Results 31 to 40 of about 439 (110)

Ag12[Ge9(Hyp)2]6 An Intermetalloid Cluster with Bis‐Silylated Ge9 Units

Angewandte Chemie, Volume 138, Issue 4, 22 January 2026.
The reaction of K2Ge9(Hyp)2 (Hyp = Si(SiMe3)3) with phosphine stabilized silver halides gives the new intermetalloid cluster Ag12[Ge9(Hyp)2]6 exhibiting a novel Ag12 core surrounded by six [Ge9(Hyp)2] units acting as ligands. Within the Ag12 core two different kinds of silver atoms are present underlining the intermetalloid character of the cluster ...
Kevin Woern, Claudio Schrenk, Eric Juratti, Andreas Schnepf   +3 more
wiley   +2 more sources

A capped octahedral MHC6 compound of a platinum group metal [PDF]

, 2016
A MHC6 complex of a platinum group metal with a capped octahedral arrangement of donor atoms around the metal center has been characterized. This osmium compound OsH{κ2-C,C-(PhBIm-C6H4)}3, which reacts with HBF4 to afford the 14 e− species [Os{κ2-C,C ...
Acharyya, Alabau, Appelhans, Baratta, Baratta, Barybin, Bautista, Baya, Bayse, Berlin, Bolaño, Bolaño, Brant, Casanova, Casarrubios, Castro-Rodrigo, Cooper, Crabtree, Crespo, Dewan, Dewan, Douglas, Eguillor, Eguillor, Eguillor, Esteruelas, Esteruelas, Gross, Gründemann, Gupta, Herrmann, Hlatky, Huang, LaRue, Lewis, Li, Luther, Maltby, Minyaev, Pfennig, Roessler, Scott, Sewell, Shima, Stylianides, Szalda, Tronnier, Tronnier, Villafañe, Wen, Xiang   +50 more
core   +1 more source

Structural chemistry of metal coordination complexes at high pressure [PDF]

, 2014
The application of pressures of up to about 10 GPa may induce significant geometric, configurational, conformational and packing changes in molecular solids.
Adams, Alexander J. Blake, Allan, Allan, Allan, Allen, Baughman, Boldyreva, Boldyreva, Boldyreva, Boldyreva, Bonnet, Bray, Brink-Shoemaker, Bujak, Bujak, Bujak, Byrne, Cairns, Cairns, Caneschi, Casati, Casati, Clegg, Dinnebier, Espallargas, Fabbiani, Ferraro, Fischer, Fisher, Forman, Galloway, Goodwin, Gould, Granier, Guido, Guionneau, Guionneau, Guionneau, Guionneau, Halder, Hansson, Hassett, Hazen, Henry L.S. Wong, Jeremiah P. Tidey, Kobayashi, Kobayashi, Konno, Ksenofontov, Legrand, Lis, Madsen, Martin Schröder, Merrill, Milios, Milios, Milios, Milios, Milios, Moggach, Moggach, Moggach, Moggach, Ohishi, Okano, Okano, Parois, Pebler, Pinkowicz, Prescimone, Prescimone, Prescimone, Prescimone, Prescimone, Rahal, Sapunov, Scheins, Schirber, Schirber, Shepherd, Shepherd, Shepherd, Shirotani, Shirotani, Shirotani, Shirotani, Shirotani, Slebodnick, Sobczyk, Spek, Takacz, Takeda, Takeda, Takeda, Takeda, Tancharakorn, Timofeeva, van der sluis, Wilson, Wong, Woodall, Wu, Zhong   +103 more
core   +1 more source

Crystal Structure of FePb 4 Sb 6 Se 14 and its Structural Relationship with FePb 3 Sb 4 Se 10 [PDF]

, 2012
Single crystals of FePb 4 Sb 6 Se 14 , were obtained from solid‐state combination of high purity elemental powders at 873K for three days. Single crystal X‐ray structure determination revealed that the compound crystallizes in the monoclinic space group
Djieutedjeu, Honore, Poudeu, Pierre F. P., Sahoo, Pranati   +2 more
core   +1 more source

Crystal structures of two mononuclear complexes of terbium(III) nitrate with the tripodal alcohol 1,1,1-tris­(hy­droxy­meth­yl)propane [PDF]

, 2017
Two new mononuclear cationic complexes in which the TbIII ion is bis-chelated by the tripodal alcohol 1,1,1-tris­(hy­droxy­meth­yl)propane (H3LEt, C6H14O3) were prepared from Tb(NO3)3·5H2O and had their crystal and mol­ecular structures solved by single ...
Accorsi, Chen, Delangle, Farrugia, Frost, Gregoli, Husson, Liu, Liu, Liu, Luzon, Meng, Osa, Rohrbaugh, Sessoli, Shannon, Sheldrick, Sheldrick, Stumpf, Su, Totaro, Vieru, Westrup, Xu, Yang, Yang, Yang, Yu   +27 more
core   +3 more sources

The cluster compound In4Ti1.5Mo0.5Mo14O26 containing Mo14 clusters and the new mono- and bi-capped trioctahedral Mo15 and Mo16 clusters: Synthesis, crystal structure, and electrical and magnetic properties.

, 2015
International audienceSingle crystals of the new quaternary compd. In4Ti1.5Mo0.5Mo14O26 were obtained by solid state reaction. The crystal structure was detd. by single-crystal X-ray diffraction.
Gall, Philippe, Gougeon, Patrick, Guizouarn, Thierry   +2 more
core   +2 more sources

Synthesis and structure of two phases with both extended and point defects: Mn1 - xBi2 + yS4 and Mn1 - xBi2 + ySe4 [PDF]

, 1993
We report the structures of Mn1 - xBi2 + yS4 (0 [les] x [les] 0.3; Y = 0.667x) and Mn1 - xBi2 + ySe4 (0.1 [les] x [les] 0.14; Y = 0.667x). Both compounds are defect structures of the HgBi2S4 structure type.
Czerniak, Jeff, Fischer, Ernest, Lee, Stephen, Nagasundaram, N.   +3 more
core   +1 more source

Tl2[Te2O6]: The First Mixed‐Valent Oxidotellurate(IV/VI) of Thallium(I)

Zeitschrift für anorganische und allgemeine Chemie, Volume 651, Issue 18, December 10, 2025.
The layered crystal structure of the mixed‐valent thallium(I) oxidotellurate(IV/VI), Tl2[Te2O6]. Single crystals of Tl2[Te2O6] were grown hydrothermally at 220 °C starting from telluric acid and elemental thallium, whereas single‐phase microcrystalline material was obtained from solid‐state reactions between Tl2CO3, Tl2O3, and TeO2 in evacuated silica ...
Berthold Stöger, Matthias Weil
wiley   +1 more source

Nitridogermanates(IV): The Germanide Oxide Sr15Ge[GeN4]3O, the Carbodiimide Ba5[GeN4][CN2], and the Oxidonitridogermanate Sr6[Ge2N6O]

Zeitschrift für anorganische und allgemeine Chemie, Volume 651, Issue 11, July 22, 2025.
During synthesis of nitridogermanates, oxygen and carbon impurities lead to a variety of novel compounds—comprising carbodiimides and oxides—significantly expanding the chemistry of this compound class. Various novel compounds have been encountered by serendipity, due to small oxygen or carbon impurities, during the explorative studies to explore the ...
Lukas Link, Rainer Niewa
wiley   +1 more source

Bonding Heterogeneity and Nanoprecipitation on Substituting the Anionic Framework in Mg3Sb2 for p‐Type Zintl Thermoelectrics

Small Structures, Volume 6, Issue 4, April 2025.
Alloying‐induced bonding heterogeneity in p‐type Mg3(Sb1−2xBixSnx)2 leads to local atomic ordering, site preferences, and heterogeneous interfaces, influencing structural transitions and thermoelectric properties. A partial trigonal‐to‐monoclinic phase transition occurs, with a cubic Mg2Sn nanophase emerging at higher alloying content.
Nagendra Singh Chauhan, Takao Mori
wiley   +1 more source