Results 61 to 70 of about 5,923 (229)

Understanding the Interplay Between Thermal Activation, Diffusion, and Phase Segregation of Molecular Dopants Blended with Polymeric Semiconductors

Advanced Electronic Materials, EarlyView.
The use of air stable but thermally labile molecules provides an efficient strategy for the N‐type doping of organic semiconductors with relatively low electron affinities. Design criteria for efficient dopants should also take into account diffusion and phase segregation that cannot be decoupled from thermally activated doping.
Francesca Pallini, Sara Mattiello, Mauro Sassi, Gabriele Paoli, Giuseppe Mattioli, Pietro Rossi, Giulia Coco, Alberto D. Scaccabarozzi, Brian Minki Kim, Pietro Mariani, Hiba Wakidi, Sadie M. Flagg, Massimiliano D'Arienzo, Mario Caironi, Thuc‐Quyen Nguyen, Luca Beverina   +15 more
wiley   +1 more source

Intramolecular Charge‐Transfer Dopants Enable Isolated Triplet Excitons as Spin Qutrits in a Single Crystal

Angewandte Chemie, EarlyView.
Photoexcitation of an intramolecular charge‐transfer molecule doped into single crystals of a structurally similar host molecule results in well‐ordered, spectrally addressable, and orientation‐tunable triplet excitons that maintain coherence at elevated temperatures.
Yaoyao Han, Samuel B. Tyndall, Kathryn R. Peinkofer, Yuheng Huang, Ryan M. Young, Matthew D. Krzyaniak, Michael R. Wasielewski   +6 more
wiley   +2 more sources

Effect of Regiochemistry on Doping and Thermoelectric Properties of n‐Doped Fullerene Derivatives

Advanced Electronic Materials, EarlyView.
Three fullerene derivatives doubly substituted with diethylene glycol chains (PDEG‐2) is presented. The different regiochemistry significantly affects the crystallinity and consequently the dielectric properties, electronic transport, and doping efficiency. By striking a balance between compatibility with the molecular dopant N‐DMBI and crystallinity a
Federico Ferrari, Sylvia Rousseva, Diego Rosas Villalva, Ewout Kessels, Jan C. Hummelen, Derya Baran, Ryan Chiechi, L. Jan Anton Koster   +7 more
wiley   +1 more source

Semi‐Reduction of Allenes to Access Deuterated Allylic Isotopomers, Isotopologs and Enantioisotopomers

Angewandte Chemie, EarlyView.
Modular and Precise Deuteration: The synthesis of molecules precisely deuterated at allylic, vinylic or both positions remains a challenging task. This work discloses a modular semi‐reductive deuteration that enables the synthesis of various isotopologs including precisely labeled d1‐, d2‐, d3‐, d5‐, and d7‐products.
Lihan Qi, Raviraj Ananda Thorat, Brad D. Maxwell, Jeffery A. Gladding, Aniel J. Rivera Arzola, Shashank P. Sancheti, Reilly E. Sonstrom, Xulin Tang, Isaac J. Anderson, Brooks H. Pate, Joseph R. Clark   +10 more
wiley   +2 more sources

Peri-Substituted Acyl Pyrrolyl Naphthalenes: Synthesis, Reactions and Photophysical Properties

Molecules
The preparation of two 1-acyl-8-pyrrolylnaphthalenes (5 and 6) and one pyrrolone (8) are reported along with the issues complicating the preparations of other compounds.
Junkai Zhao, Robert Pike, Christopher Abelt   +2 more
doaj   +1 more source

Theoretical Study of Intramolecular Interactions in Peri-Substituted Naphthalenes: Chalcogen and Hydrogen Bonds

Molecules, 2017
A theoretical study of the peri interactions, both intramolecular hydrogen (HB) and chalcogen bonds (YB), in 1-hydroxy-8YH-naphthalene, 1,4-dihydroxy-5,8-di-YH-naphthalene, and 1,5-dihydroxy-4,8-di-YH-naphthalene, with Y = O, S, and Se was carried out ...
Goar Sánchez–Sanz, Ibon Alkorta, José Elguero   +2 more
doaj   +1 more source

Neuromorphic Motor Control with Electrolyte‐Gated Organic Synaptic Transistors

Advanced Electronic Materials, EarlyView.
Electrolyte‐gated organic synaptic transistor (EGOST)‐based neuromorphic motor control systems integrate sensing, processing, and actuation by mimicking biological synapses. With advantages such as low power consumption, tunable synaptic plasticity, and mechanical flexibility, they are emerging as next‐generation core technologies for real‐time ...
Sung‐Hwan Kim, Ju‐Hyeok Yun, Hea‐Lim Park, Sin‐Hyung Lee   +3 more
wiley   +1 more source

Photoenzymatic Hydroalkylation Enables Streamlined Access to Aryl Glutarimide Precursors

Angewandte Chemie, EarlyView.
We report a photoenzymatic hydroalkylation that enables streamlined, stereocontrolled access to aryl glutarimide precursors relevant to targeted protein degradation. Engineered flavin‐dependent “ene”‐reductases provide broad scope and high enantioselectivity through a distinct electron transfer–enantioselective proton transfer pathway.
Zhi Xu, Prasun Mukherjee, Steven Gossert, Stephen Thomas, Vasil H. Vasilev, Eric R. Welin, Yichen Tan, Shane M. McKenna, Megan A. Emmanuel, Todd K. Hyster   +9 more
wiley   +2 more sources

Characterization of 9 Gas Chromatography Columns by Linear and Lee Retention Indices for Polychlorinated Biphenyls and Polychlorinated Naphthalenes

Separations, 2020
Polychlorinated biphenyls (PCBs) and naphthalenes (PCNs) are ubiquitous environmental contaminants with varying degrees of toxicity. There are hundreds of possible congeners with similar chemical characteristics, which make these compounds difficult to ...
Conner Stultz, Frank L. Dorman
doaj   +1 more source

Aging and Electrical Stability of DNTT Honey‐Gated OFETs

Advanced Electronic Materials, EarlyView.
DNTT honey‐gated organic transistors were fabricated and evaluated to assess short‐ and long‐term stability under electrical stress and aging. Short‐term transfer measurements (five days, 40 sweeps/day) showed minimal parameter shift, while extended measurements revealed gradual degradation over weeks.
Douglas H. Vieira, Ana C. de Paula, José D. F. Dias, Maria H. L. O. Fung, Rafael Furlan de Oliveira, Gabriel L. Nogueira, Keli F. Seidel, José P. M. Serbena, Neri Alves   +8 more
wiley   +1 more source