Results 281 to 290 of about 1,254,363 (318)

The Ratio of sp2 and sp3 Hybridized Carbon Determines the Performance of Carbon‐based Catalysts in H2O2 Electrosynthesis from O2

open access: yesAngewandte Chemie, Volume 137, Issue 16, April 11, 2025.
In the field of two‐electron oxygen reduction reaction, carbon‐based catalysts are widely adopted. Our statistical analysis connivingly reveals that the ratio of sp2 to sp3 hybridized carbon, rather than the widely believed oxygen functional groups, is the key structural property determining the catalytic performance.
Dayu Zhu   +4 more
wiley   +2 more sources

Observations of comets, minor planets, and Jupiter VI H

open access: bronze, 1966
Elizabeth Roemer   +2 more
openalex   +1 more source

Structures of Polyhydroxyalkanoate Synthase PhaC from Aeromonas caviae, Producing Biodegradable Plastics

open access: yesAngewandte Chemie, EarlyView.
PHA synthase (PhaC) is the key enzyme in the polymerization of a biodegradable plastic—polyhydroxyalkanoate (PHA). Structures of full‐length PhaC reveal three key regions essential for substrate specificity and polymerization. Additionally, this study also highlights the critical role of N‐domain‐dependent dimerization in PhaC activity.
Min Fey Chek   +5 more
wiley   +1 more source

Facile N═N Bond Cleavage of Cis‐Azobenzene with Bis‐silylenes

open access: yesAngewandte Chemie, EarlyView.
The unexpectedly easy N═N bond scission of cis‐azobenzene using two bis‐silylenes with different spacers and distinct SiII···SiII distances is reported. While both bis‐silylenes enable C─H and N═N π‐bond activation of trans‐azobenzene, the cooperative disilicon(II)‐mediated activation of cis‐azobenzene leads to bis‐silamines (Si═N) and related novel ...
Yun Xiong, Shenglai Yao, Matthias Driess
wiley   +1 more source

An Authentic Al=Si Double Bond

open access: yesAngewandte Chemie International Edition, Volume 64, Issue 16, April 11, 2025.
We report the first example of a bona fide Al=Si double bond stabilized in a four‐membered anionic AlSi3 cycle, which exhibits an unprecedentedly short Al−Si bond length of 2.283(1) Å and a high Wiberg bond index (WBI) of 1.31. We illustrate the typical double bond reactivity through the intramolecular activation of C−H bonds of the Tip group (Tip=2,4 ...
Nasrina Parvin   +3 more
wiley   +1 more source

On the Nomenclature of the Minor Planets [PDF]

open access: yesMonthly Notices of the Royal Astronomical Society
openaire   +2 more sources

Data‐Driven Review on Aerogels and Polymeric Aerogels

open access: yesAngewandte Chemie International Edition, Accepted Article.
Thoroughly data‐driven review on chemistry–properties–applications of aerogels is provided. Aerogel is a category of solid materials having homogeneous, highly porous nanostructures. Unique physicochemical properties of aerogels have attracted much attention in wide fields due to their potentials for energy/environmental issues in the 21st century ...
Satoru Takeshita   +2 more
wiley   +1 more source

A Joyful Journey: Tungsten(VI) and Tungsten(V) Fluorides Meet N‐Heterocyclic Carbenes and Cyclic (Alkyl)(Amino)Carbenes

open access: yesAngewandte Chemie International Edition, EarlyView.
The first tungsten(VI) fluoride complexes coordinated with N‐heterocyclic carbenes and cyclic (alkyl)(amino) carbenes were synthesized and characterized. Reduction of these seven‐coordinated complexes afforded rare octahedral tungsten(V) fluoride complexes, a dinuclear fluoride‐bridged complex (cAACMe), or a seven‐coordinated (cAACMe) bis‐carbene ...
Melanie Riethmann   +7 more
wiley   +1 more source

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