Results 31 to 40 of about 4,148 (178)

A Cu‐Based Near‐IR Active MOF with an Ion‐Pair Guest Exhibiting Versatile and Selective Gas‐Solid Reactivity

open access: yesAdvanced Materials, EarlyView.
The new Cu‐containing MOF (Me2NH2)(CuICl2)@[Cu4(INA)4Cl2O]·1.5dmf (3) contains a cation and an anion as guests and shows UV‐near‐mid‐IR absorption and near‐IR emission. MOF 3 shows gas‐solid reactivity in the presence of NH3 and HCOOH to yield two new 3D MOF.
Rajat Saha   +10 more
wiley   +1 more source

Bacterial aerobic methane cycling by the marine sponge-associated microbiome

open access: yesMicrobiome, 2023
Background Methanotrophy by the sponge-hosted microbiome has been mainly reported in the ecological context of deep-sea hydrocarbon seep niches where methane is either produced geothermically or via anaerobic methanogenic archaea inhabiting the sulfate ...
Gustavo A. Ramírez   +7 more
doaj   +1 more source

Systematic Metabolic Engineering and Model‐Guided Optimization for High‐Level Production of L‐Theanine from Xylose in Escherichia coli

open access: yesAdvanced Science, EarlyView.
This study is pioneering in constructing the shortest known synthetic pathway for L‐theanine production from xylose within E coli. Through comprehensive metabolic engineering strategies, our engineered strain achieved the highest reported L‐theanine titer from xylose, with a titer of 95.42 g/L, and a yield of 0.55 g/g.
Haolin Han   +5 more
wiley   +1 more source

The effect of chemical chaperones on the assembly and stability of HIV-1 capsid protein. [PDF]

open access: yesPLoS ONE, 2013
Chemical chaperones are small organic molecules which accumulate in a broad range of organisms in various tissues under different stress conditions and assist in the maintenance of a correct proteostasis under denaturating environments.
Ayala Lampel   +4 more
doaj   +1 more source

Symposium review: Understanding the role of the rumen microbiome in enteric methane mitigation and productivity in dairy cows

open access: yesJournal of Dairy Science, 2022
: Ruminants are one of the largest sources of global CH4 emissions. This enteric CH4 is exclusively produced by methanogenic archaea as a natural product during microbial fermentation in the reticulorumen.
Dipti Pitta   +3 more
doaj   +1 more source

Beyond Cartilage‐Inspired Supramolecular Polyurethane for Adaptive Impact‐Resistant Protection with Robustness, Self‐Healing, and Recyclability

open access: yesAdvanced Science, EarlyView.
Cartilage‐inspired supramolecular polyurethane–urea (PU‐BAMB) elastomers are developed by integrating hierarchical hydrogen bonding and π–π stacking interactions within a dynamically reconfigurable network. This synergistic supramolecular architecture overcomes the intrinsic trade‐off between rigidity and recoverability, imparting exceptional toughness,
Rou‐Han Lai   +14 more
wiley   +1 more source

Oxidation of methylamine

open access: yesInternational Journal of Chemical Kinetics, 2020
AbstractA detailed chemical kinetic model for oxidation of methylamine has been developed, based on theoretical work and a critical evaluation of data from the literature. The rate coefficients for the reactions of CHNH + O CHNH / CHNH + HO, CHNH + H CH + NH, CHNH CHNH, and CHNH + O CHNH + HO were calculated from ab initio theory. The mechanism was
Peter Glarborg   +4 more
openaire   +4 more sources

Asymmetric synthesis of chiral heterobenzylic amines via visible-light-induced enantioselective C(sp3)-H alkylation

open access: yesGreen Synthesis and Catalysis
The chiral heterobenzylic amines, such as α-alkyl substituted chiral oxadiazole methylamine skeletons are widely present in pesticides and pharmaceuticals, due to their unique biological activities.
Yumei Huo   +5 more
doaj   +1 more source

Trimethylamine N-oxide abolishes the chaperone activity of α-casein: an intrinsically disordered protein

open access: yesScientific Reports, 2017
Osmolytes (small molecules that help in circumventing stresses) are known to promote protein folding and prevent aggregation in the case of globular proteins. However, the effect of such osmolytes on the structure and function of intrinsically disordered
Mohd Younus Bhat   +2 more
doaj   +1 more source

Estimating the Lower Limit of the Impact of Amines on Nucleation in the Earth’s Atmosphere

open access: yesEntropy, 2015
Amines, organic derivatives of NH3, are important common trace atmospheric species that can enhance new particle formation in the Earth’s atmosphere under favorable conditions.
Alexey B. Nadykto   +4 more
doaj   +1 more source

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