Results 11 to 20 of about 589 (163)
Substrate-Selective Temperature-Controlled Synthesis of Thiophene Derivatives at Interfaces. [PDF]
The deposition of a dithiophene derivative on Ag(111) at room temperature followed by annealing gives rise to molecular wires, whereas the adsorption of the same precursor on a hot substrate affords the formation of benzotrithiophene species. Abstract The temperature‐controlled transformation of organic molecules at interfaces is an incipient yet ...
Pérez-Elvira E +16 more
europepmc +3 more sources
Self-assembly and Lateral Cobalt Coordination of a Fivefold Symmetric Cyanostar Macrocycle on an Au(111) Surface. [PDF]
Herein, we report the first example of the formation of a close‐packed, regular 2D monolayer of a fivefold symmetric cyanostar macrocycle on an Au(111) surface under ultra‐high vacuum and the structural modification of such self‐assembled architecture upon cobalt atom deposition.
Černá L +11 more
europepmc +2 more sources
On-Surface Synthesis and Characterization of Cumulene-Linked Stone-Wales Polymers. [PDF]
On‐surface synthesis of one‐dimensional polymers featuring Stone‐Wales defects and cumulene linkages is demonstrated via thermally and light‐induced reactions on Au(111). STM, nc‐AFM, and Raman spectroscopy, complemented by theory calculations, reveal their chemical structure with a non‐planar geometry, and a distinct electronic bandgap of 1.8 eV ...
Pérez-Elvira E +15 more
europepmc +3 more sources
Toxicidad de los nanomateriales de interés biomédico en los sistemas biológicos
La nanotecnología ha pasado exitosamente del laboratorio a la vida cotidiana, particularmente en el campo de la medicina. Debido a sus propiedades únicas de los nanomateriales, es fundamental evaluar su toxicidad potencial, tanto en el ambiente como en ...
Roberto Vazquez Muñoz +1 more
doaj +1 more source
Los trabajos presentados en este número permiten visualizar que la ciencia de nanomateriales en nuestro país tiene algunos retos como el desarrollo de nuevas alternativas sintéticas que no requieran agentes directores de estructura ni tiempos ...
Karla Oyuki Juárez Moreno +1 more
doaj +1 more source
Biomoléculas en nanotecnología
Las propiedades de reconocimiento molecular y autoensamble intrínseco de las biomoléculas han fascinado a la nanotecnología. Su incursión está revolucionando la forma de fabricar nanomateriales.
José A. D. L. C. Rodríguez Galván
doaj +1 more source
IntroducciónLa tecnología moderna cambia a gran velocidad, pero en particular elritmo del progreso en electrónica basada en estado sólido es frenéticoy vertiginoso. Desde la invención del transistor y el posterior desarrollo decircuitos integrados, se ha vuelto necesario, y compulsivo, fabricar objetosde uso diario más pequeЦos, más portátiles, fáciles
M. J. Oviedo-Bandera +2 more
openaire +3 more sources
Tunable Oxygen Connectivity in Carbaporphyrinoid Polymers on Metal Surfaces
Hydroxyl‐functionalized dicarbaporphyrinoid polymers synthesized on Au(111) enable tunable oxygen‐mediated connectivity under UHV conditions. Thermal activation yields one‐dimensional hydroxyl‐terminated polymers that can selectively evolve into either covalently‐linked dibenzo‐p‐dioxane architectures through intermolecular C–O–C coupling or two‐fold ...
Alberto Martínez‐Bajo +14 more
wiley +2 more sources
π‐Enlargement in Porphyrin Macrocycles at Interfaces
On‐surface synthesis of a 20‐π free‐base expanded porphyrin, by depositing onto a hot Ag(111) substrate an 18‐π free‐base precursor equipped with ‐CF3 functional groups ABSTRACT Porphyrins are essential heteroatomic macrocycles, fundamental to both biological systems and advanced technology.
Ana Barragán +11 more
wiley +2 more sources
Nanographene‐Based van der Waals Organic Framework With Permanent Porosity
Unlocking record‐breaking porosity in a supramolecular organic framework (SOF). Through the strategic design of a C3‐symmetric nanographene, a robust supramolecular framework is achieved via exclusively weak van der Waals forces. This metal‐free scaffold reaches a benchmark BET surface area of 1108 m2 g−1 –the highest to date for this class–combining ...
Arturo Oró +5 more
wiley +2 more sources

