Results 71 to 80 of about 4,762 (222)
Metalloporphyrin-Catalyzed Oxidation of 2-Cycloalkyl-3-hydroxynaphthoquinones
Mild H2O2 oxidation of a small series of 2-cycloalkyl-3-hydroxynaphthoquinones catalyzed by 5,10,15,20-tetrakis(pentafluorophenyl)-21H,23H-porphineiron(III) chloride in methanol−dichloromethane leads in each case to the isolation of a dehydro-dimer ...
Peter W. Scott (2325466) +3 more
core +1 more source
Engineered Metal–Organic Frameworks‐Based Materials for Environmental Detection
Engineered metal–organic frameworks (MOFs) regulated by various material modification strategies are discussed for environmental contaminant detection under different sensing mechanisms, providing future improvements of MOFs in environmental detection. Sensitive and selective detection of contaminants is crucial for environmental protection.
Pan Gao +3 more
wiley +1 more source
The Unique Structure–Activity Relationship of Porphyrins and Clay Mineral Systems in Modern Applications: A Comprehensive Review [PDF]
Porphyrins are a group of organic heterocyclic macromolecules, composed of four modified pyrrole subunits interconnected at their α carbon atoms via methine bridges. This unique and significant group of compounds has a special relationship with inorganic
J. Hassen, J. Silver
doaj +1 more source
This review provides an overview of recent developments in metal organic framework (MOF)‐based and MOF‐derived composites for efficient oxygen evolution reaction. This review also emphasizes the structural design of electrocatalyst, active site optimization, and emerging prospects of their use in practical electrolyzer systems.
Bhagyashri B. Kamble +7 more
wiley +1 more source
A new method has been developed for the C–H formylation of aromatic compounds using silyl formates synthesized from CO2 and hydrosilanes. This is the first report on the direct C–H formylation of aromatics with silyl formates. The formylation reactions were promoted by BBr3 or BCl3. The reaction mechanism has been clarified by DFT calculations. Despite
Natsumi Nitta +5 more
wiley +1 more source
Three Porphyrin-Encapsulating Metal–Organic Materials with Ordered Metalloporphyrin Moieties
1,3,5-benzenetricarboxylate, biphenyl-3,4′,5-tricarboxylate, and [1,1′:3′,1″-terphenyl]-4,4″,5′-tricarboxylate react with Cd(II) cations in the presence of meso-tetra(N-methyl-4-pyridyl) porphine cations to afford three metalloporphyrin-encapsulating ...
Lukasz Wojtas (1303443) +2 more
core +1 more source
Synergistic catalysis occurring in an enzyme pocket shows enhanced performance through supramolecular recognition and flexibility. Here the authors design an enzyme-mimic strategy to develop a Co(II) metal-metalloporphyrin gel with excellent ...
Weijie Zhang +4 more
doaj +1 more source
An overview of design principles and scalable fabrication strategies for multifunctional bio‐based packaging. Radiative cooling films, modified‐atmosphere films/membranes, active antimicrobial/antioxidant platforms, intelligent optical/electrochemical labels, and superhydrophobic surfaces are co‐engineered from material chemistry to mesoscale structure
Lei Zhang +6 more
wiley +1 more source
Halo-Wittig- and zirconium-promoted synthesis of conjugated metalloporphyrin dimers
The synthesis and spectroscopic studies of metalloporphyrin dimers having 1,3-butadiyne linker attached to the beta pyrrolic positions of the linked porphyrins are reported.
Mukhtar Ali +6 more
core +1 more source
LC-MS-MS identification of drug metabolites obtained by metalloporphyrin mediated oxidation
In this paper we report the application of liquid chromatography-mass spectrometry (LC-MS-MS) to the identification of the products formed by oxidation of albendazole and disopyramide with metalloporphyrins in dichloroethane, using iodosylbenzene as an ...
Maurin Andrea J. M. +4 more
doaj

