Results 11 to 20 of about 1,104 (197)

Photoelectrochemical Response Enhancement for Metallofullerene-[12]Cycloparaphenylene Supramolecular Complexes [PDF]

Nanomaterials, 2022
The photoelectrochemical properties of three metallofullerene-[12]cycloparaphenylene ([12]CPP) supramolecular complexes of Sc3N@C78⊂[12]CPP, Sc3N@C80⊂[12]CPP, and Sc2C2@C82⊂[12]CPP were studied.
Zhu-Xia Zhang, Linshan Liu
exaly   +5 more sources

Embedded nano spin sensor for in situ probing of gas adsorption inside porous organic frameworks [PDF]

Nature Communications, 2023
Spin-based sensors have attracted considerable attention owing to their high sensitivities. Herein, we developed a metallofullerene-based nano spin sensor to probe gas adsorption within porous organic frameworks.
Jie Zhang, Linshan Liu, Chaofeng Zheng, Wang Li, Chunru Wang, Taishan Wang   +5 more
doaj   +2 more sources

Synthesis of Endohedral Metallofullerene Glycoconjugates by Carbene Addition

Molecules, 2011
Endohedral metallofullerene glycoconjugates were synthesized under mild conditions by carbene addition using appropriate glycosylidene-derived diazirine with La2@Ih-C80.
Takeshi Akasaka, Yutaka Maeda, Chika I. Someya, Takahiro Tsuchiya, Tsukasa Nakahodo, Michio Yamada   +5 more
doaj   +2 more sources

Regioselective Radical Reaction of Monometallofullerene Y@C2v(9)-C82 With N-arylbenzamidine Mediated by Silver Carbonate [PDF]

Frontiers in Chemistry, 2020
A novel radical reaction of monometallofullerene Y@C2v(9)-C82 with N-arylbezamidine (1) is successfully conducted through catalysis with silver carbonate. The high-performance liquid chromatographic and mass spectrum results demonstrate that the reaction
Jia Li, Pengyuan Yu, Peng Lai, Jiajun Zou, Zhe Liu, Xiuguang Yi, Wei Wang, Changwang Pan, Changwang Pan   +8 more
doaj   +2 more sources

DFT Calculations of Structure and IR Spectra of Gd₂@C₈₂ Endofullerenes [PDF]

Molecules
Dimetallofullerenes are obtained in synthesis in parallel to monometallofullerenes, but they are less studied because their yields are considerably lower. In this work, DFT modeling of Gd2@C82 endohedral metallofullerene (EMF) has been performed. A total
Igor V. Nechaev, Alexey V. Krisilov, Vladislav E. Chernov, Marina G. Holyavka   +3 more
doaj   +2 more sources

Molecular spin sensor for in-situ monitoring of crystallization behavior and phase transition in aromatic materials [PDF]

Nature Communications
Spin-active materials with sensitive electron spin centers have drawn significant attention in quantum sensing due to their unique quantum characteristics. Herein, we report a molecular spin sensor based on metallofullerene Y2@C79N for in-situ monitoring
Linshan Liu, Chong Zhao, Yingjian Zhang, Zhuxia Zhang, Chunru Wang, Taishan Wang   +5 more
doaj   +2 more sources

A hard molecular nanomagnet from confined paramagnetic 3d-4f spins inside a fullerene cage [PDF]

Nature Communications, 2023
Reducing inter-spin distance can enhance magnetic interactions and allow for the realization of outstanding magnetic properties. However, achieving reduced distances is technically challenging.
Chenli Huang, Rong Sun, Lipiao Bao, Xinyue Tian, Changwang Pan, Mengyang Li, Wangqiang Shen, Kun Guo, Bingwu Wang, Xing Lu, Song Gao   +10 more
doaj   +2 more sources

Stability and Electronic Properties of Mixed Rare-Earth Tri-Metallofullerenes YxDy_3-x@C₈₀ (x = 1 or 2) [PDF]

Molecules
Tri-metallofullerenes, specifically M3@C80 where M denotes rare-earth metal elements, are molecules that possess intriguing magnetic properties. Typically, only one metal element is involved in a given tri-metallofullerene molecule.
Yabei Wu, Zhonghao Zhou, Zhiyong Wang
doaj   +2 more sources

Nanorods of endohedral metallofullerene derivative

Journal of the American Chemical Society, 2008
The article presents a research which discusses the preparation and characterization of the nanorods of the endohedral metallofullerene derivative lanthanum (La)@carbon(C)82(Ad).
Takahiro, Tsuchiya, Ryotaro, Kumashiro, Katsumi, Tanigaki, Yoichiro, Matsunaga, Midori O, Ishitsuka, Takatsugu, Wakahara, Yutaka, Maeda, Yuta, Takano, Motoki, Aoyagi, Takeshi, Akasaka, Michael T H, Liu, Tatsuhisa, Kato, Kazutomo, Suenaga, Jong S, Jeong, Sumio, Iijima, Fumiko, Kimura, Tsunehisa, Kimura, Shigeru, Nagase   +17 more
core   +3 more sources

Nd─Nd Bond in Ih and D5h Cage Isomers of Nd2@C80 Stabilized by Electrophilic CF3 Addition [PDF]

Advanced Science
Synthesis of molecular compounds with metal–metal bonds between 4f elements is recognized as one of the fascinating milestones in lanthanide metallochemistry.
Wei Yang, Georgios Velkos, Marco Rosenkranz, Sandra Schiemenz, Fupin Liu, Alexey A. Popov   +5 more
doaj   +2 more sources