Divalent Metal Vinylphosphonate Layered Materials: Compositional Variability, Structural Peculiarities, Dehydration Behavior, and Photoluminescent Properties [PDF]
A family of M-VP (M = Ni, Co, Cd, Mn, Zn, Fe, Cu, Pb; VP = vinylphosphonate) and M-PVP (M = Co, Cd; PVP = phenylvinylphosphonate) materials have been synthesized by hydrothermal methods and characterized by FTIR, elemental analysis, and thermogravimetric
Adele Turner+62 more
core +1 more source
Lewis-acid behaviour of neutral and cationic fluoridotungsten(V) and (VI) complexes [PDF]
The Lewis-behaviour of WF6 towards pyridine and derivatives thereof has been reinvestigated in detail. The stability of WF6 towards main-group donor ligands has been exploited to develop synthetic routes to numerous complexes of W(NC6F5)F4, [WF5]+, WF5 ...
Turnbull, Douglas+1 more
core
Synthesis, Spectral Characterization, Thermal and In vitro Antimicrobial Studies for Novel Co(II) and Ni(II) Complexes of (N,N'-(1,2-Phenylene)Bis(2-Aminobenzamide) [PDF]
Novel metal complexes of Co(II) and Ni(II) have been prepared from reaction of their different salts with previously prepared ligand (L) namely (N,N'-(1,2-phenylene)bis(2-aminobenzamide).
A. El-Boraey, Hanaa+2 more
core +2 more sources
Characterizing Local Order and Physical Properties of Rare Earth Complex Oxides [PDF]
With more than 500 compositions, materials possessing the pyrochlore structure have a myriad of technological applications and physical phenomena. Three of the most noteworthy properties are the structure’s ability to resist amorphization making it a ...
Shamblin, Thomas Jacob
core +1 more source
Lanthanide phosphine oxide complexes [PDF]
Phosphine oxide complexes of lanthanide metal have been studied to elucidate the fundamental aspects of their structural chemistry and to develop important technological applications mainly in the reprocessing of nuclear fuels and in photoluminescent ...
Platt, Andrew
core +1 more source
Structural Analysis of the Gd-Au-Al 1/1 Quasicrystal Approximant Phase across Its Composition-Driven Magnetic Property Changes. [PDF]
Huang YC+4 more
europepmc +1 more source
Crystallographic Stability of Metastable Phase Formed by Containerless Processing in REFeO3 (RE: Rare-Earth Element) [PDF]
Undercooling a melt often facilitates a metastable phase to nucleate preferentially. Although the classical nucleation theory shows that the most critical factor for forming a metastable phase is the interface free energy, the crystallographic stability ...
Kumar, M. S. Vijaya+1 more
core +1 more source
Trace Water Changes Metal Ion Speciation in Deep Eutectic Solvents: Ce3+ Solvation and Nanoscale Water Clustering in Choline Chloride-Urea-Water Mixtures. [PDF]
Hammond OS+3 more
europepmc +1 more source
Syntheses, Structure, Magnetism, and Optical Properties of Lutetium-based Interlanthanide Selenides [PDF]
Ln{sub 3}LuSe{sub 6} (Ln = La, Ce), {beta}-LnLuSe{sub 3} (Ln = Pr, Nd), and Ln{sub x}Lu{sub 4-x}Se{sub 6} (Ln = Sm, Gd; x = 1.82, 1.87) have been synthesized using a Sb{sub 2}Se{sub 3} flux at 1000 C.
Albrecht-Schmitt, Thomas E.+6 more
core
A 12-Connected [Y4((μ3-OH)4]8+ Cluster-Based Luminescent Metal-Organic Framework for Selective Turn-on Detection of F- in H2O. [PDF]
Li J, Wang A, Qiu S, Wang X, Li J.
europepmc +1 more source