Results 171 to 180 of about 64,940 (304)
Advanced Energy Materials, EarlyView.Fluorinated tetraphenylethene (TPE) derivatives were developed as interfacial layers for perovskite solar cells. The optimized TFP‐TPE enhances interfacial compatibility, suppresses molecular aggregation, and improves charge extraction. Devices incorporating TFP‐TPE achieved a record efficiency of 25.29% and outstanding stability under humidity and ...
Xiao‐Xin Gao +13 more
wiley +1 more source
Addressing Bottlenecks to Achieve High‐Energy Sodium‐Ion Cells Using Tin Anodes
Advanced Energy Materials, EarlyView.The challenges in coupling high voltage cathode with Sn‐alloying anode or in anode‐free cell, using glyme based electrolytes to realize high energy Na‐ion cells are reported. Surface protection strategy such as SnO coating on Sn or trapping the parasitic species from poisoning the anode, helps improving the cyclability, with ∼100% capacity retention ...
Parth Desai +11 more
wiley +1 more source
Conversion of trifluoromethyls into esters along with polyether upcycling <i>via</i> cation-transfer-catalyzed C-O/C-F metathesis. [PDF]
Chem SciLi Z, Shi X, Zhang D, Wu Q.
europepmc +1 more source
Advanced Energy Materials, EarlyView.This study develops a novel sparingly solvating electrolyte for potassium–sulfur batteries, utilizing tetrahydrofuran (THF) to induce an anion‐dominated solvation structure that eases polysulfide shuttling and forms an inorganic‐rich solid–electrolyte interphases (SEI). Dimethyl diselenide (DMDSe) accelerates quasi‐solid‐state transformations, reducing
Tianyu Chen +5 more
wiley +1 more source
Isolation and Reactivity of a Square‐Planar Trisamido Silane
Angewandte Chemie, EarlyView.We report the synthesis and comprehensive characterisation of a square‐planar Si(+IV) hydride supported by an unsymmetric, trianionic and dearomatised N,N,N‐pincer ligand. This system enables element–ligand cooperative reactivity as an alternative to silicon‐centred redox chemistry, illuminating a largely unexplored regime in high‐valent silicon ...
David M. J. Krengel +5 more
wiley +2 more sources
Propylene Glycol Ethers: Widespread Use and Missing Neurotoxicity Testing. [PDF]
ToxicsHopf NB, De Luca HP.
europepmc +1 more source
Advanced Energy Materials, EarlyView.We identify two decisive levers for SAM interfaces: molecular design (carboxylic acid‐based, phosphonic acid, other anchoring chemistries, and polymeric SAMs) and mixing routes (co‐assembly, in situ assembly, pre‐ and post‐treatment). Coordinated tuning of headgroups and assembly pathways optimises energy alignment and film formation, suppresses ...
Jiaxu Zhang, Bochun Kang, Feng Yan
wiley +1 more source
Angewandte Chemie, EarlyView.This review highlights recent advances in integrating biocatalysis and chemocatalysis in continuous flow to create streamlined, sustainable processes. It examines chemo‐enzymatic cascades combining at least one enzymatic and one chemical step, discusses challenges such as enzyme immobilization, leaching, and reactor clogging, and presents solutions ...
Petros Siasiaridis +2 more
wiley +2 more sources
Formation of cyclopentanes and cyclopropanes through alkylation of benzylic anions using ethers, thioethers and alcohols as substrates under Grubbs-Stoltz (Et<sub>3</sub>SiH/KO<i>t</i>Bu) conditions. [PDF]
Chem SciStewart AJ +10 more
europepmc +1 more source
Advanced Intelligent Discovery, EarlyView.This work introduces a novel framework for identifying non‐small cell lung cancer biomarkers from hundreds of volatile organic compounds in breath, analyzed via gas chromatography‐mass spectrometry. This method integrates generative data augmentation and multi‐view feature selection, providing a stable and accurate solution for biomarker discovery in ...
Guancheng Ren +10 more
wiley +1 more source