Results 1 to 10 of about 1,104 (197)
Metalloborospherene Analogs to Metallofullerene
Boron, the neighbor element to carbon in the periodic table, is characterized by unique electron deficiency that fosters multicenter delocalized bonding, contributing to its diverse chemistry.
Jordan Burkhardt +2 more
doaj +3 more sources
A new class of single‐molecule magnets (SMMs) based on Dy‐oxide clusterfullerenes is synthesized. Three isomers of Dy2O@C82 with Cs(6), C3v(8), and C2v(9) cage symmetries are characterized by single‐crystal X‐ray diffraction, which shows that the ...
Wei Yang +12 more
doaj +1 more source
A Dual PET/MR Imaging Nanoprobe: 124I Labeled Gd3N@C80
The current report describes the development of a dual modality tomographic agent for both positron emission tomography and magnetic resonance imaging (PET/MRI).
Jianqiao Luo +6 more
doaj +1 more source
Infrared Spectral Fingerprint of Neutral and Charged Endo- and Exohedral Metallofullerenes
Small metal-containing molecules have been detected and recognized as one of the hybrid species that are efficiently formed in space, especially in the circumstellar envelopes of evolved stars.
R. Barzaga +7 more
doaj +1 more source
New Horizons in Chemical Functionalization of Endohedral Metallofullerenes
This overview explains some new aspects of chemical functionalization of endohedral metallofullerenes (EMFs) that have been unveiled in recent years.
Michio Yamada +3 more
doaj +1 more source
Structure of [60]fullerene with a mobile lithium cation inside [PDF]
The structure of crystalline [60]fullerene with a lithium cation inside (Li+@C60) was determined by synchrotron radiation X-ray diffraction measurements to understand the electrostatic and thermal properties of the encapsulated Li+ cation.
Shinobu Aoyagi +5 more
doaj +1 more source
Photochemical carbosilylation of Lu3N@Ih-C80 was performed using siliranes (silacyclopropanes) to afford the corresponding [5,6]- and [6,6]-adducts.
Masahiro Kako +9 more
doaj +1 more source
We isolated and purified three disamarium metallofullerenes of known structure, Sm2@D2(35)-C88, Sm2@C1(21)-C92 and Sm2@D3d(822)-C104, by the reported method.
Jie Chen +4 more
doaj +3 more sources
Functionalization of Endohedral Metallofullerenes with Reactive Silicon and Germanium Compounds
Exohedral derivatization of endohedral metallofullerenes (EMFs) has been exploited as a useful method for characterizing the structural and chemical properties of EMFs, and for functionalizing them for potential applications.
Masahiro Kako +2 more
doaj +1 more source
Thermodynamically stable [4 + 2] cycloadducts of lanthanum-encapsulated endohedral metallofullerenes
The [4 + 2] cycloaddition of o-quinodimethanes, generated in situ from the sultine 4,5-benzo-3,6-dihydro-1,2-oxathiin 2-oxide and its derivative, to La metal-encapsulated fullerenes, La2@C80 or La@C82, afforded the novel derivatives of endohedral ...
Yuta Takano +4 more
doaj +1 more source

