Results 171 to 180 of about 1,208,360 (336)

Liquid‐Catalyst‐Activated Sparingly Solvating Electrolytes for Low‐Temperature Potassium‐Sulfur Batteries

open access: yesAdvanced Energy Materials, EarlyView.
This study develops a novel sparingly solvating electrolyte for potassium–sulfur batteries, utilizing tetrahydrofuran (THF) to induce an anion‐dominated solvation structure that eases polysulfide shuttling and forms an inorganic‐rich solid–electrolyte interphases (SEI). Dimethyl diselenide (DMDSe) accelerates quasi‐solid‐state transformations, reducing
Tianyu Chen   +5 more
wiley   +1 more source

Molecular Design and Interfacial Functions of Self‐Assembled Monolayers for Perovskite and Tandem Solar Cells

open access: yesAdvanced Energy Materials, EarlyView.
We identify two decisive levers for SAM interfaces: molecular design (carboxylic acid‐based, phosphonic acid, other anchoring chemistries, and polymeric SAMs) and mixing routes (co‐assembly, in situ assembly, pre‐ and post‐treatment). Coordinated tuning of headgroups and assembly pathways optimises energy alignment and film formation, suppresses ...
Jiaxu Zhang, Bochun Kang, Feng Yan
wiley   +1 more source

Silicon‐Based Anodes for Sulfide Solid‐State Batteries: Failure Mechanisms and Multiscale Design Strategies

open access: yesAdvanced Energy Materials, EarlyView.
Silicon anodes in sulfide SSBs face coupled electrochemo‐mechanical failure by interface instability. This review examined recent advances and proposed mitigation strategies via material‐, electrode/interface‐, and cell‐level‐ engineering. We further evaluate scalable synthesis of sulfide SEs.
Murugesan Karuppaiah   +4 more
wiley   +1 more source

Reductive Cleavage of Diarylalkyl Methyl Ethers by Electron Transfer from Alkali Metals

open access: yes, 1994
The reaction mechanism of the reductive cleavage of two model diarylalkyl methyl ethers by electron transfer from alkali metals in tetrahydrofuran has been ...
C. Finà   +5 more
core  

Nickel‐Free Synthesis of Poly(pyrene‐4,5,9,10‐tetraone) for Sodium‐based Batteries: Insights into Electrode Architecture and Reversible Na‐ion Insertion

open access: yesAdvanced Energy Materials, EarlyView.
A nickel‐free and practical synthesis strategy to poly(pyrene tetraone) and its integration with a percolated CNTs/Ketjen Black network enables stable cycling and efficient energy storage in a sodium‐based batteries. This work demonstrates how controlling polymer structure and electrode architecture improves ion transport and mitigates dissolution in ...
Md. Adil   +9 more
wiley   +1 more source

Palladacarboxamide Capping Reagents for Carbon Isotope Labeling and Pharmaceutical Diversification

open access: yesAngewandte Chemie, EarlyView.
Herein, we present a method for carbon isotope labeling of arylamides via the coupling of air‐stable palladium carboxamide complexes and boronic ester/acids. A wide variety of functionalized boronic esters and acids have been coupled with simple palladium carboxamides complexes.
Daniel V. Hoffmann   +8 more
wiley   +2 more sources

Polysulfones: solid organic catalysts for the chemoselective cleavage of methyl-substituted allyl ethers under neutral conditions

open access: yes
The solid polysulfone made of SO2 and methylidenecyclopentane catalyzes the cleavage of methyl-substituted allyl ethers and liberates the corresponding alcohols.LGSASwiss Fed Inst Technol, EPFL, Lab Glycochem & Asymmetr Synth, BCH, CH-1015 Lausanne ...
Ekstrand, M.   +3 more
core   +1 more source

Sputtering Mechanism of an Unsintered Organic–Inorganic Sputtering Target for Perovskite Solar Cells

open access: yesAdvanced Energy Materials, EarlyView.
An unsintered MAPbI3 sputtering target fabricated via a mechanochemical route enables large‐area vacuum deposition of perovskite absorber layers, while revealing an ion–photon coupled decomposition mechanism that governs target erosion and film composition under RF plasma exposure.
Doha Lim   +9 more
wiley   +1 more source

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