Results 31 to 40 of about 428 (111)
Manganese(II) pyrimidine-4,6-dicarboxylates: Synthetic, structural, magnetic and adsorption insights into the system [PDF]
A series of manganese(II) coordination polymers containing the bridging ligand pyrimidine-4,6-dicarboxylate (pmdc) have been prepared. The stoichiometries and structural features of these materials, which range from the one-dimensional (1D) chains in ...
Beobide, Garikoitz+7 more
core +1 more source
Crystal Structure of FePb 4 Sb 6 Se 14 and its Structural Relationship with FePb 3 Sb 4 Se 10 [PDF]
Single crystals of FePb 4 Sb 6 Se 14 , were obtained from solid‐state combination of high purity elemental powders at 873K for three days. Single crystal X‐ray structure determination revealed that the compound crystallizes in the monoclinic space group
Djieutedjeu, Honore+2 more
core +1 more source
Li2Eu3Br2[BO3]2 : a new europium(II) halide oxoborate with yellow luminescence [PDF]
The europium(II) oxoborate Li2Eu3Br2[BO3]2 featuring lithium and bromide ions was synthesized by the reaction of Eu2O3 with Li[BH4] as lithium‐ and boron‐ as well as EuBr3 as bromide‐source at 750 °C for 24 h in silica‐jacketed sealed niobium capsules ...
Blaschkowski, Björn+3 more
core +1 more source
Structural chemistry of metal coordination complexes at high pressure [PDF]
The application of pressures of up to about 10 GPa may induce significant geometric, configurational, conformational and packing changes in molecular solids.
Adams+103 more
core +1 more source
Li2Eu3Br2[BO3]2: A New Europium(II) Halide Oxoborate with Yellow Luminescence
The europium(II) oxoborate Li2Eu3Br2[BO3]2 featuring lithium and bromide ions was synthesized by the reaction of Eu2O3 with Li[BH4] as lithium‐ and boron‐ as well as EuBr3 as bromide‐source at 750 °C for 24 h in silica‐jacketed sealed niobium capsules.
Jean‐Louis Hoslauer+3 more
wiley +1 more source
A capped octahedral MHC6 compound of a platinum group metal [PDF]
A MHC6 complex of a platinum group metal with a capped octahedral arrangement of donor atoms around the metal center has been characterized. This osmium compound OsH{κ2-C,C-(PhBIm-C6H4)}3, which reacts with HBF4 to afford the 14 e− species [Os{κ2-C,C ...
Acharyya+50 more
core +1 more source
Enlighten me! The unprecedented borate hydride (deuteride) Sr5(BO3)3H (Sr5(BO3)3D) is synthesized mechanochemically and its structure is determined by neutron diffraction. DFT calculations, NMR, IR, and Raman measurements unambiguously confirm the successful synthesis. An orange‐red phosphor is obtained upon doping with Eu2+. Abstract The unprecedented
Thomas Wylezich+7 more
wiley +1 more source
Crystal structures of two mononuclear complexes of terbium(III) nitrate with the tripodal alcohol 1,1,1-tris(hydroxymethyl)propane [PDF]
Two new mononuclear cationic complexes in which the TbIII ion is bis-chelated by the tripodal alcohol 1,1,1-tris(hydroxymethyl)propane (H3LEt, C6H14O3) were prepared from Tb(NO3)3·5H2O and had their crystal and molecular structures solved by single ...
Accorsi+27 more
core +3 more sources
The ligand exchange between cyanide and hydroxide in hexacyanochromate negolyte was caused by the disruption of coordination environment of the redox mediator ([Cr(CN)6]4‐/3−), with a critical factor as an elevated pH during electrochemical cycle. To mitigate this electrolyte co‐modulation strategy is introduced, optimizing the [OH−]/[CN−] ratios ...
Ji‐Eun Jang+7 more
wiley +1 more source
During synthesis of nitridogermanates, oxygen and carbon impurities lead to a variety of novel compounds—comprising carbodiimides and oxides—significantly expanding the chemistry of this compound class. Various novel compounds have been encountered by serendipity, due to small oxygen or carbon impurities, during the explorative studies to explore the ...
Lukas Link, Rainer Niewa
wiley +1 more source