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Chiral Micellar Electrokinetic Chromatography [PDF]

open access: yesJournal of Chromatography A, 2020
The potential of Micellar Electrokinetic Chromatography to achieve enantiomeric separations is reviewed in this article. The separation principles and the most frequently employed separation strategies to achieve chiral separations by Micellar ...
Sandra Salido-Fortuna   +2 more
exaly   +4 more sources

Microemulsion Electrokinetic Chromatography – Or Solvent-Modified Micellar Electrokinetic Chromatography?

open access: yesTrAC - Trends in Analytical Chemistry, 2001
An overview of the microemulsion electrokinetic chromatography technique and its fields of applications in analytical chemistry are given. The separation mechanisms involved are discussed and the technique is compared to solvent-modified micellar ...
Stig Pedersen-Bjergaard   +1 more
exaly   +4 more sources
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Characterisation of Retention in Micellar High-Performance Liquid Chromatography, in Micellar Electrokinetic Chromatography and in Micellar Electrokinetic Chromatography With Reduced Flow

Journal of Chromatography A, 2001
The retention (migration) behaviour of various barbiturates, phenylurea and triazine herbicides in micellar electrokinetic chromatography (MEKC) with uncoated fused-silica capillaries was compared with the behaviour in micellar electrokinetic chromatography with reduced electroosmotic flow (RF-MEKC) using capillaries modified with linear polyacrylamide.
Pavel Jandera
exaly   +3 more sources

Micellar Electrokinetic Chromatography

Bulletin of the Chemical Society of Japan, 1998
Abstract A review of the research on micellar electrokinetic chromatography (MEKC), carried out mainly in our laboratory, is described from the viewpoints of (1) fundamental characteristics of MEKC, such as the separation principle, chromatographic parameters, selectivity and resolution, thermodynamic parameters, retention index, and ...
K, Otsuka, S, Terabe
openaire   +3 more sources

Recent Advances in Micellar Electrokinetic Chromatography

Electrophoresis, 2005
AbstractThis review contains nearly 200 reference citations, and covers advances in electrokinetic capillary chromatography based on micelles, including stabilized micelle complexes, polymeric and mixed micelles from 2003–2004. Detection strategies, analyte determinations, and applications in micellar electrokinetic capillary chromatography (MEKC) are ...
Lisa A Holland, Melissa Gayton-Ely
exaly   +3 more sources

Micellar electrokinetic chromatography on microchips

Journal of Separation Science, 2008
AbstractThis review highlights the methodological and instrumental developments in microchip micellar EKC (MCMEKC) from 1995. The combination of higher separation efficiencies in micellar EKC (MEKC) with high‐speed separation in microchip electrophoresis (MCE) should provide high‐throughput and high‐performance analytical systems.
Kitagawa, Fumihiko, Otsuka, Koji
openaire   +2 more sources

Determination of benzodiazepines by micellar electrokinetic chromatography

ELECTROPHORESIS, 1994
AbstractA method for the separation and determination of benzodiazepines by micellar electrokinetic chromatography (MEKC) has been developed. Separation buffers consisted of aqueous solutions of glycine and triethanolamine (pH 9.0), containing sodium dodecyl sulfate (SDS) as surfactant and methanol as organic modifier.
Bechet, I.   +3 more
openaire   +3 more sources

Micellar Electrokinetic Chromatography

2018
Micellar electrokinetic chromatography (MEKC) is a mode of capillary electrophoresis that allows for the separation of neutral molecules in an electric field. Typically, neutral molecules move with electroosmotic flow (EOF) or bulk flow during electrophoretic separations resulting in no temporal resolution between mixtures of neutral analytes ...
Braden C, Giordano   +2 more
openaire   +2 more sources

Micellar Electrokinetic Chromatography of Aminoglycosides

2008
The components of the aminoglycosides, e.g., gentamicin, sisomicin, netilmicin, kanamycin, amikacin, and tobramycin, and related impurities of these antibiotics can be separated by means of micellar electrokinetic chromatography (MEKC). Derivatization with o-phthaldialdehyde and thioglycolic acid is found to be appropriate for all antibiotics.
Ulrike, Holzgrabe   +2 more
openaire   +3 more sources

Microemulsion and micellar electrokinetic chromatography of steroids

Journal of Chromatography B: Biomedical Sciences and Applications, 1996
A mixture of ten steroids was separated by microemulsion and micellar (SDS and glycodeoxycholate) electrokinetic chromatography systems. Separations were done on a 50 cm (to the detector) x 50 microns I.D. fused-silica capillary. Complete separation of all the test compounds in the micellar mode was obtained with glycodeoxycholate (50 mM) in 25 mM ...
L, Vomastová, I, Miksík, Z, Deyl
openaire   +2 more sources

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