Extension of the single-event microkinetic model to alkyl substituted monoaromatics hydrogenation on a Pt catalyst [PDF]
, 2012 The Single-Event Micro Kinetic (SEMK) methodology, which had been successfully applied to benzene hydrogenation on a Pt catalyst, has now been extended toward substituted monoaromatics, that is, toluene and o-xylene.
Bera, Tapan, Marin, Guy, Thybaut, Joris
core +2 more sources
CO-tolerant RuNi/TiO2 catalyst for the storage and purification of crude hydrogen
Nature Communications, 2022 Efficient storage of crude hydrogen, through toluene hydrogenation to methylcyclohexane, is often inhibited by CO impurities. Here, the authors develop a RuNi/TiO2 catalyst which avoids deactivation through promoting simultaneous CO methanation.
Zhaohua Wang +11 more
doaj +1 more source
Pd based Inorganic Hollow Fibre Membranes for H2 Permeation and Methylcyclohexane Dehydrogenation
, 2011 The availability of inorganic membranes which can withstand high temperatures and harsh chemical environments has resulted in a wide range of opportunities for the application of membranes in chemical reactions and separations.
Mohamed Dzahir
openalex +2 more sources
Model arenes hydrogenation with silica-supported rhodium nanoparticles:The role of the silica grains and of the solvent on catalytic activities [PDF]
, 2009 Silica-supported rhodium-based nanoheterogeneous catalysts were easily prepared by impregnation with a pre-stabilized colloidal suspension. The resulting catalysts contain rhodium nanoparticles well-dispersed in the silica pores with a mean size of 5 nm.
Barthe, Laurie +5 more
core +4 more sources
Comparison of Various Column Packing Materials’ Efficiency for Hydrocarbons and Aqueous Mixtures [PDF]
Chemical and Biochemical Engineering Quarterly, 2019 The efficiency of industrial column packings is commonly tested by standard hydrocarbon mixtures. However, a reduced efficiency value is often observed, particularly during distillation of aqueous mixtures.
J. Zbytovský +3 more
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Comparative study on the gas to solution phase solvation free energies of model combustion flue gas compounds (N~2~, O~2~, CO~2~, H~2~O, SO~2~, and CO) in 178 organic solvents using the IEFPCM-UFF, CPCM, and SMD implicit solvent models at the Gaussian-4 (G4) level of theory [PDF]
, 2010 Gas to solution phase Gibbs free energies of solvation at 298.15 K for transfer of six representative combustion flue gas compounds (N~2~, O~2~, CO~2~, H~2~O, SO~2~, and CO) were calculated at the Gaussian-4 (G4) level of theory using the IEFPCM-UFF ...
Kaya Forest, Sierra Rayne
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IUPAC-NIST solubility data series. 81. Hydrocarbons with water and seawater-revised and updated. Part 5. C7 hydrocarbons with water and heavy water [PDF]
, 2005 The mutual solubility and related liquid-liquid equilibria of C7 hydrocarbons with water and heavy water are exhaustively and critically reviewed. Reports of experimental determination of solubility in 23 chemically distinct binary systems that appeared ...
Blazej, K. +12 more
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Separation of Methylcyclohexane-Toluene Mixture Using Imidazolium Ionic Liquids
Chemical Engineering Transactions, 2022 This study aimed to design a process for methylcyclohexane-toluene mixture separation. For the separation of a binary mixture containing 10 mole % of toluene, two imidazolium ionic liquids (ILs) were tested, namely 1-hexyl-3-methylimidazolium ...
Elena Graczová +2 more
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Methyl-Cyclohexane Methanol (MCHM) Isomer-Dependent Binding on Amorphous Carbon Surfaces
Molecules, 2021 In January 2014, over 10,000 gallons of methyl-cyclohexane methanol (MCHM) leaked into the Elk River in West Virginia, in a chemical spill incident that contaminated a large portion of the state’s water supply and left over 300,000 residents without ...
William A. Alexander
doaj +1 more source
Mechanical Engineering Journal, 2017 In this research, we investigated an energy supply system based on hydrogen derived from renewable energy. We modeled the energy flow and efficiency of a system using the MCH-toluene-hydrogen reaction cycle (MTHR) by methylcyclohexane (MCH, C6H11CH3) and
Shin'ya OBARA
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