Results 161 to 170 of about 80,245 (335)

Light‐Enabled [2σ + 2π] Cycloadditions of Bicyclo[1.1.0]butanes and Alkenes by Ti‐Salen Photocatalysis

open access: yesChemistryEurope, EarlyView.
This study reports an unprecedented Ti(Salen)‐catalyzed [2σ+2π] photocycloaddition of bicyclo[1.1.0]butanes and alkenes, featuring broad substrate scope, excellent functional group tolerance, scalability, and potential pharmaceutical applications. Notably, this work represents the first application of a Ti(Salen) complex as an efficient photoredox ...
Jinping Xing   +5 more
wiley   +1 more source

Polycyclic Aromatics as Promising Phosphorescence Materials

open access: yesChemistryEurope, EarlyView.
This review focuses on the recent progress of polycyclic aromatic compounds (PACs)‐based phosphorescent materials. Their molecular structural characteristics as promising phosphors are highlighted, and the efficient strategies from molecular and aggregation levels have been illustrated systematically to promote the development of PACs with desirable ...
Peipei Liu, Qianqian Li, Zhen Li
wiley   +1 more source

Synthesis of Cyclic Sulfilimines and Sulfoximines via Copper‐Mediated C(sp2)–H Sulfanylation of Benzylamines with a Catalytic Transient Directing Group

open access: yesChemistryEurope, EarlyView.
Copper‐mediated transient C─H sulfanylation of benzylamines with sulfenamides enables rapid access to thioethers, cyclic sulfilimines, and sulfoximines. Mechanistic investigations using 1H NMR and electron paramagnetic resonance spectroscopy reveal an unprecedented thermally induced homolytic cleavage of the sulfenamide N─S bond, slowly releasing the ...
Tsz‐Kan Ma   +4 more
wiley   +1 more source

Unusual Rearrangement of a 1,8-Naphthalene Derivative. [PDF]

open access: yesJ Org Chem
Habib A   +7 more
europepmc   +1 more source

Elucidating the Role of Intralayer Cation Ordering and Disordering in Li0.6[Li0.2Mn0.8]O2 Cathode Materials

open access: yesCarbon Energy, EarlyView.
The researchers successfully synthesized ordered/disordered Li0.6[Li0.2Mn0.8]O2 material. Based on the results of ab initio molecular dynamics (AIMD) simulations, the structure exhibits stability as evidenced by energy fluctuations around the equilibrium position without any abrupt drops.
Huaifang Shang   +11 more
wiley   +1 more source

A Potassium Base‐Promoted Intramolecular Enolate–Olefin Metathesis

open access: yesChemistry – A European Journal, EarlyView.
A novel olefin metathesis, the enolate‐olefin metathesis reaction, in which two double bonds recombine via a four‐membered carbocyclic intermediate (NOT metallacyclobutane intermediate), is developed. The methodology is a transition‐metal‐free, base‐promoted enolate–olefin metathesis involving [2 + 2] / retro‐[2 + 2] cycloaddition sequences of 2‐acyl‐2′
Kazuma Sugimoto   +11 more
wiley   +1 more source

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