Results 1 to 10 of about 1,104 (197)

Metalloborospherene Analogs to Metallofullerene

open access: yesInorganics
Boron, the neighbor element to carbon in the periodic table, is characterized by unique electron deficiency that fosters multicenter delocalized bonding, contributing to its diverse chemistry.
Jordan Burkhardt   +2 more
doaj   +3 more sources

Single Molecule Magnetism with Strong Magnetic Anisotropy and Enhanced Dy∙∙∙Dy Coupling in Three Isomers of Dy‐Oxide Clusterfullerene Dy2O@C82

open access: yesAdvanced Science, 2019
A new class of single‐molecule magnets (SMMs) based on Dy‐oxide clusterfullerenes is synthesized. Three isomers of Dy2O@C82 with Cs(6), C3v(8), and C2v(9) cage symmetries are characterized by single‐crystal X‐ray diffraction, which shows that the ...
Wei Yang   +12 more
doaj   +1 more source

A Dual PET/MR Imaging Nanoprobe: 124I Labeled Gd3N@C80

open access: yesApplied Sciences, 2012
The current report describes the development of a dual modality tomographic agent for both positron emission tomography and magnetic resonance imaging (PET/MRI).
Jianqiao Luo   +6 more
doaj   +1 more source

Infrared Spectral Fingerprint of Neutral and Charged Endo- and Exohedral Metallofullerenes

open access: yesThe Astrophysical Journal Supplement Series, 2023
Small metal-containing molecules have been detected and recognized as one of the hybrid species that are efficiently formed in space, especially in the circumstellar envelopes of evolved stars.
R. Barzaga   +7 more
doaj   +1 more source

New Horizons in Chemical Functionalization of Endohedral Metallofullerenes

open access: yesMolecules, 2020
This overview explains some new aspects of chemical functionalization of endohedral metallofullerenes (EMFs) that have been unveiled in recent years.
Michio Yamada   +3 more
doaj   +1 more source

Structure of [60]fullerene with a mobile lithium cation inside [PDF]

open access: yesRoyal Society Open Science, 2018
The structure of crystalline [60]fullerene with a lithium cation inside (Li+@C60) was determined by synchrotron radiation X-ray diffraction measurements to understand the electrostatic and thermal properties of the encapsulated Li+ cation.
Shinobu Aoyagi   +5 more
doaj   +1 more source

Photoreactions of Endohedral Metallofullerene with Siliranes: Electronic Properties of Carbosilylated Lu3N@Ih-C80

open access: yesMolecules, 2017
Photochemical carbosilylation of Lu3N@Ih-C80 was performed using siliranes (silacyclopropanes) to afford the corresponding [5,6]- and [6,6]-adducts.
Masahiro Kako   +9 more
doaj   +1 more source

Electrochemical Studies of Three Disamarium Large Metallofullerenes Sm2@D2(35)-C88, Sm2@C1(21)-C92 and Sm2@D3d(822)-C104

open access: yesInternational Journal of Electrochemical Science, 2016
We isolated and purified three disamarium metallofullerenes of known structure, Sm2@D2(35)-C88, Sm2@C1(21)-C92 and Sm2@D3d(822)-C104, by the reported method.
Jie Chen   +4 more
doaj   +3 more sources

Functionalization of Endohedral Metallofullerenes with Reactive Silicon and Germanium Compounds

open access: yesMolecules, 2017
Exohedral derivatization of endohedral metallofullerenes (EMFs) has been exploited as a useful method for characterizing the structural and chemical properties of EMFs, and for functionalizing them for potential applications.
Masahiro Kako   +2 more
doaj   +1 more source

Thermodynamically stable [4 + 2] cycloadducts of lanthanum-encapsulated endohedral metallofullerenes

open access: yesBeilstein Journal of Organic Chemistry, 2014
The [4 + 2] cycloaddition of o-quinodimethanes, generated in situ from the sultine 4,5-benzo-3,6-dihydro-1,2-oxathiin 2-oxide and its derivative, to La metal-encapsulated fullerenes, La2@C80 or La@C82, afforded the novel derivatives of endohedral ...
Yuta Takano   +4 more
doaj   +1 more source

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