Results 31 to 40 of about 7,237 (234)

Development and Application of a UPLC–MRM–MS Method for Quantifying Trimethylamine, Trimethylamine-N-Oxide, and Related Metabolites in Individuals with and Without Metabolic Syndrome

open access: yesSeparations
Trimethylamine-N-oxide (TMAO) is associated with various chronic diseases. TMAO is a downstream oxidative metabolite of trimethylamine (TMA) that is generated by the gut microbiota from dietary choline, carnitine, and betaine.
Mohammed E. Hefni, Cornelia M. Witthöft
doaj   +1 more source

Diazo Transfer From Nitrous Oxide Employing Phosphorus Ylides

open access: yesAngewandte Chemie, EarlyView.
A phosphorus ylide‐mediated strategy achieves the direct fixation of nitrous oxide (N2O) to access diazo compounds, which after intra‐ or intermolecular trapping, afford N2‐containing organic building blocks. This approach provides an alternative to hazardous diazo‐transfer reagents and establishes N2O fixation as a sustainable methodology.
Jhen‐Kuei Yu   +4 more
wiley   +2 more sources

Synthesis and Characterization of New Copper(II) Coordination Compounds with Methylammonium Cations

open access: yesInorganics
We synthesized four new copper(II) complexes with acetato and chlorido ligands and methylammonium (MA), dimethylammonium (DMA), and tetramethylammonium (TMA) counterions: (MA)4[Cu2Ac4Cl2]Cl2·2H2O (1), (DMA)2[Cu2Ac4Cl2] (2), (DMA)4[Cu2Ac4Cl2]Cl2·2H2O (3),
Amalija Golobič   +5 more
doaj   +1 more source

Convergent Valorization via Scalable C═N Bond Electrosynthesis Through Metal‐Dopant Interfacial Engineering in a Flow Electrolyzer

open access: yesAngewandte Chemie, EarlyView.
This study establishes an innovative approach to synthesize organonitrogens featuring C═N bonds efficiently using non‐precious metal‐doped MoS2 in a flow electrolyzer. Fe dopant significantly enhances Faradaic efficiency and yield rate, achieving over 81% and 2630 mmol h−1 g−1 for formaldoxime production. This platform upcycles pollutants into valuable
Ruijie Yi   +9 more
wiley   +2 more sources

Phylogenomic Reconstruction and Metabolic Potential of the Genus Aminobacter

open access: yesMicroorganisms, 2021
Bacteria belonging to the genus Aminobacter are metabolically versatile organisms thriving in both natural and anthropized terrestrial environments. To date, the taxonomy of this genus is poorly defined due to the unavailability of the genomic sequence ...
Irene Artuso   +5 more
doaj   +1 more source

Capacity for Cellular Osmoregulation Defines Critical Salinity of Marine Invertebrates at Low Salinity

open access: yesFrontiers in Marine Science, 2022
Low-salinity stress can severely affect the fitness of marine organisms. As desalination has been predicted for many coastal areas with ongoing climate change, it is crucial to gain more insight in mechanisms that constrain salinity acclimation ability ...
Imke Podbielski   +5 more
doaj   +1 more source

On the link between ocean biota emissions, aerosol, and maritime clouds: Airborne, ground, and satellite measurements off the coast of California [PDF]

open access: yes, 2009
Surface, airborne, and satellite measurements over the eastern Pacific Ocean off the coast of California during the period between 2005 and 2007 are used to explore the relationship between ocean chlorophyll a, aerosol, and marine clouds.
Albrecht   +126 more
core   +2 more sources

Reductive functionalization of CO2 with amines: an entry to formamide, formamidine and methylamine derivatives [PDF]

open access: yes, 2015
International audienceCO2 utilization for the production of C1-containing molecules is a desirable route to value-added chemicals. In this perspective, we summarize the recent results devoted to the formation of nitrogen compounds obtained by reductive ...
Blondiaux, Enguerrand   +3 more
core   +3 more sources

Mixed‐Metal Promotion in a Manganese‐Molybdenum Oxynitride as Catalyst to Integrate C─C and C─N Coupling Reactions for the Direct Synthesis of Acetonitrile from Syngas and Ammonia

open access: yesAdvanced Materials, EarlyView.
Transition metal oxy/carbo‐nitrides show great promise as catalysts for sustainable processes. A Mn‐Mo mixed‐metal oxynitride attains remarkable performance for the direct synthesis of acetonitrile, an important commodity chemical, via sequential C─N and C─C coupling from syngas (C1) and ammonia (N1) feedstocks.
M. Elena Martínez‐Monje   +7 more
wiley   +1 more source

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