Results 21 to 30 of about 78,321 (222)

A DFT Study on Adsorption of SF₆ Decomposition Products on Zr-MOF-808

Chemosensors, 2023
Identifying the main byproducts of SF6 decomposition proves to be an effective strategy for determining the nature and severity of internal discharge faults in gas-insulated switchgears (GISs).
Tianxiang Lei, Fangcheng Lv, Bowen Jiang
doaj   +2 more sources

Unveiling MOF-808 photocycle and its interaction with luminescent guests

Physical Chemistry Chemical Physics
The world of metal–organic frameworks (MOFs) has become a hot topic in recent years due to the extreme variety and tunability of their structures. There is evidence of MOFs that exhibit intrinsic luminescence properties that arise directly from their ...
Emmanuel Marin, Russel Edward Morris, Gianpiero Buscarino, Vincenzo De Michele, Ludovico Giuseppe Barbata, Romy Ettlinger, Alice Sciortino, Marco Cannas, Giuseppe FIcarra   +8 more
core   +4 more sources

Functionalisation of the MOF-808 framework as a versatile catalyst for fine chemicals synthesis [PDF]

MOFs, particularly MOF-808 are potentially greener and more sustainable catalysts for synthetically useful reactions due to their chemical versatility. MOF-808 can be tuned into a bifunctional catalyst due to the ease with which its formate ligands can ...
Ndlovu, Soneni
core   +3 more sources

Influence of Charge Compensating Anions on the Adsorption of Perfluorobutanesulfonate in MOF-808. [PDF]

ACS Omega
Per- and poly fluoroalkyl substances (aka PFAS) are a class of anthropogenic compounds that have come under scrutiny given their ability to bioaccumulate in the environment and negatively impact health outcomes. Metal-organic frameworks (MOFs) are an emerging category of sorbents that are attractive for PFAS remediation given their readily modifiable ...
Mikel J, Berens B, Versnik G, Wadzinski K, Rottiger T, Siewert M, Stellpflug O, Riha SC, Mondloch JE.   +8 more
europepmc   +3 more sources

Tuning the Properties of MOF-808 via Defect Engineering and Metal Nanoparticle Encapsulation. [PDF]

Chemistry, 2021
AbstractDefect engineering and metal encapsulation are considered as valuable approaches to fine‐tune the reactivity of metal–organic frameworks. In this work, various MOF‐808 (Zr) samples are synthesized and characterized with the final aim to understand how defects and/or platinum nanoparticle encapsulation act on the intrinsic and reactive ...
Hardian R, Dissegna S, Ullrich A, Llewellyn PL, Coulet MV, Fischer RA.   +5 more
europepmc   +6 more sources

Cu‐MOF‐808 as a Sensing Material for Gaseous Hydrogen Sulfide

ChemPlusChem, 2023
AbstractThe selective detection of hydrogen sulfide (H2S) is an important task because of its potentially hazardous effects not only on the environment but also on human health. Here, we present the zirconium‐based MOF‐808, which was modified with copper salts, as a colorimetric sensor material for the visible, reversible and sensitive H2S detection at
Nele Marquardt, Melina Dahlke, Andreas Schaate   +2 more
openaire   +2 more sources

Multifunctional Fe-Doped MOF-808 Nanocomposites for Chemo/Chemodynamic Synergistic Therapy. [PDF]

Small
Abstract Theranostic nanomedicines combining targeted drug delivery and emerging therapeutic modalities with diagnosis are a rapidly evolving field in cancer therapy. In addition to conventional drug delivery, metal–organic frameworks (MOFs), consisting of metal ions/clusters and multitopic organic ligands, have been recently ...
Wang Y, Pan Y, Sproules S, Liu J, Forgan RS.   +4 more
europepmc   +4 more sources

Novel MOF-808 metal-organic framework as highly efficient adsorbent of perfluorooctane sulfonate in water

, 2022
Perfluorooctane sulfonate (PFOS) is a highly persistent contaminant of emerging concern causing harmful effects to human and ecosystem health. In this study, a novel MOF-808 metal-organic framework (MOF) was prepared and evaluated for adsorptive removal ...
Tzou, Yu-Min, Chen, Chien-Yen, Mukhopadhyay, Raj, Chang, Po-Hsiang, Sarkar, Binoy, Chen, Wenhua   +5 more
core   +5 more sources

Thermodynamics of alkali metal ion uptake from aqueous solution in MOF-808. [PDF]

Chem Sci
Molecular mechanisms governing alkali metal ion uptake from aqueous solution in MOF-808 are studied via free-energy calculations and enhanced sampling simulations, revealing the subtle interplay between hydration structure and confinement effects.
Pan Y, Saha S, Burigana M, Singh V, Yaghi OM, Paesani F.   +5 more
europepmc   +3 more sources

Degradation of Glyphosate to Benign N-Formyl Glycine Using MOF-808 Nanocrystals. [PDF]

Angew Chem Int Ed Engl
AbstractGlyphosate (N‐phosphonomethyl glycine, GPh) is an industrial herbicide used worldwide in modern agricultural practices. With the growing concerns regarding cumulative environmental and health effects, pathways for catalytic GPh degradation to benign products are becoming a pressing societal need.
Prada JAP, Navarro TAH, Chua SL, Granados AM, Pao CW, Fracaroli AM, Bedford NM.   +6 more
europepmc   +5 more sources