Results 11 to 20 of about 1,728 (205)

Rhodium(III)-Catalyzed [4+2] Annulation via C-H Activation: Synthesis of Multi-Substituted Naphthalenone Sulfoxonium Ylides

open access: yesMolecules, 2019
A convenient Rh(III)-catalyzed C-H activation and cascade [4+2] annulation for the synthesis of naphthalenone sulfoxonium ylides has been developed. This method features perfect regioselectivity, mild and redox-neutral reaction conditions, and broad ...
Xiaohan Song   +4 more
doaj   +1 more source

Metal-free oxidative cross-coupling enabled practical synthesis of atropisomeric QUINOL and its derivatives

open access: yesNature Communications, 2021
1-(Isoquinolin-1-yl)naphthalen-2-ol (QUINOL) is an atropisomeric heterobiaryl that serves as a platform for the synthesis of other biaryl ligands useful in asymmetric catalysis. Here, the authors report a straightforward oxidative cross-coupling reaction
Peng-Ying Jiang   +4 more
doaj   +1 more source

Salicylic Acid-catalyzed Three-component Synthesis of 1-Amido/thioamidoalkyl-2-naphthols Under Solvent-free Conditions

open access: yesOrbital: The Electronic Journal of Chemistry, 2019
A simple, efficient, and green procedure for the solvent-free synthesis of 1-amido/thioamidoalkyl-2-naphthols by one-pot stirring of starting reactants at 100 °C has been introduced.
Hassan Darbandi, Hamzeh Kiyani
doaj   +3 more sources

THE BETA-NAPHTHOL VS. HYDRO-NAPHTHOL CONTENTION. [PDF]

open access: yesJAMA: The Journal of the American Medical Association, 1889
"Who shall decide when doctors disagree?" says the poet, with as close accordance with a general truth as reason and poetry require. Yet we shall always find, even in the case of the disagreement of doctors, criteria by which rational decision may be reached. In the first place, the opinions of individual doctors, as well as of persons not doctors, are
openaire   +1 more source

Carboxylation of hydroxyarens with metal alkyl carbonates

open access: yesGreen Processing and Synthesis, 2015
The objective of this work was to investigate the possibility of using alkali metal salts of ethylcarbonic acid as a carboxylating reagent in phenol (naphthols) carboxylation and developing a new and simple method for the synthesis of hydroxybenzoic and ...
Suerbaev Khakim A.   +2 more
doaj   +1 more source

Selenium-Mediated Synthesis of Tetrasubstituted Naphthalenes through Rearrangement

open access: yesMolecules, 2015
New β-keto ester substituted stilbene derivatives have been synthesized and cyclized with selenium electrophiles in the presence of Lewis acids. This now allows access to 1,2,3,4-tetrasubstituted naphthalene derivatives as cyclization and rearrangement ...
James Tancock, Thomas Wirth
doaj   +1 more source

Light‐Controlled Modulation of 15‐Lipoxygenase‐1 Regulates Intestinal Inflammatory Signaling

open access: yesAngewandte Chemie, EarlyView.
The developed target‐guided strategy enables the rational design of diazo‐based photoswitchable inhibitors of 15‐lipoxygenase‐1. Distinct molecular architectures program opposite light‐dependent activity, allowing on‐demand control of enzyme inhibition.
Anastasia Louka   +10 more
wiley   +2 more sources

Development of Bifunctional Chiral Thioureas and Thiosquaramides in the Synthesis of Betti Bases

open access: yesMolecules, 2023
Bifunctional thioureas and, for the first time, bifunctional thiosquaramides as organocatalysts were used in the asymmetric Betti reaction involving 1-, 2-naphthols and hydroxyquinoline with N-tosylimine and ketimine.
Martyna Malinowska, Anna Zawisza
doaj   +1 more source

Naphthol Preparations in Disinfection [PDF]

open access: yesthe american journal of the medical sciences, 1906
n ...
openaire   +1 more source

Flavin Catalysts in Organic Synthesis

open access: yesAngewandte Chemie, EarlyView.
Flavins and their congeners are potent catalysts for organic synthesis inspired by enzymatic transformations. In addition to catalysis in the flavin ground state via covalent intermediates, the excited singlet and triplet states unlock applications including photooxidation, photoreduction, and energy transfer via sensitization.
Jan Freudenberg, Golo Storch
wiley   +2 more sources

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