Results 31 to 40 of about 45,496 (243)

Photocatalytic Cross‐Coupling of Phenols and Heteroaryl Halides With Machine Learning‐Guided Reaction Prediction

open access: yesAngewandte Chemie, EarlyView.
Photocatalytic cross‐coupling: A redox‐neutral photochemical method enables direct C(sp2)─C(sp2) bond formation between phenols and heteroaryl halides using an organic dye and base. Complementary radical generation allows efficient cross‐coupling in up to 91% yield. Mechanistic studies, DFT, HTE, and machine learning rationalize and predict reactivity,
Matthew C. Carson   +4 more
wiley   +2 more sources

A novel DR/NIR T-shaped aiegen: Synthesis and x-ray crystal structure study [PDF]

open access: yes, 2020
We developed a new benzodifuran derivative as the condensation product between 2,6-diamino-4-(4-nitrophenyl)benzo[1,2-b:4,5-b’]difuran-3,7-dicarboxylate and 3-hydroxy-2-naphthaldehyde.
Bakayoko, G.   +4 more
core   +1 more source

Two-stage steam explosion pretreatment of softwood with 2-naphthol as carbocation scavenger

open access: yesBiotechnology for Biofuels, 2019
Background  Lignocellulosic biomass is considered as a potential source for sustainable biofuels. In the conversion process, a pretreatment step is necessary in order to overcome the biomass recalcitrance and allow for sufficient fermentable sugar yields
Christoph-Maximilian Seidel   +4 more
doaj   +1 more source

Sensitivity Analysis for Multiple Comparisons in Matched Observational Studies through Quadratically Constrained Linear Programming

open access: yes, 2015
A sensitivity analysis in an observational study assesses the robustness of significant findings to unmeasured confounding. While sensitivity analyses in matched observational studies have been well addressed when there is a single outcome variable ...
Fogarty, Colin B., Small, Dylan S.
core   +2 more sources

Marinomonas brasilensis sp. nov., isolated from the coral Mussismilia hispida, and reclassification of Marinomonas basaltis as a later heterotypic synonym of Marinomonas communis [PDF]

open access: yes, 2011
A Gram-negative, aerobic bacterium, designated strain R-40503(T), was isolated from mucus of the reef-builder coral Mussismilia hispida, located in the Sao Sebastiao Channel, Sao Paulo, Brazil.
Alves   +14 more
core   +2 more sources

Cyclization of Hydrazones of 2-Acetyl-1-naphthol and 1-Acetyl-2-naphthol with Triphosgene. Synthesis of Spiro Naphthoxazine Dimers

open access: yesMolecules, 2009
Cyclization of hydrazones derived from 2-acetyl-1-naphthol and 1-acetyl-2-naphthol with triphosgene gave naphtho[1,2-e]-1,3-oxazines, naphtho[2,1-e]-1,3-oxazines or their spiro dimers depending on the molar ratio of triphosgene used for the cyclization.
Hamad Zaid Alkhathlan   +5 more
doaj   +1 more source

Reactions of cyclobutenones with nucleophilic reagents via vinylketen intermediates [PDF]

open access: yes, 1976
While strong nucleophiles add to the endocyclic double bond of cyclobutenones to yield cyclobutanones, weaker nucleophiles (e.g. alcohols, aniline) interact with the vinylketens which are thermally or photochemically generated from cyclobutenones; the ...
Huisgen, Rolf, Mayr, Herbert
core   +1 more source

High-Performance Liquid Chromatographic Determination of Naphtholsulfonic Acids

open access: yesCHIMIA, 1979
A HPLC-method for the quantitative analysis of mixed solutions of 2-naphthol-5,7-disulfonic acid and 2-naphthol-7-sulfonic acid was developed. A complete reproducible separation of these compounds in a very short time could be reached by using a ...
Luca Rossinelli   +2 more
doaj   +1 more source

A new chiral electro-optic effect: Sum-frequency generation from optically active liquids in the presence of a dc electric field

open access: yes, 2003
We report the observation of sum-frequency signals that depend linearly on an applied electrostatic field and that change sign with the handedness of an optically active solution. This recently predicted chiral electro-optic effect exists in the electric-
A. D. Buckingham   +6 more
core   +1 more source

Characterization of an Injectable Poly(vinyl alcohol)‐gelatin Hydrogel for Growth Factor Delivery in an Orthopedic Application

open access: yesAdvanced Healthcare Materials, EarlyView.
This work introduces photo‐crosslinkable tyraminated poly(vinyl alcohol)‐gelatin (PVA‐GT) hydrogels as tunable injectable platforms for tissue engineering and growth factor delivery applications. This schematic illustrates the two developed hydrogel formulations and the experimental workflow used to evaluate their physico‐chemical properties in vitro ...
Alessia Longoni   +15 more
wiley   +1 more source

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