Results 101 to 110 of about 2,728 (198)

Supramolecular Assembly of an Antimicrobial Peptide Into a Pore

open access: yesAngewandte Chemie, EarlyView.
Supramolecular assembly of an AMP is linked to transport across the Staphylococcus aureus membrane. ABSTRACT Antimicrobial peptides (AMPs) have long been ascribed the ability to form pores. These structures, some observed, others inferred, vary in their mechanisms of action, though most are associated with lysis.
Kathyana Deeyagahage   +3 more
wiley   +2 more sources

Data‐Guided Photocatalysis: Supervised Machine Learning in Water Splitting and CO2 Conversion

open access: yesAdvanced Intelligent Discovery, EarlyView.
This review highlights recent advances in supervised machine learning (ML) for photocatalysis, emphasizing methods to optimize photocatalyst properties and design materials for solar‐driven water splitting and CO2 reduction. Key applications, challenges, and future directions are discussed, offering a practical framework for integrating ML into the ...
Paul Rossener Regonia   +1 more
wiley   +1 more source

Hydration‐Gated Photoinduced Electron Transfer in BODIPY Dyes

open access: yesAngewandte Chemie, EarlyView.
Hydration switches photoinduced electron transfer (PET) ON in alkoxy‐coordinated BODIPY dyes via specific hydrogen bonding. This gating yields a fluorescence lifetime span of ∼6 ns, enabling fluorescence lifetime imaging microscopy (FLIM) contrast in live cells and organoids. ABSTRACT Fluorescent probes based on photoinduced electron transfer (PET) are
Venkata N. K. Mamillapalli   +9 more
wiley   +2 more sources

Robot‐Assisted Measurement of the Critical Micelle Concentration

open access: yesAdvanced Intelligent Systems, Volume 7, Issue 3, March 2025.
The study introduces (SIMO) smart integrator for manual operations, a robotic platform for precise, repeatable determination of (CMC) critical micelle concentration in surfactants. SIMO reduces standard deviation by 80% compared to manual methods. Surfactant, dye, and diluent selection, robotic protocols, and data handling are detailed.
Vincenzo Scamarcio   +3 more
wiley   +1 more source

Non‐Covalent PL, CD, and CPL Activation of Linear Aromatic Oligomers within Axially Chiral Aromatic Capsules

open access: yesAngewandte Chemie, EarlyView.
Linear aromatic oligomers display intense photoluminescence (PL), circular dichroism (CD), and circularly polarized luminescence (CPL) properties upon non‐covalent encapsulation by axially‐chiral aromatic capsules under ambient aqueous conditions.
Yoshihisa Hashimoto   +4 more
wiley   +2 more sources

pH‐Responsive Ultrasmall Iron Oxide Nanoassemblies for Activatable T2/T1 Magnetic Resonance Imaging

open access: yesAdvanced NanoBiomed Research, EarlyView.
This research reports a pH‐responsive ultrasmall iron oxide nanoparticle (USIONs)/polymer nanoassemblies for activatable magnetic resonance imaging. Amphiphilic diphosphonic acid block copolymers compactly encapsulate USIONs to generate T2‐weighted contrast at physiological pH, while acidic conditions trigger disassembly, activating T1‐weighted ...
Xumin Huang   +11 more
wiley   +1 more source

Remote Electrostatic Effect between Octahedral Ru/Ir‐Complexes and Aromatic Micelles to Improve Their Photofunctions in Water

open access: yesAngewandte Chemie, EarlyView.
The aqueous‐state encapsulation of cationic Ru(II)/Ir(III)‐complexes is efficiently demonstrated by anionic aromatic micelles via remote electrostatic interactions. The resulting host–guest composites exhibit enhanced metal‐complex‐based emission (∼3 to 10‐fold) and NIR emission through guest‐to‐guest FRET upon co‐encapsulation.
Rina Morooka   +2 more
wiley   +2 more sources

Diblock Copolymer Nanoparticles Act as Nanoreactors for the Synthesis of Sterically‐Stabilized Inorganic Oxide Particles in Non‐polar Media

open access: yesAngewandte Chemie, EarlyView.
Poly(lauryl methacrylate)‐poly(2‐hydroxyethyl methacrylate) (PLMA‐PHEMA) diblock copolymer nanoparticles prepared in non‐polar media serve as nanoreactors for the in situ synthesis of silica from tetraethyl orthosilicate (TEOS). A silica mass loading of 17% as judged by thermogravimetric analysis (TGA) produces a highly transparent dispersion, and ...
Priyanka Chohan   +6 more
wiley   +2 more sources

Anion–π Interaction‐Regulated Ion Generation and High Piezoionic Response in Ultrasoft Low‐Salinity Hydrogels

open access: yesAngewandte Chemie, EarlyView.
The first hydrogel system employing anion–π interactions as a central design motif is developed. The cooperative aromatic–phosphate interaction motif provides dynamic cohesion and is proposed to regulate the separation and transport of water‐derived ionic species, achieving high piezoionic response in injectable, self‐healing, ultrasoft, low‐salinity ...
Jinyang Jiang   +11 more
wiley   +2 more sources

Coarse‐Grained Simulations Rationalize Thermosensitivity and Hydrolytic Degradation of Vinyl Copolymers Obtained by Radical Ring‐Opening Polymerization

open access: yesAngewandte Chemie, EarlyView.
Coarse‐grained (CG) molecular dynamics simulations were used to predict the upper critical solution temperature of copolymers obtained by radical ring‐opening copolymerization of cyclic ketene acetals and vinyl monomers, and to account for their unique degradation kinetics under physiological conditions by evaluating the solvation of their ester groups.
Ping Gao   +3 more
wiley   +2 more sources

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