Results 41 to 50 of about 5,339 (237)

Mixed‐Metal Promotion in a Manganese‐Molybdenum Oxynitride as Catalyst to Integrate C─C and C─N Coupling Reactions for the Direct Synthesis of Acetonitrile from Syngas and Ammonia

open access: yesAdvanced Materials, EarlyView.
Transition metal oxy/carbo‐nitrides show great promise as catalysts for sustainable processes. A Mn‐Mo mixed‐metal oxynitride attains remarkable performance for the direct synthesis of acetonitrile, an important commodity chemical, via sequential C─N and C─C coupling from syngas (C1) and ammonia (N1) feedstocks.
M. Elena Martínez‐Monje   +7 more
wiley   +1 more source

In Situ Amine Formation to Modulate MOF‐Derived PdIn N‐Doped Carbon Catalysts

open access: yesAdvanced Materials, EarlyView.
An amine‐assisted approach converts PdIn‐MOF into PdIn intermetallic nanoparticles embedded in N‐doped carbon. In situ‐generated amines trigger early Pd nucleation, producing smaller PdIn domains than direct pyrolysis. Amine sterics and basicity tune composition and particle size, while solvent and amine co‐determine textural features.
Gonzalo Egea   +9 more
wiley   +1 more source

"Supported Ziegler-Natta catalysts from MgCl2·nROH precursors and its catalytic behaviors for diene copolymerization"

open access: yesHecheng xiangjiao gongye
The precursor MgCl2 · nROH of supported Ziegler Natta catalyst was prepared by chemical activation method, and different pre catalysts TiCl4/MgCl2 (C-Cat) were prepared by loading TiCl4.
FAN Xun-zhang, ZHAO Yuan-jin, LUO Shu-fang, HE Ai-hua?
doaj   +1 more source

Synthesis of novel styrene-olefin triblock copolymer via living anionic polymerization [PDF]

open access: yesPolyolefins Journal
Innovative strides in polymer synthesis have led to the successful living anionic polymerization of styrene-olefin triblock copolymers, yielding varying molecular weights and a remarkably narrow dispersity (Đ) in cyclohexane solvent at 45°C, initiated by
Mohammad Jozaghkar, Farshid Ziaee
doaj   +1 more source

Phase Engineering of Nanomaterials (PEN): Evolution, Current Challenges, and Future Opportunities

open access: yesAdvanced Materials, EarlyView.
This review summarizes the synthesis, phase transition, advanced characterization spanning ex situ to in situ and operando techniques, and diverse applications of phase engineering of nanomaterials (PEN). It further outlines key challenges and future opportunities, such as phase stability, architecture control, and artificial intelligence (AI)‐driven ...
Ye Chen   +7 more
wiley   +1 more source

Weaving Intelligence: Thermally Drawn Multimaterial Fibers Toward AI‐Enabled Smart Textiles

open access: yesAdvanced Materials, EarlyView.
Thermally drawn multimaterial fibers are rapidly advancing as intelligent structural units for next‐generation smart textiles. Integrating multimaterial architectures with neuromorphic and spiking‐neural‐network principles enables fabrics that can sense, compute, and adapt autonomously.
Vuong Dinh Trung   +9 more
wiley   +1 more source

DFT Modeling of Coordination Polymerization of Polar Olefin Monomers by Molecular Metal Complexes

open access: yesInorganics
Introducing polar functional groups into polyolefin chains through polar olefin monomer coordination (co)polymerization can directly and significantly improve the surface properties of polymer materials and expand their application range.
Yanan Zhao, Zhenli Zhang, Yi Luo
doaj   +1 more source

Fabrication of Fibers With Complex Features Using Thermal Drawing of 3D‐Printed Preforms

open access: yesAdvanced Materials Technologies, EarlyView.
3D printing enables rapid fabrication of macroscale polymer preforms with complex geometries. Thermal drawing then scales these structures into long fibers while preserving micron‐scale cross‐sectional features. This workflow provides a fast, low‐cost route to functional fibers with tailored geometries and material combinations for catheter, robotic ...
Ali Anil Demircali   +4 more
wiley   +1 more source

Functional Fibers in Soft Robotics: Advances in Material, Structural, and Systemic Tactics

open access: yesAdvanced Robotics Research, EarlyView.
Fiber‐form robotic systems offer a scalable pathway toward embodied intelligence in soft robotics. This review surveys functional fibers as material, structural, and systemic elements, highlighting advances in responsive materials, architectural programing, and fabrication strategies.
Joonhee Won   +5 more
wiley   +1 more source

Facile Preparation of a Poly[2]Catenane Network Using Self‐Assembled [2]Catenane Unit

open access: yesAngewandte Chemie, EarlyView.
Polycatenanes show a higher degree of conformational freedom and mobility compared to covalent polymers. However, the number of its studies is far lower than that of other dynamic polymers. This may reflect the fact that the preparation of polycatenanes involves the complicated synthesis of covalent catenation.
Jinsa Li   +5 more
wiley   +2 more sources

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