Results 31 to 40 of about 6,458 (220)

Geospatial Synthesis of Biogeochemical Attributions of Porphyrins to Oil Pollution in Marine Sediments of the Gulf of México

open access: yesGeosciences, 2022
Porphyrins are highly persistent in the environment and represent a helpful biogeochemical attribute to assess the spatial distribution of the effects of oil spills on ecosystems and their resilience.
Francisco Muñoz-Arriola   +1 more
doaj   +1 more source

Synthesis and Properties of Metal-complex Catalysts Based on Oil Metalloporphyrins [PDF]

open access: yes, 2020
The study of the properties and use of natural metalloporphyrins in the development of new highly selective methods for the oxygenation of hydrocarbons at moderate temperatures is an urgent problem.
Aghahuseynova, M. (Minira)
core   +2 more sources

Unravelling the structural‐property relations of porphyrinoids with respect to photo‐ and electro‐chemical activities

open access: yesElectrochemical Science Advances, 2023
Porphyrins have multiple roles in living and nonliving systems because of their exceptional tunable chemical and physical properties. They are interesting macrocyclic compounds that could be modified in a number of ways.
Gita Singh, Sudeshna Chandra
doaj   +1 more source

Immobilized Lignin Peroxidase-Like Metalloporphyrins as Reusable Catalysts in Oxidative Bleaching of Industrial Dyes

open access: yesMolecules, 2016
Synthetic and bioinspired metalloporphyrins are a class of redox-active catalysts able to emulate several enzymes such as cytochromes P450, ligninolytic peroxidases, and peroxygenases.
Paolo Zucca   +5 more
doaj   +1 more source

Metalloporphyrins as therapeutic catalytic oxidoreductants in central nervous system disorders

open access: yes, 2014
Significance: Metalloporphyrins, characterized by a redox-active transitional metal (Mn or Fe) coordinated to a cyclic porphyrin core ligand, mitigate oxidative/nitrosative stress in biological systems.
Chaparro, Raphael E.   +6 more
core   +2 more sources

Seeing smells: development of an optoelectronic nose

open access: yesQuímica Nova, 2007
The development of an array of chemically-responsive dyes on a porous membrane and in its use as a general sensor for odors and volatile organic compounds (VOCs) is reviewed. These colorimetric sensor arrays (CSA) act as an "optoelectronic nose" by using
Kenneth S. Suslick   +11 more
doaj   +1 more source

Carbene Transfer Reactions Catalysed by Dyes of the Metalloporphyrin Group

open access: yesMolecules, 2018
Carbene transfer reactions are very important transformations in organic synthesis, allowing the generation of structurally challenging products by catalysed cyclopropanation, cyclopropenation, carbene C-H, N-H, O-H, S-H, and Si-H insertion, and ...
Mário M. Q. Simões   +8 more
doaj   +1 more source

“Smelltronics”—From Gas to Smell Sensing

open access: yesAdvanced Materials, EarlyView.
The emerging field of smelltronics, encompassing sensing technologies for complex volatile organic compounds, holds significant potential for extracting valuable chemical information. It facilitates the noninvasive, real‐time monitoring of humans, food, and the environment.
Takeshi Ono   +7 more
wiley   +1 more source

A New Composition for Co(II)-porphyrin-based Membranes Used in Thiocyanate-selective Electrodes

open access: yesSensors, 2006
In the present paper, the potentiometric response characteristics of ametalloporphyrin-based electrode in o-nitrophenyloctylether (o-NPOE) plasticizedpolyvinyl chloride (PVC) membrane are presented for a set of monovalent anions.
Otilia Bizerea-Spiridon   +2 more
doaj   +1 more source

Side‐Chain‐Induced Interlayer Slipping in Metalloporphyrin COFs Enables Microenvironment and Spin‐State Regulation for Photocatalytic CO2 Reduction

open access: yesAdvanced Materials, EarlyView.
Alkoxy chain length drives a continuous transition from eclipsed AA to a serrated, slipped AA* configuration over Co‐porphyrin COFs. A moderate slip both contracts the pore channel to enrich CO2 and suppress hydrogen evolution, and enhances collective high‐spin of Co sites, which delivers a record CO production rate with high selectivity.
Jie He   +8 more
wiley   +1 more source

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