Bioconversion of Airborne Methylamine by Immobilized Recombinant Amine Oxidase from the Thermotolerant Yeast Hansenula polymorpha [PDF]
Aliphatic amines, including methylamine, are air-pollutants, due to their intensive use in industry and the natural degradation of proteins, amino acids, and other nitrogen-containing compounds in biological samples.
Sasi Sigawi +5 more
doaj +2 more sources
Methylamine plays an important role in the global carbon and nitrogen budget; microorganisms that grow on reduced single carbon compounds, methylotrophs, serve as a major biological sink for methylamine in aerobic environments.
Dipti D. Nayak, Christopher J. Marx
doaj +2 more sources
Triazido[tris(2-pyridyl-κN)methylamine]cobalt(III) [PDF]
The title compound, [Co(N3)3(C16H14N4)], was synthesized by hydrothermal reaction of [Co(NH3)6](NO3)3, NaN3 and tris(2-pyridyl)methylamine. The structure contains two independent complexes in the asymmetric unit, with closely comparable geometry.
Xia Liu, Lujiang Hao
doaj +2 more sources
Background: Methylamine, a natural soluble amine present in foods, is known to be a substrate of primary amine oxidase (PrAO) widely expressed in animal tissues.
Christian Carpéné +6 more
doaj +2 more sources
Electrocatalytic C─C Bond Formation Via Cyanide Interception of CO<sub>2</sub> Reduction Intermediates. [PDF]
ABSTRACT Electrochemical CO2 reduction offers a sustainable route to convert greenhouse gas into high‐value‐added chemicals, yet product distributions remain largely limited to simple C1‐C3 molecules. Here, we report a new reaction in which CO2 reduction intermediates undergo direct C‐C coupling with an external carbon nucleophile under electrochemical
Liu G +10 more
europepmc +2 more sources
Physiology and Evolution of Methylamine Metabolism across Methylobacterium extorquens strains [PDF]
The interplay between physiology and evolution in microorganisms is extremely relevant from the stand-point of human health, the environment, and biotechnology; yet microbial physiology and microbial evolution largely continue to grow as disjoint fields ...
Nayak, Dipti Dinkar
core +6 more sources
H-Bonding-Induced Repulsion Between Small Groups Toward a Highly Puckered Benzene. [PDF]
A benzene derivative bearing methylamino and nitro substituents adopts a boat‐shaped ring conformation. Comparison with four related compounds supports a role for intramolecular hydrogen bonding in constraining substituent orientations and promoting local steric crowding associated with ring puckering.
Zhao C +6 more
europepmc +2 more sources
MILLIMETER/SUBMILLIMETER SPECTROSCOPY OF THE METHYLAMINE PHOTODISSOCIATION PRODUCT AMINOMETHYL RADICAL (·CH₂NH₂) [PDF]
Methylamine (CH₃NH₂) is the simplest primary amine and a precursor of the simplest amino acid, glycine. Therefore, methylamine is a molecule of particular interest in astrochemistry and prebiotic chemistry.
Liang, Haocheng
core +1 more source
Redox-Active Verdazyl Radical Polymers via Postpolymerization Modification of Active Ester Polymers. [PDF]
Organic radical polymers were synthesized via postpolymerization modification (PPM) of poly(pentafluorophenyl (meth)acrylate) with diverse 6‐oxoverdazyl stable radicals. This work servs as an electrochemical proof‐of‐concept, exhibiting a chemically reversible redox couple at 3.43 V versus Li/Li+, validating the electrochemical accessibility of the ...
Ellingsen TA +7 more
europepmc +2 more sources
Rotational Rest Frequencies and First Astronomical Search of Protonated Methylamine
We report first laboratory rest frequencies for rotational transitions of protonated methylamine, CH3NH3+, measured in a cryogenic 22-pole ion trap machine and employing an action spectroscopy scheme.
Philipp C. Schmid +8 more
doaj +1 more source

