Results 31 to 40 of about 4,291 (212)

Highly Efficient Deep Blue Luminescence of 2-Coordinate Coinage Metal Complexes Bearing Bulky NHC Benzimidazolyl Carbene

open access: yesFrontiers in Chemistry, 2020
The structural, photophysical and electrochemical properties of three luminescent 2-coordinate coinage metal (i.e., M = Cu, Ag, Au) complexes bearing a sterically bulky benzimidazolyl carbene, 1,3-bis(2,6-diisopropylphenyl)-1-H-benzo[d]imidazol-2-ylidene
Rasha Hamze   +6 more
doaj   +1 more source

Solvent-dependent complex reaction pathways of bromoform revealed by time-resolved X-ray solution scattering and X-ray transient absorption spectroscopy

open access: yesStructural Dynamics, 2019
The photochemical reaction pathways of CHBr3 in solution were unveiled using two complementary X-ray techniques, time-resolved X-ray solution scattering (TRXSS) and X-ray transient absorption spectroscopy, in a wide temporal range from 100 ps to tens of ...
Qingyu Kong   +16 more
doaj   +1 more source

Separation of Isoeugenol from Methylcyclohexane as a Model Mixture of Biojet Fuel Purification: Solvent Selection and Liquid–Liquid Equilibrium

open access: yes, 2023
The biorefinery concept emerged as an opportunity to reduce the negative effects of climate change and as a potential source of products for the fuel industry, where jet fuel produced by hydrodeoxygenation of bio-oil (denominated as biojet fuel) is of ...
Sebastián Ormazábal-Latorre   +19 more
core   +1 more source

Cationic polymerization of β-pinene in the presence of alkylaluminum chlorides as catalysts

open access: yesЖурнал Белорусского государственного университета: Химия, 2020
Cationic polymerization of β-pinene, a naturally occurring monomer, was studied in the presence of different alkylaluminum chlorides ((iBu)3Al2Cl3, Et3Al2Cl3 и Мe2AlCl) in the solvent mixture dichloromethane/methylcyclohexane (DCM/MCH) at –78 °C.
Maksim I. Hulnik   +2 more
doaj   +1 more source

Frustrated Lewis Pairs and Metallic Ni Synergistically Enabled Low‐Temperature Hydrogenolysis of Lignin Models

open access: yesAdvanced Science, EarlyView.
Nickel–aluminum composite oxide (NiAlOx‐300) derived from NiAl layered double hydroxide showed high activity for hydrogenolysis of various lignin models. Especially, hydrogenolysis of benzyl phenyl ether could be efficiently proceeded at 20°C and 1 MPa H2.
Jinpeng Liang   +9 more
wiley   +1 more source

Metal (n+1)p‐nd Orbital Hybridization and Excited‐State Metal–Ligand π‐Interactions Enable d10 Carbene‐Metal‐Amide TADF OLEDs with High Efficiency and Long Operational Lifetime

open access: yesAdvanced Science, EarlyView.
We elucidate the key roles of metal p‐d orbital hybridization, excited‐state metal–ligand π‐interactions, and structural rotation in TADF of d10 CMA complexes. Introducing electron‐withdrawing or π‐extended ligand substituents weakens excited‐state metal‐ligand π‐interactions and improves kTADF, but may compromise emitter stability in device operation.
Shuo Xu   +5 more
wiley   +1 more source

X-ray Diffraction Studies of Liquid Methylcyclohexane $C_6H_{11}-CH_3$ Structure at 293 K

open access: yes, 2008
The structure of methylcyclohexane $C_6H_{11}-CH_3$ at 293 K was investigated using the X-ray diffraction method. An angular distribution of X-ray radiation scattered in liquid methylcyclohexane was measured. The observable range of scattering angles was
Drozdowski, H., Nowakowski, K.
core   +1 more source

Convergent Total Synthesis of 16β‐Hydroxylpseudobufarenogin

open access: yesAngewandte Chemie, Volume 138, Issue 23, 1 June 2026.
We present a novel convergent strategy that integrates Pd/Ag‐promoted Suzuki–Miyaura coupling with Ir‐catalyzed radical‐relay cyclization, enabling the first total synthesis of 16β‐hydroxylpseudobufarenogin. This approach is broadly applicable to the total synthesis of various oxygenated bufadienolides by simply modifying the fragment structures ...
Wataru Shigematsu   +3 more
wiley   +2 more sources

4-Methylcyclohexane methanol (MCHM) affects viability, development, and movement of Xenopus embryos

open access: yesToxicology Reports, 2021
Following chemical spill disasters, it is important to estimate the effects of spilled chemicals on humans and the environment. Here we analyzed the toxicological effects of the coal cleaning chemical, 4-methylcyclohexane methanol (MCHM), which was ...
Mark Perfetto   +4 more
doaj   +1 more source

Beyond Furnaces: Harnessing In Situ Joule Heating for Efficient C1 Catalysis

open access: yesCarbon Energy, EarlyView.
Joule‐heated catalysis directly converts electrical energy into localized heat within conductive catalysts, overcoming the heat‐transfer limitations of conventional furnaces. This review summarizes recent advances in C1 molecule conversion, including CO2 methanation, reforming for hydrogen production, and HCHO/CO oxidation, while highlighting ...
Xue Kong   +8 more
wiley   +1 more source

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