A general strategy for heterogenizing olefin polymerization catalysts and the synthesis of polyolefins and composites [PDF]
Nature Communications, 2022 The heterogenization of homogeneous metal complexes on solid supports has a series of drawbacks that restrict their implementation in olefin polymerization, particularly for copolymerization with polar comonomers. Here the authors show an ionic anchoring
Chen Zou, Guifu Si, Changle Chen
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Atomistic simulation of olefin polymerization reaction by organometallic catalyst: significant role of microscopic structural dynamics of (pyridylamido) Hf(IV) complex in catalytic reactivity [PDF]
Frontiers in ChemistryUnderstanding the microscopic catalytic mechanism of the olefin polymerization reaction is crucial for the rational design of next-generation catalysts.
Kentaro Matsumoto +6 more
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Active site nature of magnesium dichloride-supported titanocene catalysts in olefin polymerization [PDF]
Polyolefins Journal, 2015 Heterogeneous Ziegler-Natta and homogeneous metallocene catalysts exhibit greatly different active sitenature in olefin polymerization. In our previous study, it was reported that MgCl2-supported titanocenecatalysts can generate both Ziegler-Natta-type ...
Toshiaki Taniike +2 more
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Preparation of Pincer Hafnium Complexes for Olefin Polymerization [PDF]
Molecules, 2019 Pincer-type [Cnaphthyl, Npyridine, Namido]HfMe2 complex is a flagship among the post-metallocene catalysts. In this work, various pincer-type Hf-complexes were prepared for olefin polymerization.
Su Jin Kwon +8 more
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Olefin polymerization catalysts
Polimery, 2002 Polyolefins, which are products of polymerisation of unsaturated hydrocarbons of the olefin series, have a molecular weight in the range from several thousands to several millions. Depending on the type of monomer and method and mechanism of polymerisation the resulting polyolefins may differ in their structure and molecular weight. They can be used in
Maria Nowakowska
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Octahedral Zirconium Salan Catalysts for Olefin Polymerization: Substituent and Solvent Effects on Structure and Dynamics. [PDF]
Inorg Chem, 2023 Dall'Anese A +11 more
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Late Transition Metal Catalysts with Chelating Amines for Olefin Polymerization [PDF]
Catalysts, 2022 Handou Zheng, Lixia Pei, Haiyang Gao
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Polymer Testing, 2023 Isotactic polybutene-1 (PB)/isotactic polypropylene (PP) blends, typical crystalline/crystalline polymer blends with low-melting-temperature (Tm) PB and high-Tm PP, exhibit complicated interactions between their components in both molten and solid states.
Xiangjie Yan +5 more
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An improved method for the high isotacticity measurement of polybutene-1
Polymer Testing, 2021 High isotactic polybutene-1 (HiPB) plays important roles in presenting outstanding resistance to creep and crack at high temperature. Therefore, rapid and accurate measurement of the HiPB is extremely important for both synthesis and application of ...
Weiping Zheng +4 more
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Polymer Testing, 2023 The creep resistance of polymer determines the dimensional stability of product under stress. The isotactic polybutene-1 (iPB) with outstanding high-temperature creep resistance and stress-crack resistance is applied widely in the field of hot-water ...
Yuanjin Zhao +3 more
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