Pd-Catalyzed Asymmetric Dearomative Heck/Tsuji-Trost Difunctionalization of Naphthalenes. [PDF]
Adv Sci (Weinh)We have developed a palladium‐catalyzed asymmetric dearomative Heck/Tsuji‐Trost 1,4‐difunctionalization reaction of naphthalenes, affording 4‐aminospirocyclohexene oxindole products bearing two remote chiral centers. Through the effect of the newly designed chiral sulfinamide phosphine ligand with large steric hindrance, side reactions are inhibited ...
Ma LL, Xu B, Zhang J, Zhang ZM.
europepmc +2 more sources
Synthesis and Characterisation of Eight Isomeric Bis(2-pyridyloxy)naphthalenes [PDF]
Molecules, 2006 Eight isomeric bis(2-pyridyloxy)naphthalenes have been prepared from reactions of 2-bromopyridine with the appropriate dihydroxynaphthalene and the products fully characterised by 1- and 2-D NMR spectroscopy.
Peter J. Steel +1 more
doaj +4 more sources
Chemical structure drives developmental toxicity of alkyl-substituted naphthalenes in zebrafish [PDF]
Environment InternationalNaphthalene and its alkyl-substituted derivatives are among the most abundant polycyclic aromatic hydrocarbons (PAHs) in environmental and human exposure studies, yet their developmental toxicity and mode of action remain poorly understood due to ...
Mackenzie L. Morshead +5 more
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Enantioselective aza-electrophilic dearomatization of naphthalene derivatives [PDF]
Nature CommunicationsThe catalytic asymmetric dearomatization of naphthalenes is a pivotal strategy for generating enantioenriched three-dimensional aliphatic polycycles from flat aromatic precursors.
Jun Liu +5 more
doaj +2 more sources
Photoinduced polarity-mismatched transformations of isoquinolines into naphthalenes [PDF]
Nature CommunicationsIsosteric replacement is an important strategy for lead optimization in drug-development paradigms. However, it is usually restricted to cost- and labor-intensive de novo syntheses.
Congcong Zhang +6 more
doaj +2 more sources
Biomimetic Mn(III) porphyrin-catalyzed aromaticity-breaking epoxidation of electron-deficient naphthalene [PDF]
Nature CommunicationsSelective catalytic aromaticity-breaking epoxidation of arenes remains an ongoing research challenge, attributed to the stability of aromatic systems, the occurrence of over-oxidation, and the instability of epoxides.
Hongli Wu +7 more
doaj +2 more sources
Unveiling the Photodegradation Mechanism of Monochlorinated Naphthalenes under UV-C Irradiation: Affecting Factors Analysis, the Roles of Hydroxyl Radicals, and DFT Calculation [PDF]
MoleculesPolychlorinated naphthalenes (PCNs) are a new type of persistent organic pollutant (POP) characterized by persistence, bioaccumulation, dioxin-like toxicity, and long-range atmospheric transport. Focusing on one type of PCN, monochlorinated naphthalenes (
Yingtan Yu +6 more
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Substituted Naphthalenes and Their Role as Potato Sprout Suppressants [PDF]
, 1991 This thesis describes work relating to the substituted naphthalenes and their use as potato sprout suppressant chemicals. Sprout suppressants are used to control the sprouting of potatoes during extended storage.
O'Hagan, Noreen
core +6 more sources
Perfluorohalogenated Naphthalenes: Synthesis, Crystal Structure, and Intermolecular Interaction [PDF]
, 2023 Perfluorohalogenated naphthalenes (PFXNaPs) are unique small molecules with great potential to exhibit a new type of σ-hole and π-hole bonding, owing to the incorporation of multiple fluorine atoms onto the naphthalene ring.
Satoshi, SUGIURA +6 more
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Spirodienone and Bis(spirodienone) Derivatives of Calix[4]naphthalenes
, 2016 Calix[4]naphthalenes 11 and 12 in which hydroxyl groups are situated intraannularly can be oxidized with PTMATB and base to form the bis(spirodienone) 13, from 11, and bis(spirodienone) 20−21 and spirodienone 22, from 12.
Paris E. Georghiou (828618) +3 more
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