Results 21 to 30 of about 428 (111)

Synthesis of Geminal Bis‐ and Tetrakisphosphonate Ester Derivatives and Their Coordination Behavior Towards Ca(II) Ions

open access: yesEuropean Journal of Inorganic Chemistry, Volume 2022, Issue 17, June 17, 2022., 2022
Geminal Bisphosphonate (BP) Esters in Ca(II) Ion Coordination. A series of geminal BPs was prepared starting from their corresponding ethyl‐ or isopropyl (arylmethylene)phosphonate ester precursors. Complexation with CaCl2 yields the derived coordination compounds [Ca(H2O)2(L1–L3)2]Cl2 or [Ca(L8)Cl2]n.
Ingo Koehne, Rudolf Pietschnig
wiley   +1 more source

The Pivotal Role of s‐, p‐, and f‐Block Metals in Water Electrolysis: Status Quo and Perspectives

open access: yesAdvanced Materials, Volume 34, Issue 18, May 5, 2022., 2022
This review pioneeringly presents the unique and essential role of some s‐, p‐, and f‐block metal species enabling transition metal‐based electrocatalysts to efficiently drive hydrogen evolution and oxygen evolution reaction. Abstract Transition metals, in particular noble metals, are the most common species in metal‐mediated water electrolysis because
Ziliang Chen   +4 more
wiley   +1 more source

Tracing the Jahn‐Teller Distortion of C60n− in Isostructural Fullerides [M(NH3)7]C60 ⋅ NH3, M=Ba, Sr, K

open access: yesZeitschrift für anorganische und allgemeine Chemie, Volume 647, Issue 11, Page 1132-1138, June 11, 2021., 2021
Abstract Single crystals of new [Sr(NH3)7]C60 ⋅ NH3 (compound 1) and [K(NH3)7]C60 ⋅ NH3 (compound 2) were prepared by extracting mixtures of potassium and C60 with liquid ammonia, where for the synthesis of 1 solid strontium chloride was added to the extraction mixture.
Jörg Daniels   +2 more
wiley   +1 more source

Ternary erbium chromium sulfides : structural relationships and magnetic properties [PDF]

open access: yes, 2009
Single crystals of four erbium-chromium sulfides have been grown by chemical vapor transport using iodine as the transporting agent. Single-crystal X-ray diffraction reveals that in Er(3)CrS(6) octahedral sites are occupied exclusively by Cr(3+) cations,
Adolphe C.   +40 more
core   +1 more source

New Crystal Structures of Rare‐Earth Metal(III) Oxotellurates(IV) RE2Te3O9: A1‐Type (RE=La, Ce) and A2‐Type (RE=Pr, Nd)

open access: yesZeitschrift für anorganische und allgemeine Chemie, Volume 647, Issue 2-3, Page 134-150, February 11, 2021., 2021
Abstract The new rare‐earth metal(III) oxotellurates(IV) RE2Te3O9 (RE=La−Nd) of the so far unknown A‐type structure can be obtained as needle‐shaped single crystals through solid‐state reactions of the corresponding binary oxides. Their crystal structures were determined as A1‐type for RE=La and Ce or A2‐type for RE=Pr and Nd by single‐crystal X‐ray ...
Sheng‐Chun Chou   +4 more
wiley   +1 more source

Structural classification of quasi-one-dimensional ternary nitrides [PDF]

open access: yes, 2016
This review focuses on the crystal structural features of ternary (mixed-metal) quasi-one-dimensional nitrides i.e., nitrides containing (cation-³⁻) coordination polyhedra sharing either corners, edges, or faces, arranged in linear chains, and ...
Francesconi, Maria Grazia   +2 more
core   +1 more source

Co-ordination behaviour of a novel tristhiourea tripodal ligand; structural variations in a series of transition metal complexes [PDF]

open access: yes, 2016
The co-ordination chemistry of a tristhiourea tris(2-pyridylmethyl)amine ligand (L1) with a series of transition metal ions has been investigated. Crystallographic data show that large metal ions, with no geometrical preferences , such as Mn(II) and Cd ...
Amoroso, Angelo James   +3 more
core   +1 more source

[2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN2)-1,10-phenanthroline-κ2N,N′]bis(nitrito-κ2O,O′)cadmium(II)

open access: yesActa Crystallographica Section E, 2010
In the title complex, [Cd(NO2)2(C17H14N4)], the CdII ion assumes a distorted monocapped octahedral coordination geometry defined by an N3O4 donor set. The crystal structure is stabilized by π–π stacking interactions [shortest ...
Jing Min Shi, Lin Meng, Yu Qing Wang
doaj   +1 more source

Cadmium—1,4-cyclohexanedicarboxylato coordination polymers bearing different di-alkyl-2,2’-bipyridines: syntheses, crystal structures and photoluminescence studies [PDF]

open access: yes, 2017
Cadmium–1,4-cyclohexanedicarboxylato coordination polymers bearing different di-alkyl-2,2′-bipyridines: syntheses, crystal structures and photoluminescence studiesFour coordination polymers have been synthesized using self-assembly solution reactions ...
Sánchez Mendieta, Víctor   +1 more
core   +1 more source

Home - About - Disclaimer - Privacy