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Computational Study on the Inhibition Mechanisms of the Ziegler-Natta Catalyst in the Propylene Polymerization Process: Part 1 Effects of Acetylene and Methylacetylene. [PDF]
Hernandez-Fernandez J +2 more
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Trimethylaluminum Activates Zeolite-Confined Lanthanum Borohydrides to Enhance Catalytic C-H Borylation. [PDF]
Li Y +5 more
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Sulfonated porous organic polymer supported Ziegler-Natta catalysts for the synthesis of ultra-high molecular weight polyethylene. [PDF]
Kang W +5 more
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Macromolecules, 2018
A novel type of comb-branched ethylene/1-octene copolymer elastomers (CPOEs) was synthesized, and their properties were systematically investigated in this work.
Kailun Zhang +5 more
semanticscholar +1 more source
A novel type of comb-branched ethylene/1-octene copolymer elastomers (CPOEs) was synthesized, and their properties were systematically investigated in this work.
Kailun Zhang +5 more
semanticscholar +1 more source
Supported Metallocene Catalysts
CATTECH, 2000Single-site olefin polymerization catalysts have been researched extensively and are now achieving wide acceptance in the polyolefin industry. To achieve commercial significance in the majority of today's commercial processes, these soluble catalysts must be immobilized on a carrier.
Edmund M. Carnahan, Grant B. Jacobsen
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“Oscillating” Metallocene Catalysts: How Do They Oscillate?
Angewandte Chemie International Edition, 2002Based on the results of a series of propylene polymns. using oscillating metallocene catalysts of type [(2-Ar-indenyl)2ZrCl2] (Ar = C6H5 or 3,5-(t-Bu)2-4-MeO-C6H2) with various cocatalysts (MAO, TIBAl), the oscillating behavior of the zirconocenes is discussed with respect to the rac/meso stereochem. outcome of the obtained polypropylenes.
BUSICO, VINCENZO +5 more
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