysts in the production of polymers with broad molecular weight distribution are reviewed. The polymerization using dual-site catalysts is more economical and allows to produce a higher quality product ...
João H. Z. dos Santos   +3 more
doaj   +1 more source

The Missing Link in Ferrocenophane Chemistry: Isolation of a Carba[1]Ferrocenophane

open access: yesAngewandte Chemie International Edition, Volume 65, Issue 34, 17 August 2026.
The synthesis and isolation of a crystalline carba[1]ferrocenophane is reported. A single carbon atom is the smallest bridging motif yet incorporated into a ferrocenophane, resulting in a dihedral angle between the cyclopentadienyl ring planes of 36.7°, which is the highest angular deflection from ferrocene's coplanarity observed so far.
Aylin Feuerstein   +5 more
wiley   +1 more source

Synthesis and Antiparasitic Activities of New Organometallic Derivatives of the Benzimidazole Anthelmintic Drugs

open access: yesChemBioChem, Volume 27, Issue 15, 14 August 2026.
Organometallic derivatization of existing drugs is a common strategy to look for new drug candidates. This work describes the derivatization of the benzimidazole anthelmintic scaffold, from the synthesis of the organometallic derivatives to the evaluation of their biological properties. It highlights a broad range of antiparasitic activities and leaves
Corentin Ludwig   +14 more
wiley   +1 more source

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