Unexpected Ductility Enhancement in Crystalline-Crystalline Polyolefin Diblock Copolymers without Introducing Soft Segments. [PDF]
Di Girolamo R +3 more
europepmc +1 more source
Unusual phenomena of ethylene homopolymerization catalyzed by α-diimine nickel emerging in a microflow platform. [PDF]
Zhang Z, Li T, Dong Y, Lu Y.
europepmc +1 more source
Controlled Chain-Walking Polymerization in the Gas Phase to Ultrahigh Molecular Weight Polyethylene. [PDF]
Wang Y, Li S, Zhang M, Dai S.
europepmc +1 more source
Mechanism of cationic ring-opening polymerisation of ε-caprolactone using metallocene/borate catalytic systems: a DFT and NCI study on chain initiation, propagation and termination. [PDF]
Meelua W, Linnolahti M, Jitonnom J.
europepmc +1 more source
Olefin Polymerizations Oriented by Rational Designs of Group-13 Compounds. [PDF]
Tanaka R, Zou Y.
europepmc +1 more source
Polymerization of allylbenzene with metallocene catalysts
Homopolymerization of allylbenzene was carried out with various metallocene/methylaluminoxane (MAO) catalysts. Different polymerization behavior was observed depending upon the catalysts empolyed. rac-Et(Ind)2ZrCl2 and rac-Me2Si(Ind)2ZrCl2 gave semicrystalline polyallylbenzenes while i-Pr(CpFlu)ZrCl2 and CpTiCl3 did not give any polymeric product.
Doo-Jin Byun +3 more
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Catalyst comprising a metallocene complex and a co-catalyst
The invention relates to a metallocene complex, I (M = metal selected from lanthanides or transition metals from group 3, 4, 5 or 6 of the Periodic System of the Elements; Q = anionic ligand to M, k is the no. of Q groups and equals the valence of M minus 2, R = bridging group contg. at least one carbon atom bonded to the indenyl moiety at 2-position;
Vadake Kulangara, S. +13 more
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Kinetic and Mechanistic Aspects of Metallocene Polymerization Catalysts
AbstractFor Abstract see ChemInform Abstract in Full Text.
Bochmann, Manfred
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Catalyst comprising a metallocene complex and a co-catalyst
The invention relates to a metallocene complex according to formula I or II wherein M is a metal selected from lanthanides or transition metals from group 3, 4, 5 or 6 of the Periodic System of the Elements, Q is an anionic ligand to M, k is the no. of Q groups and equals the valence of M minus 2, R is a divalent bridging group, R1, R2, R3 and R4 are ...
Vadake Kulangara, S. +9 more
openaire +2 more sources

