Results 51 to 60 of about 46,076 (249)

Colloidal Heterostructures Enable Interfacial Transport of Immiscible Molecules in Printable Organohydrogels

Advanced Materials, EarlyView.
Multiphase printable organohydrogels with tunable microstructures are developed to control molecular transport pathways for immiscible cargo. The tortuosity and domain size of the colloidal phases are tuned by adjusting temperature and shear during processing, which enables the tailoring of diffusion kinetics due to different transport pathways.
Riley E. Dowdy‐Green, Rony Waheibi, Nazanin Shakoury, Yuemei Ye, Lilian C. Hsiao   +4 more
wiley   +1 more source

Mechanism of H_2 Evolution from a Photogenerated Hydridocobaloxime [PDF]

, 2010
Proton transfer from the triplet excited state of brominated naphthol to a difluoroboryl bridged Co^I-diglyoxime complex, forming Co^(III)H, was monitored via transient absorption. The second-order rate constant for Co^(III)H formation is in the range (3.
Dempsey, Jillian L., Gray, Harry B., Winkler, Jay R.   +2 more
core   +1 more source

A Biochar‐Based Composite Hydrogel Microenvironment for Enhanced Biocatalysis

Advanced Materials, EarlyView.
This work presents the synthesis of a polyacrylamide hydrogel wherein biomass‐derived biochar is co‐encapsulated with the enzyme horseradish peroxidase (HRP). The resulting composite hydrogel possesses balanced electron‐rich and electron‐deficient domains, creating an optimal microenvironment that concentrates both hydrogen peroxide and phenol ...
Shengzhe Wang, Jingling Zhu, Weiyang Xue, Yuting Wen, Zhongxing Zhang, Xia Song, Yuan Yu, Chenglin Sun, Huangzhao Wei, Jun Li   +9 more
wiley   +1 more source

Neutral‐pH Electropolymerization of Aniline on Hierarchically Porous Laser‐Induced Graphene Electrodes for Dual Biosensing

Advanced Materials Technologies, EarlyView.
Neutral‐pH electropolymerization of aniline on laser‐induced graphene (LIG) produces stable, brush‐like polyaniline coatings without requiring acidic conditions. The resulting PANI–LIG electrodes exhibit enhanced electroactive surface area, efficient charge transfer, and dual sensing capability for β‐blockers and pH, providing a scalable platform ...
Angelika Łepek, Aiswarya Manohar, Mattia Pierpaoli, Robert Bogdanowicz, Łukasz Gaweł, Mohsen Khodadadi Yazdi, Jacek Ryl   +6 more
wiley   +1 more source

Chiral Potassium Brønsted Base‐Catalyzed Stereoselective Synthesis of 1,3‐Diols via a Tandem Allylic Isomerization/Asymmetric Aldol–Tishchenko Reaction

Advanced Synthesis &Catalysis, EarlyView.
Chiral potassium base catalysts featuring 1,1´‐bi‐2‐naphthol‐derived chiral crown ethers as ligands promote a tandem allylic isomerization/asymmetric aldol‐Tishchenko reaction of allylic alcohols and aldehydes. This method provides enantioenriched 1,3‐diols with excellent diastereoselectivity and high enantioselectivity, thereby expanding the synthetic
Hiroki Ishikawa, Masahiro Sai
wiley   +1 more source

Sterol 3β-glucosyltransferase biocatalysts with a range of selectivities, including selectivity for testosterone [PDF]

, 2013
The main objectives of this work were to characterise a range of purified recombinant sterol 3β-glucosyltransferases and show that rational sampling of the diversity that exists within sterol 3β-glucosyltransferase sequence space can result in a range of
Altschul, Anthony Flinn, Bellu, Bonsor, Cantarel, Coutinho, Doerks, Gary W. Black, Grille, Hansen, Hashimoto, Julian S. Northen, Justin J. Perry, Laemmli, Lemmon, Li, Lynn G. Dover, Madina, Madina, Meng Zhang, O'Reilly, Oku, Palcic, Poppenberger, Rabbani, Robertson, Vatsala Malik, Warnecke, Weijers, Yang, Zea   +30 more
core   +1 more source

Gαi1/3 Is a Novel Regulatory Target for RANKL Signal Transduction and Osteoporosis

Advanced Science, EarlyView.
ABSTRACT Osteoporosis, characterized by progressive bone loss and increased fracture risk, is a growing concern as the population ages. Current treatments, though advanced, remain limited, underscoring the necessity for novel therapeutic targets. Recent studies have shown that the immune system plays a key role in osteoporosis, with osteoclasts driving
Chaowen Bai, Mingchao Zhang, Le Liu, Lide Tao, Chenyang Xu, Hao Chai, Xin Shi, Yin Wang, Xiaopei Zhang, Qiong Chen, Dong Liu, Jinyu Bai, Chang She, Xiaozhong Zhou, Cong Cao, Huajian Shan   +15 more
wiley   +1 more source

Equilibrium Adsorption of Single Component and Binary Mixtures of Aromatic Compounds onto a Polyfunctional Hypercrosslinked Polymeric Adsorbent

Adsorption Science & Technology, 2004
A polyfunctional hypercrosslinked polymeric adsorbent, LA-8, was synthesized and characterized. It was first used to investigate the adsorption properties of 1-amino-2-naphthol-4-sulphonic acid (1,2,4-acid), including the corresponding adsorption ...
Liu Fuqiang, Chen Jinlong, Li Aimin, Fei Zhenghao, Ge Junjie, Zhang Quanxing   +5 more
doaj   +1 more source

Determination of association constants between 5 '-guanosine monophosphate gel and aromatic compounds by capillary electrophoresis [PDF]

, 2013
Hydro gel formed by 5'-guanosine monophosphate (GMP) in the presence of a potassium ion is expected to exhibit interesting selectivity in capillary electrophoretic separations.
Alberty, Barker, Case, Chen, Chinai, Cohen, Cohen, Cohen, Davis, Dobashi, Dong, Dong, Dowling, Gozel, Heiger, Hjertén, Honda, Jorgenson, Kaori Yamaguchi, Khaledi, Kuhn, Kuhn, Mikkers, Muijselaar, Nobuyuki Takeyasu, Rundlett, Sepulveda, Smith, Takashi Kaneta, Terabe, Ueda, Widhalm, Šponer   +32 more
core   +1 more source

An All‐in‐One Lignin‐Based Artificial Thylakoid Nanovesicle Via In‐Situ Confined Growth Strategy for High‐Efficient and Selectivity CO2 Photoreduction

Carbon Energy, EarlyView.
The low light/CO2 capture and slow dynamic transfer of photogenerated electrons hamper photocatalysts’ high activity and selectivity. Inspired by the chloroplast's photosynthesis mechanism, an all‐in‐one lignin‐based artificial thylakoid nanovesicle (AiO‐L‐ATN) is constructed using a confined growth strategy of lignin molecules. The performance of such
Hang Wang, Ganmao Su, Xianxian Lin, Yan Qing, Yiqiang Wu, Fuxiang Chu, Fuquan Xiong   +6 more
wiley   +1 more source