Dual Activation of H2 and CO2 by a Pincer‐Type Ni–Zn Heterobimetallic Complex
A bimetallic Ni−Zn complex performs sequential activations of H2 (1 equiv) and CO2 (2 equiv). This bimetallic cooperativity is attributed to the weak Lewis acidic nature of Zn(II), which promotes fluxional ligand binding. Namely, an X‐type ligand at Ni, where X is hydride or formate, toggles between two different binding modes: bridging Zn(μ‐X)Ni and ...
Krishnendu Dey +3 more
wiley +2 more sources
Shifts in ruminant fermentation during inhibition of methanogenesis are reflected in the isotope compositions of volatile fatty acids. [PDF]
Mueller EP +4 more
europepmc +1 more source
A heterogeneous photocatalytic system has been developed that enables the dehydrogenative decarbonylation of primary alcohols under visible light using highly dispersed oxidic iron sites supported on aryl‐modified graphitic carbon nitride (Fe@f–gC3N4).
Jun Hu +11 more
wiley +2 more sources
Seasonal Landfill Methane Emissions Driven by Temperature and Pressure. [PDF]
Hallward-Driemeier A +9 more
europepmc +1 more source
Rapidly Diversifying Hydrogen‐Bonded Organic Frameworks With Permanent Porosity
This article reviews diversifying hydrogen‐bonded organic frameworks (HOFs) with permanent porosity reported over the past 15 years, based on the molecular structures of their constituent tectons. Furthermore, several distinctive aspects and concepts are described, such as permanent porosity, isostructural (isoreticular) HOFs, and multicomponent mixed ...
Taito Hashimoto, Ichiro Hisaki
wiley +2 more sources
RegB/A-dependent redox regulation links iron uptake to methanol metabolism in <i>Methylomonas</i> sp. DH-1. [PDF]
Park W +5 more
europepmc +1 more source
Force‐Induced Control of Circularly Polarized Luminescence With Rotaxane Architecture
Force‐induced reversible on/off switching of circularly polarized luminescence is achieved with a rotaxane‐based supramolecular mechanophore. The mechanophore, featuring a chiral helicene luminophore, is incorporated as a first network cross‐linker into a double‐network organogel.
Keigo Nonaka +10 more
wiley +2 more sources
From Waste to Health: Landfill Biogas Recovery as a Strategy for Greenhouse Gas Mitigation and Public Health Co-Benefits in Brazil. [PDF]
Nazzari EC +6 more
europepmc +1 more source
Variations in methane emissions from dairy cows: associations with rumen microbial synergy and metabolic pathway divergence. [PDF]
Jia P, Dong L, Ma T, Bi Y, Tu Y, Diao Q.
europepmc +1 more source

