Results 11 to 20 of about 5,339 (237)

A general strategy for heterogenizing olefin polymerization catalysts and the synthesis of polyolefins and composites [PDF]

open access: yesNature Communications, 2022
The heterogenization of homogeneous metal complexes on solid supports has a series of drawbacks that restrict their implementation in olefin polymerization, particularly for copolymerization with polar comonomers. Here the authors show an ionic anchoring
Chen Zou, Guifu Si, Changle Chen
doaj   +2 more sources

Atomistic simulation of olefin polymerization reaction by organometallic catalyst: significant role of microscopic structural dynamics of (pyridylamido) Hf(IV) complex in catalytic reactivity [PDF]

open access: yesFrontiers in Chemistry
Understanding the microscopic catalytic mechanism of the olefin polymerization reaction is crucial for the rational design of next-generation catalysts.
Kentaro Matsumoto   +6 more
doaj   +2 more sources

Preparation of Pincer Hafnium Complexes for Olefin Polymerization [PDF]

open access: yesMolecules, 2019
Pincer-type [Cnaphthyl, Npyridine, Namido]HfMe2 complex is a flagship among the post-metallocene catalysts. In this work, various pincer-type Hf-complexes were prepared for olefin polymerization.
Su Jin Kwon   +8 more
doaj   +2 more sources

Accelerated crystallization and crystal-crystal transition of PB induced by PP with optimized content

open access: yesPolymer Testing, 2023
Isotactic polybutene-1 (PB)/isotactic polypropylene (PP) blends, typical crystalline/crystalline polymer blends with low-melting-temperature (Tm) PB and high-Tm PP, exhibit complicated interactions between their components in both molten and solid states.
Xiangjie Yan   +5 more
doaj   +1 more source

An improved method for the high isotacticity measurement of polybutene-1

open access: yesPolymer Testing, 2021
High isotactic polybutene-1 (HiPB) plays important roles in presenting outstanding resistance to creep and crack at high temperature. Therefore, rapid and accurate measurement of the HiPB is extremely important for both synthesis and application of ...
Weiping Zheng   +4 more
doaj   +1 more source

High-temperature creep behaviors of polybutene-1 with different chain microstructure and molecular weight

open access: yesPolymer Testing, 2023
The creep resistance of polymer determines the dimensional stability of product under stress. The isotactic polybutene-1 (iPB) with outstanding high-temperature creep resistance and stress-crack resistance is applied widely in the field of hot-water ...
Yuanjin Zhao   +3 more
doaj   +1 more source

Multi-heterostructure composites of Fe3O4 coated Janus nanoparticles and MWCNTs with high microwave absorption

open access: yesPolymer Testing, 2023
Microwave-absorbing materials with heterostructure represent a major challenge and opportunity in enabling strong microwave absorption over a wide bandwidth.
Hengqian Jin   +4 more
doaj   +1 more source

Evolution of crosslinking networks structure and thermo-oxidative aging behavior of unfilled NR/BR blends with TBIR as extra functional compatibilizer

open access: yesPolymer Testing, 2022
As the most popular rubber blends in rubber industry, the aging behaviors of NR/BR vulcanizates have been a major challenge in science and industry. Our previous work reported the substitution of trans-1,4-poly (isoprene-co-butadiene) (TBIR) for BR in ...
Huafeng Shao, Qinrui Guo, Aihua He
doaj   +1 more source

Interfacial structure and properties of isotactic polybutene-1/polyethylene blends

open access: yese-Polymers, 2022
Polymer blending is one of the most economical and effective techniques for achieving products with high comprehensive performances. However, the immiscibility between polymers results in a weak interface, which is typically the position where material ...
Niu Xiu   +5 more
doaj   +1 more source

"Relationship between microstructure and properties of chlorinated butyl rubber"

open access: yesHecheng xiangjiao gongye, 2023
Several chlorinated butyl rubbers (CIIR) with different microstructures were selected to study the effects of microstructure and calcium stearate content on their vulcanization characteristics, physical and mechanical properties and heat aging resistance.
GAO Song1,2, HAO Fu-lan1,2, MOU Xiao-juan1,2, FAN Guang-kun1,2, ZHENG Hong-bing1,2
doaj   +1 more source

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