Interconvertable modular framework and layered lanthanide(III)-etidronic acid coordination polymers [PDF]
POCI/QUI/58377/2004 - FEDERSFRH/BPD/9309/2002 (to F.-N.S.)SFRH/BPD/14410/2003 (to L.C.-S.)NoE ...
Carlos, L. D. +7 more
core +1 more source
Alloying‐induced bonding heterogeneity in p‐type Mg3(Sb1−2xBixSnx)2 leads to local atomic ordering, site preferences, and heterogeneous interfaces, influencing structural transitions and thermoelectric properties. A partial trigonal‐to‐monoclinic phase transition occurs, with a cubic Mg2Sn nanophase emerging at higher alloying content.
Nagendra Singh Chauhan, Takao Mori
wiley +1 more source
This concept highlights the innovative synthesis and magnetic enhancement of heterometallic 3d/4f complexes, showcasing the influence of diamagnetic CoIII and ZnII ions on their magnetization dynamics. Through experimental and computational studies, it is demonstrated how these diamagnetic ions contribute to the enhancement of magnetic anisotropy and ...
Vipanchi +4 more
wiley +1 more source
Electronic properties of lanthanide oxides from the GW perspective
A first-principles understanding of the electronic properties of f -electron systems is currently regarded as a great challenge in condensed-matter physics because of the difficulty in treating both localized and itinerant states on the same footing by ...
Jiang, H., Rinke, P., Scheffler, M.
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Isostructural imidonitridophosphates AE2AlP8N15(NH) (AE=Ca, Sr, Ba) were synthesized by high‐pressure/high‐temperature reactions. Atomic‐resolution EDX mapping and solid‐state NMR are consistent with the structure determination by X‐ray diffraction. A PN4‐tetrahedra network features channels occupied by aluminum and alkaline‐earth ions.
Monika M. Pointner +8 more
wiley +1 more source
Quaternary Silver Bismuth Chalcogenide Halides Ag - Bi - Q - X (Q = S, Se; X = Cl, Br): Syntheses and Crystal Structures [PDF]
Systematic synthetic investigations of the quaternary systems Ag - Bi - Q - X (Q = S, Se; X = Cl, Br) led to a variety of quaternary phases that exhibit considerable structural diversity with increasing complexity.
Poudeu Poudeu, Pierre Ferdinand
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Syntheses and Crystal Structures of Two Cadmium Methanetetrabenzoates Featured by Open Framework and Infinite Layers [PDF]
International audienceColourless single crystals of Cd2[μ8-MTB]*3H2O*DMF (1) were prepared in DMF/H2O solution. 1: Space group C2/c (no. 15) with a = 1821.30(6), b = 2175.08(6), c = 1269.87(4) pm, β = 129.684(1)°.
Gorls, Helmar +3 more
core +2 more sources
New interstitially stabilized cluster complexes of dysprosium, holmium and erbium [PDF]
This thesis was intended to broaden our knowledge of interstitially stabilized rare-earth cluster halides of the elements dysprosium, holmium and erbium in terms of structures and electronic situation.
Daub, Kathrin
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Divalent Metal Vinylphosphonate Layered Materials: Compositional Variability, Structural Peculiarities, Dehydration Behavior, and Photoluminescent Properties [PDF]
A family of M-VP (M = Ni, Co, Cd, Mn, Zn, Fe, Cu, Pb; VP = vinylphosphonate) and M-PVP (M = Co, Cd; PVP = phenylvinylphosphonate) materials have been synthesized by hydrothermal methods and characterized by FTIR, elemental analysis, and thermogravimetric
Adele Turner +62 more
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Lewis-acid behaviour of neutral and cationic fluoridotungsten(V) and (VI) complexes [PDF]
The Lewis-behaviour of WF6 towards pyridine and derivatives thereof has been reinvestigated in detail. The stability of WF6 towards main-group donor ligands has been exploited to develop synthetic routes to numerous complexes of W(NC6F5)F4, [WF5]+, WF5 ...
Turnbull, Douglas +1 more
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