Results 91 to 100 of about 5,159 (225)

Designing organometallic compounds for catalysis and therapy [PDF]

open access: yes, 2012
Bioorganometallic chemistry is a rapidly developing area of research. In recent years organometallic compounds have provided a rich platform for the design of effective catalysts, e.g. for olefin metathesis and transfer hydrogenation.
Abraha Habtemariam   +188 more
core   +1 more source

Epoxidised Natural Rubber (ENR)/Wollastonite Composites for Tyre Inner Liners: A Practical Replacement for Butyl Rubber in Industrial Applications

open access: yesPolymer Engineering &Science, Volume 66, Issue 2, Page 1153-1169, February 2026.
Replacing butyl rubber with ENR+Wollastonite in tyre inner‐liners. ABSTRACT This study aimed to develop epoxidised natural rubber (ENR)‐based rubber compound formulations as an alternative to butyl rubber for tyre inner liners. The effects of different vulcanization systems, designed to achieve similar curing behavior in NR‐based carcass compounds and ...
Tuba Ünügül Yavuz   +4 more
wiley   +1 more source

Six-coordinated half-metallocene catalyst for ethylene polymerization and its mechanism study

open access: yesGiant
The demand for catalysts capable of enabling olefin polymerization at elevated temperatures to meet industrial requirements continues to grow. Among emerging candidates, novel six-coordinated half-metallocene catalysts, which combine the advantages of ...
Qian Li   +10 more
doaj   +1 more source

In situ synthesis of nanoclay filled polyethylene using polymer supported metallocene catalyst system

open access: yesQuímica Nova, 2011
In situ ethylene polymerizations were performed using bis(cyclopentadiene)titanium dichloride supported on polyethersulfone as catalyst. The bis(cyclopentadiene)titanium dichloride supported on polyethersulfone catalyst activity estimated by ethylene ...
Z. V. P Murthy   +2 more
doaj   +1 more source

Fragmentable Heterogeneous Cocatalysts for the Metallocene-Catalyzed Polymerization of Olefins, II [1]. Preparation, Characterization and Testing of the Cocatalysts and Microscopic Evaluation of the Polyethylene [PDF]

open access: yes, 2005
Surface modified silica were reacted with different aluminiumalkyls AlR2R’ (R = Me, Et, i-Bu, R’ = H, Me, Et, i-Bu), oligomeric methylaluminoxane (MAO) and combinations of both, to yield heterogeneous cocatalysts.
Lange, Katharina C. H.   +3 more
core   +1 more source

Advancing Single‐Walled Carbon Nanotubes toward Next‐Generation Electronic Materials: The Critical Roles of Purity and Processability

open access: yesSmall Methods, Volume 10, Issue 4, 23 February 2026.
Single‐walled carbon nanotubes (SWNTs) are promising for a wide range of applications. In particular, their exceptional electrical conductivity positions them as potential alternatives to traditional metal conductors. This review identifies the key mechanisms governing their conductivity within composites and proposes practical pathways for translating
Xiao Yu, Alex Adronov
wiley   +1 more source

Synthesis, reactivity, and catalytic activity of triangular ZrM2 (M = Rh, Ir) early-late heterobimetallic complexes [PDF]

open access: yes, 2016
Reactions of the zirconium−sulfide metallocene anion [Cptt2ZrS2]2- (Cptt = η5-1,3-di-tert-butylcyclopentadienyl) with [{M(μ-Cl)(diolefin)}2 gave the d0−d8 complexes [Cptt2Zr(μ3-S)2{M(diolefin)}2] (M = Rh, diolefin = 2,5-norbornadiene (nbd) (1), 1,5 ...
Ciriano, Miguel A.   +6 more
core   +1 more source

Polyethylene Melt Rupture and Slip in Simple Shear: A Visual and Mechanistic Study

open access: yesJournal of Applied Polymer Science, Volume 143, Issue 3, January 15, 2026.
Slip velocity transient curve (left) with images of the specimen at different times during a simple shear experiment. On the right, schematics illustrate the sample and its side view before and after simple shear. ABSTRACT Melt rupture of a bimodal molecular weight distribution polyethylene is studied under simple shear via flow visualization ...
Mohammadali Sattari   +2 more
wiley   +1 more source

MULTI-OBJECTIVE OPTIMIZATION OF SYNDIOTACTIC POLYMERIZATION OF STYRENE USING GENETIC ALGORITHM TECHNIQUE

open access: yesDiyala Journal of Engineering Sciences, 2015
The optimal control policies for the syndiotactic polymerization of styrene over silica supported metallocene catalyst, have been determined using a multiobjective optimization technique.
S. R. Sultan
doaj  

Fe-Mediated Nitrogen Fixation with a Metallocene Mediator: Exploring pK_a Effects and Demonstrating Electrocatalysis [PDF]

open access: yes, 2018
Substrate selectivity in reductive multi-electron/proton catalysis with small molecules such as N_2, CO_2, and O_2 is a major challenge for catalyst design, especially where the competing hydrogen evolution reaction (HER) is thermodynamically and ...
Chalkley, Matthew J.   +3 more
core   +1 more source

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