Results 141 to 150 of about 410,603 (295)

Decoding Gas Evolution Pathways and Interfacial Chemistry in Layered Oxide Cathodes for Safer Sodium‐Ion Batteries

open access: yesAdvanced Energy Materials, EarlyView.
Gas evolution behaviors of sodium layered oxide cathodes with varying compositions, cutoff voltages, dopants, and particle sizes/morphologies have been systematically investigated by online electrochemical mass spectrometry. The fundamental outgassing mechanisms of sodium‐based cathodes compared to lithium‐based cathodes have been elucidated.
Chen Liu, Zehao Cui, Arumugam Manthiram
wiley   +1 more source

Engineering Na‐Rich P2‐Type Layered Oxides Through Li/Ti Dual Doping for Oxygen Redox Activation and Superior Structural Stability

open access: yesAdvanced Energy Materials, EarlyView.
P2‐type sodium layered oxides have potential for high‐voltage operation but suffer from structural instability and capacity fading. This work demonstrates that synergistic Li and Ti co‐doping enhances sodium inventory, suppresses detrimental phase transitions, and activates reversible lattice oxygen redox.
Rishika Jakhar   +16 more
wiley   +1 more source

Stabilizing Magnesium Anodes in Rechargeable Magnesium Batteries via Fluorinated Cyclic Ether Electrolyte Additive

open access: yesAdvanced Energy Materials, EarlyView.
A fluorinated cyclic ether, FDOL, is shown to stabilize Mg metal anodes by tuning Mg2+ solvation of the G2 electrolyte. The G2‐FDOL electrolyte suppresses passivation and thick, diffusion‐blocking Mg deposits, enabling more uniform Mg plating/stripping and sustained interfacial reactions.
Hafiz Ahmad Ishfaq   +9 more
wiley   +1 more source

Role of Wadsley Defects and Cation Disorder to Enhance MoNb12O33 Diffusion

open access: yesAdvanced Energy Materials, EarlyView.
Wadsley‐Roth niobates are high‐rate capable and durable anode materials for lithium‐ion batteries. Defect‐tailoring of MoNb12O33 is shown to substantially enhance lithium diffusion. Computational models were used to separate the effects of cation disorder and Wadsley defects to identify that both led to the occupation of fast diffusion sites at lower ...
CJ Sturgill   +10 more
wiley   +1 more source

Investigation of the Lithium Extraction Mechanism from LiNi0.6Mn0.2Co0.2O2 by Using Operando Neutron Diffraction in an All‐Solid‐State Battery

open access: yesAdvanced Energy Materials, EarlyView.
All‐solid‐state batteries (ASSB) are promising for high‐energy applications. Using a newly designed electrochemical cell, this study demonstrates reversible Li+ insertion/extraction in a thick ASSB and enables operando neutron diffraction. The results reveal structural evolution and H1‐H2 phase coexistence in LiNi0.6Mn0.2Co0.2O2 (NMC622), while ...
Sreelakshmi Anil Kumar   +7 more
wiley   +1 more source

Universal Oxychlorination Strategy in Halide Solid Electrolytes for All‐Solid‐State Batteries

open access: yesAdvanced Energy Materials, EarlyView.
A WO2Cl2‐driven oxychlorination strategy enables bulk oxygen incorporation into close‐packed LixMCl6 (M = Zr, Y, Er, In) halide lattices. Oxygen is selectively anchored by W6+ as lattice‐integrated [WO2Cl4]2− units, regulating the anionic framework, diversifying Li coordination, and weakening Li–Cl interactions.
Jae‐Seung Kim   +13 more
wiley   +1 more source

An experimental investigation of retro-reinforced clay brick arches

open access: yes, 2010
This paper describes the laboratory testing of eight 2.95m span segmental profile clay brick arches. Seven of the arches were strengthened with longitudinal intrados (soffit) reinforcement; the eighth was left unreinforced as an experimental control ...
Ashour, AF, Chen, Y, Garrity, SW
core  

Oxygen‐Driven Structural Reorganization by Trace Water Enabling Fast Li‐Ion Transport in a Pliable Solid Electrolyte

open access: yesAdvanced Energy Materials, EarlyView.
Trace water is acting as a constructive mediator in 2LiCl–GaF3, markedly increasing ionic conductivity while reorganizing local coordination. Hydration creates localized Li+ solvation environments and partially dissociates ion pairs, enhancing Li‐ion mobility.
Youngkyung Kim   +10 more
wiley   +1 more source

Enhancing Ion‐Electron Transport in Positive Electrode of Solid‐State Lithium Metal Batteries With Multifunctional Catholyte Made of Polymer Mixed Ionic‐Electronic Conductor PEDOT:PSSTFSI and Li3InCl6

open access: yesAdvanced Energy Materials, EarlyView.
A mixed ion‐electron conducting polymer binder, PEDOT:PSSTFSI, enhances both ionic and electronic transport in NMC‐based positive electrode composite (PEC) for ASSBs. Optimal polymer loading (0.33 wt.% in PEC) provides the most balanced transport, with an effective conductivities (σel/σion) ratio closest to unity, enabling high discharge capacity at 1 ...
Elina Nazmutdinova   +6 more
wiley   +1 more source

Depth‐of‐Discharge‐Dependent Chemical Evolution in Sulfurized Polyacrylonitrile Cathodes for Ether‐Based Room‐Temperature Sodium–Sulfur Batteries

open access: yesAdvanced Energy Materials, EarlyView.
Sulfurized polyacrylonitrile (SPAN) is investigated as a cathode for room‐temperature Na–S batteries in ether‐based electrolytes under controlled discharge depths. Depth‐of‐discharge‐dependent structural evolution reveals that deep discharge below 1.0 V destabilizes SPAN structure, alters polysulfide equilibria, and promotes sodium dendrite formation ...
Liwen Yang   +5 more
wiley   +1 more source

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