Graphene-mediated exchange coupling between a molecular spin and magnetic substrates [PDF]
Using first-principles calculations we demonstrate sizable exchange coupling between a magnetic molecule and a magnetic substrate via a graphene layer. As a model system we consider cobaltocene (CoCp2) adsorbed on graphene deposited on Ni(111).
MANGHI, Franca +5 more
core +2 more sources
Tandem Takeoff: Powering Tomorrow with Industrial‐Grade Perovskite/Silicon Solar Cells
Perovskite/silicon tandem solar cells have recently achieved certified power conversion efficiencies of 34.85%, far exceeding the Shockley‐Queisser limit for single‐junction silicon and standalone perovskite cells. This review highlights the latest advances in the design, integration, and optimization of perovskite top cells for monolithic tandem ...
Maria Vasilopoulou +19 more
wiley +1 more source
Synthesis, Structure, and Dynamics of Tris(η5-cyclopentadienyl)lanthanides and Bis(η5-cyclopentadienyl)[bis(trimethylsilyl)amido]cerium(III) [PDF]
The crystal structures of tris(η5-cyclopentadienyl)lanthanides (Ln = Ce, Dy, Ho) have been determined using different X-ray diffraction methods. Cp3Ce and Cp3Ho (Cp = cyclopentadienyl) crystal data needed special solution and refinement methods, due to ...
Baisch, Ulrich +5 more
core +1 more source
Replacing butyl rubber with ENR+Wollastonite in tyre inner‐liners. ABSTRACT This study aimed to develop epoxidised natural rubber (ENR)‐based rubber compound formulations as an alternative to butyl rubber for tyre inner liners. The effects of different vulcanization systems, designed to achieve similar curing behavior in NR‐based carcass compounds and ...
Tuba Ünügül Yavuz +4 more
wiley +1 more source
Comparative NMR study on the reactions of Hf(IV) organometallic complexes with Al/Zn alkyls [PDF]
NMR spectroscopy has been exploited to investigate the reactions of Hf(IV) organometallic complexes with trialkylaluminum and dialkylzinc, with the aim of obtaining insights into the elementary steps of coordinative chain transfer polymerization (CCTP ...
Busico, Vincenzo +3 more
core +2 more sources
In this study, COOH-functionalized co-polymer of acrylonitrile and itaconic acid (P(AN-co-IA)) is synthesized via free radical copolymerization using DMSO as solvent.
Taewoo Kim +4 more
doaj +1 more source
Cp* Noninnocence Leads to a Remarkably Weak C–H Bond via Metallocene Protonation [PDF]
Metallocenes, including their permethylated variants, are extremely important in organometallic chemistry. In particular, many are synthetically useful either as oxidants (e.g., Cp_2Fe^+) or as reductants (e.g., Cp_2Co, Cp*_2Co, and Cp*_2Cr).
Chalkley, Matthew J. +2 more
core +5 more sources
Current applications and future potential for bioinorganic chemistry in the development of anticancer drugs [PDF]
This review illustrates notable recent progress in the field of medicinal bioinorganic chemistry as many new approaches to the design of innovative metal-based anticancer drugs are emerging.
Aird +75 more
core +1 more source
One-pot synthesis of an ionic half-sandwich complex of Neodymium. Application to stereospecific isoprene polymerization catalysis. [PDF]
International audienceThe reaction of one equivalent of Nd(BH4)3(THF)3 with an half equivalent of dialkylmagnesium in the presence of a stoechiometric amount of pentamethylcyclopentadiene cleanly affords a new kind of half-sandwich of neodymium that is ...
Mortreux, André +3 more
core +3 more sources
Harvesting and Electron-Exchange Energy Transfer by d0 Metallocene-based Organized Systems [PDF]
The present contribution will provide an up-to-date overview of novel experimental and theoretical (de-rived quantum-chemically) knowledge on photonics of group IV metallocene-based systems, also with re-spect to their prominent use in catalysis and ...
Loukova, G.V.
core

