A quartz crystal adsorbent coated with 5,10,15,20-tetrakis(4-methylphenyl) porphyrin was used to examine the complexation phenomenon of three metallic ions [aluminum(III), iron(III) and indium(III)].
Haifa Alyousef +4 more
doaj +1 more source
Remarkable enhancement of catalytic activity of a 2 : 1 complex between a non-planar Mo(V)–porphyrin and a ruthenium-substituted Keggin-type heteropolyoxometalate in catalytic oxidation of benzyl alcohols [PDF]
A 2 : 1 complex composed between a non-planar Mo(V)–porphyrin complex ([Mo(DPP)(O)]+, DPP2− = dodecaphenylporphyrin) and a ruthenium-substituted Keggin-type heteropolyoxometalate (Ru-POM), [SiW11O39RuIII(DMSO)]5−, acts as an efficient catalyst for ...
Fukuzumi Shunichi +6 more
core +1 more source
Fiber‐type soft bioelectronics for wearable and implantable sensing and therapy
Fiber‐type soft bioelectronics are emerging as versatile platforms for wearable and implantable health monitoring and therapeutic applications. These bioelectronics use organic and inorganic matrices combined with advanced fillers, which feature high conductivity, electrochemical sensitivity, softness, and biocompatibility.
Haneul Kim +5 more
wiley +1 more source
Multiporphyrin coordination arrays based on complexation of magnesium(II) porphyrins with porphyrinylphosphine oxides [PDF]
Di- and triporphyrin arrays consisting of 5,15-diphenylporphyrinatomagnesium(II) (MgDPP) coordinated to free- base and Ni( II) porphyrinyl mono- and bis-phosphine oxides, as well as the self-coordinating diphenyl[10,20-diphenylporphyrinatomagnesium(II)-5-
Arnold, D. P. +2 more
core +2 more sources
The axial‐bonding of aluminum(III) porphyrins was used to create two covalently linked special‐pair mimics to probe charge‐transfer between a porphyrin dimer and a C60 unit for artificial photosynthesis. Although excitonic coupling between the porphyrins is weak, incorporation of a second porphyrin markedly increases both the yield and lifetime of the ...
Stefan Charon +7 more
wiley +1 more source
Multispectral oximetry of murine tendon microvasculature with inflammation [PDF]
We report a novel multispectral imaging technique for localised measurement of vascular oxygen saturation (SO2) in vivo. Annular back-illumination is generated using a Schwarzchild-design reflective objective.
Brewer, James M +2 more
core +1 more source
Heteroatom‐Doped Graphdiynes and Their Applications in Photo‐/Electro‐Catalytic CO2 Conversion
This review highlights the versatile role of doped graphdiyne (GDY) in boosting CO2 conversion, where metal and non‐metal doping simultaneously tune the electronic structure, create abundant active sites, and improve charge separation, light harvesting, and CO2 adsorption.
Fangzhou Yang +3 more
wiley +1 more source
Application of Rh(III)-Metalloporphyrin Grafted Fe3O4 Nanoparticles for the Extraction of Thiocyanate Ions from Aqueous Solutions [PDF]
A new sorbent composed of 3-aminopropyltriethoxy-silane-coated magnetic nanoparticles, functionalized with rhodium(III) porphyrin complex was synthesized and characterized by elemental analysis, X-Ray Diffraction (XRD), Transmission Electron Microscopy ...
Tahereh Poursaberi +2 more
doaj
Subsequent treatment of H2TPP(CO2H)4 (tetra(p-carboxylic acid phenyl)porphyrin, 1) with an excess of oxalyl chloride and HNR2 afforded H2TPP(C(O)NR2)4 (R = Me, 2; iPr, 3) with yields exceeding 80%.
Rasha K. Al-Shewiki +6 more
doaj +1 more source
Elucidating the Ultrafast Dynamics of Photoinduced Charge Separation in Metalloporphyrin-Fullerene Dyads Across the Electromagnetic Spectrum [PDF]
Metalloporphyrins are prominent building blocks in the synthetic toolbox of advanced photodriven molecular devices. When the central ion is paramagnetic, the relaxation pathways within the manifold of excited states are highly intricate so that ...
Canton, S. E. +9 more
core +2 more sources

