Results 221 to 230 of about 372,622 (283)

Evidence for a Cu(II)‐Catalysed CuAAC Reaction: A Combined Experimental and Computational Study

open access: yesAngewandte Chemie, EarlyView.
A new mechanistic pathway for the CuAAC reaction has been found to operate under specific reaction conditions. The pathway is catalysed by Cu(II) through a self‐assembled dinuclear Cu(II) complex that incorporates the triazole product. Computational analysis and assessment of generality are reported.
Matthew J. Andrews   +12 more
wiley   +1 more source

Orchestrating Anion–π+ Interactions to Accelerate Metal‐Free Room‐Temperature Phosphorescence

open access: yesAngewandte Chemie, EarlyView.
Tuning anion–π+ interactions in pyridinium iodide contact ion pairs enables ultrafast metal‐free room‐temperature phosphorescence (540–605 nm) with radiative rates up to 5.2×105 s−1. Strong iodide→π+ charge‐transfer coupling, enhanced spin–orbit interactions, and dynamic ion‐pair organization accelerate intersystem crossing and emission, establishing ...
Eetu Hakkarainen   +12 more
wiley   +1 more source

Isomorphous dinuclear copper(I) complexes bridged by 4-methyl-1<i>H</i>-1,2,4-triazole-5-thiol-ate ligands: chloride and bromide analogues. [PDF]

open access: yesActa Crystallogr E Crystallogr Commun
Ahmad A   +6 more
europepmc   +1 more source

Differential Water Networks Guide Selectivity Optimization of a Cell Active BPTF Inhibitor in Neuroblastoma

open access: yesAngewandte Chemie, EarlyView.
BZ2 is a second‐generation Bromodomain PHD finger Transcription Factor (BPTF) inhibitor with improved selectivity over Class I and Class IV BRD off‐targets identified in our previously reported inhibitor, BZ1. Structural analyses reveal that water network engagement is key to this selectivity.
Kesavan Babu   +19 more
wiley   +1 more source

Spectral CT electron density for evaluation of lumbar intervertebral disk degeneration. [PDF]

open access: yesPLoS One
Nakajo M   +14 more
europepmc   +1 more source

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