Cobalt‐Catalyzed C─N Bond Formation via Metal‐Hydride Hydrogen Atom Transfer (MHAT)
Cobalt‐catalyzed metal‐hydride hydrogen atom transfer (Co‐MHAT) converts simple alkenes into C─N bonds under mild, near‐neutral conditions. A shared Co─H‐initiated radical/organocobalt intermediate is channeled into radical trapping, radical‐polar crossover, or radical ligand transfer, unifying hydroamination, hydroazidation, hydroamidation, and remote
Arman Khosravi, Ming‐Yu Ngai
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Depositional Environment and Diagenetic History of Gas Hydrate-Bearing Sediments of the Alaska North Slope (HYDRATE 02 Geo Data Well). [PDF]
Phillips SC +9 more
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Accelerating Phosphate Transport Across Membranes via Synergistic Chemical‐Electrochemical Carriers
A new membrane design principle based on synergistic chemical and electrochemical carriers is proposed to construct an electro‐driven carrier‐conducting membrane for high‐throughput phosphate transport. Monodispersed ferrihydrite nanoparticles embedded within the membrane act as built‐in phosphate carriers, enabling accelerated phosphate migration via ...
Lei Xia +9 more
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Novel Polymer-Based Smart Hydrogels: Design, Properties and Applications. [PDF]
Ma N, Zhan XQ, Tsai FC.
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Atmospheric water harvesting (AWH) under arid conditions requires desiccants that load water below 30% RH and regenerate below 60°C, a performance regime traditionally limited to physisorbents. Here, we show that the inherent hydrolytic instability of M′FSIX‐25‐M coordination networks enable regeneration‐optimized chemisorbents (ROCs) with projected ...
Xiang‐Jing Kong +15 more
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Synergistic Modification of Static Chemical Agent with Fly Ash and Hemihydrate Gypsum for Mechanically Compatible Gas Drainage Borehole Sealing. [PDF]
Tang W +6 more
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Coarse‐grained (CG) molecular dynamics simulations were used to predict the upper critical solution temperature of copolymers obtained by radical ring‐opening copolymerization of cyclic ketene acetals and vinyl monomers, and to account for their unique degradation kinetics under physiological conditions by evaluating the solvation of their ester groups.
Ping Gao +3 more
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Experimental Study on Mechanical Properties and the Hydration Mechanism of Fly Ash-Doped High-Water Filling Materials. [PDF]
Sun Y +7 more
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Supramolecular 1‐D, 2‐D, and 3‐D networks comprised of ‐(‐O═Xe(O2)‐‐)‐∞ and ‐(‐Xe(O2)O‐‐‐HO(H)‐‐)‐∞ chains coordinated to polytopic N‐base ligands were synthesized and structurally characterized by X‐ray crystallography. Their Xe‐‐‐N and Xe‐‐‐O bonds are characteristic of σ–hole bonds in which the nucleophilic Lewis base sites of the N‐ligands, H2O ...
James T. Goettel +2 more
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Agglomerations of Methane Hydrate Particles in Aqueous Solutions: Insight from Dissipative Particle Dynamics Simulations. [PDF]
Wang M, Cao P.
europepmc +1 more source

