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Nickel(II)-Catalyzed Borylation of Alkenyl Methyl Ethers via C-O Bond Cleavage.

Organic Letters, 2020
A new protocol has been developed for the borylation of conjugated alkenyl methyl ethers using B2Pin2 via C-O bond cleavage catalyzed by Ni(II). In this cross-coupling reaction, both E/Z isomers of alkenyl ethers are converted into (E)-alkenyl boronic ...
Xiaodong Qiu   +6 more
semanticscholar   +1 more source

Synthesis of (+)-Spirolaxine Methyl Ether

The Journal of Organic Chemistry, 2006
A short and efficient synthesis of (+)-spirolaxine methyl ether, a metabolite of the fungus Sporotrichum laxum with inhibitory activity against Helicobacter pylori, is described. The synthesis has been carried out by a Prins cyclization, to obtain the [6,5]-spiroketal system, and a Wadsworth-Emmons condensation, applied for the installation of the ...
R.NANNEI   +4 more
openaire   +4 more sources

Reactions of methylene with ethers. Part 1.—Dimethyl ether, methyl ethyl ether, methyl n-propyl ether, methyl-isopropyl ether, methyl-t-butyl ether and tetrahydrofuran

Trans. Faraday Soc., 1968
The reactions of methylene, produced by the photolysis of both ketene and diazomethane, with a number of simple ethers have been studied. Most of the data obtained refer to the gas phase but some liquid-phase results are also reported. Methylene in its singlet state has been found to insert in the various carbon hydrogen bonds in a near random fashion.
H. M. Frey, M. A. Voisey
openaire   +1 more source

Total synthesis of (±)-shonanyl methyl ether and (±)-ferruginyl methyl ether

Tetrahedron Letters, 1989
Abstract An efficient reductive methylation of the tricyclic ketone 12 in anhydrous ammonia provided the β,γ-unsaturated ketone 15 in high yield which was subsequently converted into (±)-shonanyl methyl ether ( 3 ) and (±)-ferruginyl methyl ether ( 6 ).
Manuka Ghosal   +2 more
openaire   +1 more source

Equations of state for fluorinated ether refrigerants, pentafluoroethyl methyl ether and heptafluoropropyl methyl ether

Fluid Phase Equilibria, 2001
Abstract Thermodynamic properties of two fluorinated ethers, that meet the criteria of the potential new-generation refrigerants with considerably low global warming potential (GWP) and the zero ozone depletion potential (ODP), are studied in the present paper. The recommended candidates are pentafluoroethyl methyl ether, CF 3 CF 2 OCH 3 (245cbEβγ),
Januarius V. Widiatmo, Koichi Watanabe
openaire   +1 more source

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