Synthesis of Telechelic Polyisoprene via Ring-Opening Metathesis Polymerization in the Presence of Chain Transfer Agent [PDF]
Telechelic polyisoprene was synthesized via the ring-opening metathesis polymerization (ROMP) of 1,5-dimethyl-1,5-cyclooctadiene (DMCOD) in the presence of cis-1,4-diacetoxy-2-butene as a chain transfer agent (CTA).
Grubbs, Robert H., Thomas, Renee M.
core +2 more sources
Ring-Expansion Metathesis Polymerization: Catalyst-Dependent Polymerization Profiles [PDF]
Ring-expansion metathesis polymerization (REMP) mediated by recently developed cyclic Ru catalysts has been studied in detail with a focus on the polymer products obtained under varied reaction conditions and catalyst architectures.
Boydston, Andrew J. +6 more
core +2 more sources
Olefin solution polymerization can be used to obtain high-performance polyolefin materials that cannot be obtained via other polymerization processes. Polyolefin elastomers (POE) are a typical example.
Changjiang Wu +7 more
doaj +1 more source
Monomer effect on the chain transfer by diethyl zinc in olefin polymerization by metallocene catalysts [PDF]
The present paper systematically studies the homo- and copolymerization of ethylene or propylene using metallocene as catalyst and diethyl zinc as chain transfer agent to obtain the polyolefin waxes with narrow molecular weight distribution and with a ...
Wei Wang, Taoyi Zhang, Liping Hou
doaj +1 more source
Continuous Additive Manufacturing using Olefin Metathesis
The development of chemistry is reported to implement selective dual‐wavelength olefin metathesis polymerization for continuous additive manufacturing (AM).
Jeffrey C. Foster +6 more
doaj +1 more source
Nickel-based ethylene polymerization catalysts have unique features, being able to produce macromolecules with a variable content of branches, resulting in polymers ranging from semicrystalline plastics to elastomers to hyperbranched amorphous waxes and ...
Ilaria D’Auria +2 more
doaj +1 more source
Zirconium and titanium complexes supported by tridentate LX2 ligands having two phenolates linked to furan, thiophene, and pyridine donors: precatalysts for propylene polymerization and oligomerization [PDF]
Zirconium and titanium complexes with tridentate bis(phenolate)-donor (donor = pyridine, furan and thiophene) ligands have been prepared and investigated for applications in propylene polymerization.
Agapie, Theodor +4 more
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The present article contains the data of tensile stress-strain curves, crosslinking characteristics curves, filler dispersion images and dynamic mechanical properties of SSBR/BR blends and SSBR/BR/SiO2 composites during room-temperature annealing.
Xinping Zhang +3 more
doaj +1 more source
Monotelechelic Poly(oxa)norbornenes by Ring-Opening Metathesis Polymerization Using Direct End-Capping and Cross-Metathesis [PDF]
Two different methodologies for the synthesis of monotelechelic poly(oxa)norbornenes prepared by living ring-opening metathesis polymerization (ROMP) are presented.
Grubbs, Robert H., Matson, John B.
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Photolithographic Olefin Metathesis Polymerization
Patterning functional materials is a central challenge across many fields of science. The ability to lithographically fabricate micro- and nanostructures has been one of the most impactful technological breakthroughs of the last century. In part due to the complexity of the chemical processes in photoresists, there is a limited variety of materials ...
Weitekamp, Raymond A. +2 more
openaire +3 more sources

