On the intrinsic dynamic nature of the rigid UiO-66 metal-organic framework [PDF]
UiO-66 is a showcase example of an extremely stable metal-organic framework, which maintains its structural integrity during activation processes such as linker exchange and dehydration.
Caratelli, Chiara+6 more
core +2 more sources
Halogen Bonding in Sulphonamide Co-Crystals: X···π Preferred over X···O/N?
Sulphonamides have been one of the major pharmaceutical compound classes since their introduction in the 1930s. Co-crystallisation of sulphonamides with halogen bonding (XB) might lead to a new class of pharmaceutical-relevant co-crystals. We present the
Tobias Heinen+3 more
doaj +1 more source
Bi- and tri-dentate imino-based iron and cobalt pre-catalysts for ethylene oligo-/polymerization [PDF]
Recent progress on the use of iron and cobalt complex pre-catalysts for ethylene reactivity is reviewed. The review is organized in terms of the denticity of the chelate ligands employed, with particular reference to the influence of the ligand ...
Feng, Chun+6 more
core +1 more source
The Extraction of Community Structures from Publication Networks to Support Ethnographic Observations of Field Differences in Scientific Communication [PDF]
The scientific community of researchers in a research specialty is an important unit of analysis for understanding the field specific shaping of scientific communication practices. These scientific communities are, however, a challenging unit of analysis
Baus+52 more
core +2 more sources
Evolution of the Immunoglobulin Isotypes—Variations of Biophysical Properties among Animal Classes
The adaptive immune system arose around 500 million years ago in jawed fish, and, since then, it has mediated the immune defense against pathogens in all vertebrates.
Nancy D. Pomarici+4 more
doaj +1 more source
Synthesis and characterization of hybrid organic-inorganic materials based on sulphonated polyamideimide and silica [PDF]
The preparation of hybrid organic–inorganic membrane materials based on a sulphonated polyamideimide resin and silica filler has been studied. The method allows the sol–gel process to proceed in the presence of a high molecular weight polyamideimide,
Anita Hill+26 more
core +1 more source
Impact of peanut shells, olive pomace, and plaster on the dielectric properties of PA6
Polyamide 6 (PA6) is among the most widely used technical polymers due to its excellent balance between performance and cost. The diversity of its applications reflects its main qualities (good mechanical properties, thermal stability, resistance to many
O. Oulidi+7 more
doaj +1 more source
Synthesis of Alkaline Earth Diazenides MAEN2 (MAE = Ca, Sr, Ba) by Controlled Thermal Decomposition of Azides under High Pressure [PDF]
The alkaline earth diazenides MAEN2 with MAE = Ca, Sr and Ba were synthesized by a novel synthetic approach, namely, a controlled decomposition of the corresponding azides in a multianvil press at highpressure/ high-temperature conditions.
Andersen O. K.+48 more
core +1 more source
Smart Ligands for Efficient 3d-, 4d- and 5d-Metal Single-Molecule Magnets and Single-Ion Magnets
There has been a renaissance in the interdisciplinary field of Molecular Magnetism since ~2000, due to the discovery of the impressive properties and potential applications of d- and f-metal Single-Molecule Magnets (SMMs) and Single-Ion Magnets (SIMs) or
Panagiota S. Perlepe+4 more
doaj +1 more source
Functionalisation of colloidal transition metal sulphides nanocrystals: A fascinating and challenging playground for the chemist [PDF]
Metal sulphides, and in particular transition metal sulphide colloids, are a broad, versatile and exciting class of inorganic compounds which deserve growing interest and attention ascribable to the functional properties that many of them display.
Dengo, Nicola+2 more
core +1 more source