Results 191 to 200 of about 266,020 (304)

Cold seep seafloor observatories revise the notion of 'life in the slow lane'. [PDF]

Natl Sci Rev
Teske A.
europepmc   +1 more source

Copper(II/III) Redox Couple Enables C─H Methylation via a Radical Mechanism Analogous to SAM Enzymes

Angewandte Chemie, EarlyView.
Biological C–H methylation proceeds through radical pathways mediated by one‐electron redox cofactors, yet no synthetic model has reproduced this reactivity. Here, we report the first isolable Cu(II/III)–methyl complexes that mediate C–H methylation through hydrogen atom transfer and methyl radical rebound.
Emily N. Doss, Curtis E. Moore, Shiyu Zhang   +2 more
wiley   +2 more sources

The influence mechanism of micropore spatial distribution form on the methane desorption capability in selected Chinese coals. [PDF]

PLoS One
Liang X, Zhang L, Yin B, Guo H, Chen Y, Guo J, Zhang B.   +6 more
europepmc   +1 more source

Borylcyclopropanes: Synthetic Strategies and Applications

Angewandte Chemie, EarlyView.
Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley   +2 more sources

Dynamic Fracture Monitoring Technique in Deep Coal Seams Based on a Time-Varying Electric Field Method

ACS Omega
Jinshui Zhang, Fan Yang, Qi An, Haiyan Ding, XinLe Cao, Bingsen Yan, Qinghuan Deng   +6 more
doaj   +1 more source

Rapid <i>de novo</i> assembly of animal-microbe biofilter to mitigate seabed methane leakage. [PDF]

Natl Sci Rev
Liang Q, Deng L, Xie R, Liu X, Xiao X, Hou J, Wang J, Sui W, Lu N, Tong Z, Huang D, Wang Y, Han Y, Zhao J, Guo B, Zhang W, Geng M, Ren T, Ye W, Xiong Z, Dong L, Ruff SE, Meile C, Tao J, Dong X, Wang F.   +25 more
europepmc   +1 more source

Reaction Environment Engineering for Selective C3+ Formation in CO2 Electroreduction: Progress and Perspectives

Angewandte Chemie, EarlyView.
This work focuses on how to improve the selectivity and activity of electrocatalytic CO2 reduction to C3+ products, by the integration of electrocatalyst and electrolyte co‐design. We summarize key C3+ formation mechanisms and provide a comprehensive reaction network through thermodynamic analysis.
Ling Chen, Damien Voiry, Yan Jiao
wiley   +2 more sources

Mapping the soil microbiome functions shaping wetland methane emissions. [PDF]

mSystems
Borton MA, Oliverio AM, Narrowe AB, Villa JA, Rinke C, Hoyt DW, Liu P, McGivern BB, Bechtold EK, Ellenbogen JB, Daly RA, Smith GJ, Angle JC, Flynn RM, Freiburger AP, Louie KB, Stemple B, Northen TR, Henry C, Miller CS, Morin TH, Bohrer G, Wrighton KC.   +22 more
europepmc   +1 more source

The Role of Zn–Hf Site Proximity and Oxygen Vacancies for Methanol Formation Over ZnHfOx Catalysts Under CO2 Hydrogenation Conditions

Angewandte Chemie, EarlyView.
ZnHfOx catalysts enable highly selective hydrogenation of CO2 to methanol over a wide range of Zn contents, as the Zn‐VO‐Hf active motif (VO = oxygen vacancy) exists not only in solid solution‐type ZnHfOx for low Zn contents (≤ 35 mol%), but also as HfOx cluster/single atom decorated ZnO surfaces for Zn contents > 95 mol%.
Alexander Oing, Diana Piankova, Jean C. Villa‐Arpi, Muhammad Helmi Risansyauqi, Hector Prats, Felix Donat, Paula M. Abdala, Aleix Comas‐Vives, Christoph R. Müller   +8 more
wiley   +2 more sources

Molecular-Scale Study of the Interfacial Effects of Kinetic Inhibitors on Hydrate Growth and Crystal Stability. [PDF]

ACS Omega
Liang H, Mo P, Chen H, Qin R, Shen S, Lv X, Li X.   +6 more
europepmc   +1 more source