Results 151 to 160 of about 4,291 (212)
Pyrolysis of methylcyclohexane
Collection of Czechoslovak Chemical Communications, 1987 The kinetics of pyrolysis of methylcyclohexane was investigated from the viewpoint of coke formation in a steel tubular reactor (S/V = 6·65 cm-1) at 0·1 MPa, 700 to 820 °C and residence time 0·01 to 0·24 s. Decomposition of methylcyclohexane proceeds as a first order reaction with a frequency factor 6·31 . 1015 s-1 and activation energy 251·2 kJ mol-1.
Ulrika Králíková +2 more
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Catalysis Today, 2008 8th Europacat Conference -- AUG 26-31, 2007 -- Turku, FINLANDPrevious results on different catalysts revealed that methylcyclohexane underwent selective dehydrogenation to form toluene and hydrogen.
Sevim Yolcular Karaoglu
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Fluid Phase Equilibria, 2002 Equilibrium hydrate formation conditions for methane with methylcyclohexane (MCH), and a ternary gas mixture of methane, ethane, propane with methylcyclohexane are obtained by employing the isothermal pressure search method. Methylcyclohexane is reported
Zhigao Sun, Shuanshi Fan, R Z Wang
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Combustion and Flame, 1997
Abstract High-temperature (1050–1200 K) pyrolysis studies of pure methylcyclohexane (MCH) and oxidation studies of pure MCH and MCH/toluene blends were performed in the Princeton Turbulent Flow Reactor. Since MCH is a proposed endothermic jet fuel, as well as a possibly significant constituent of current commercial automotive and aviation fuel blends,
S. Zeppieri, K. Brezinsky, I. Glassman
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Abstract High-temperature (1050–1200 K) pyrolysis studies of pure methylcyclohexane (MCH) and oxidation studies of pure MCH and MCH/toluene blends were performed in the Princeton Turbulent Flow Reactor. Since MCH is a proposed endothermic jet fuel, as well as a possibly significant constituent of current commercial automotive and aviation fuel blends,
S. Zeppieri, K. Brezinsky, I. Glassman
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Mechanism of Methylcyclohexane Ozonolysis
Russian Journal of Applied Chemistry, 2003A mathematical model of selective oxidation of methylcyclohexane with ozone-oxygen mixtures was substantiated.
A. M. Syroezhko +2 more
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J. Chem. Soc., Faraday Trans. 2, 1984
Measurements of isothermal compressibility, κT, have been carried out for methylcyclohexane + toluene mixtures at 298.15, 318.15, 318.15 and 333.15 K. The results were combined with data for other parameters to obtain isentropic compressibilities and heat capacities at constant volume.
M. Luz Rey +3 more
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Measurements of isothermal compressibility, κT, have been carried out for methylcyclohexane + toluene mixtures at 298.15, 318.15, 318.15 and 333.15 K. The results were combined with data for other parameters to obtain isentropic compressibilities and heat capacities at constant volume.
M. Luz Rey +3 more
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Fluid Phase Equilibria, 2002
Abstract Consistent vapor–liquid equilibria (VLE) at 101.3 kPa has been determined for the ternary system 3-methylpentane+diisopropyl ether (DIPE)+methylcyclohexane and the binary subsystems 3-methylpentane+methylcyclohexane and DIPE+methylcyclohexane in the temperature range from 336 to 374 K.
Sonia Loras, Antonio Aucejo, Rosa Muñoz
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Abstract Consistent vapor–liquid equilibria (VLE) at 101.3 kPa has been determined for the ternary system 3-methylpentane+diisopropyl ether (DIPE)+methylcyclohexane and the binary subsystems 3-methylpentane+methylcyclohexane and DIPE+methylcyclohexane in the temperature range from 336 to 374 K.
Sonia Loras, Antonio Aucejo, Rosa Muñoz
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Conversion of methylcyclohexane to 1-amino-1-methylcyclohexane by trichloramine-aluminum chloride
Tetrahedron, 1967Abstract Methylcyclohexane underwent amination to 1-amino-1-methylcyclohexane on treatment with trichloramine and aluminum chloride. The simple procedure resulted in yields as high as 82% based on trichloramine. Several reaction variables were studied: solvent, temperature, catalyst, and reagent concentration.
P. Kovavic, S.S. Chaudhary
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Chemical shifts in methylcyclohexane
Organic Magnetic Resonance, 1969AbstractIn order to determine the effect of a single methyl group on the chemical shifts of protons in a cyclohexane ring, methylcyclohexane‐1,2,3,3,5,5,‐d6 has been synthesized. The protons in the 4‐position and the 2,6‐equatorial protons are not significantly different from those in ring‐frozen cyclohexane.
Joseph B. Lambert, Yoshinobu Takeuchi
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Unimolecular dissociation of ionized methylcyclohexane
European Journal of Mass Spectrometry, 1998The mass spectrometric fragmentation of methylcyclohexane has been studied with high mass resolution. The use of 25 isotopomers, labeled with 13 C and/or D, allowed the elucidation of different fragmentation mechanisms, but demonstrated also the limits of the method.
Tino Gäumann +3 more
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