Results 131 to 140 of about 16,319 (283)

Kinetically Stable Boron‐Heteroatom Bonds

Angewandte Chemie, Volume 138, Issue 38, 14 September 2026.
This study investigates the kinetic stability of boron‐heteroatom bonds in N‐methyliminodiacetic acid (MIDA) boronates. The hemilabile nature of the ligand enables the synthesis of molecules that would otherwise be considered too hydrolytically labile. Depending on the structure, acid‐promoted migration of the boryl group was found to produce compounds
Alina Trofimova, Ben Zhen Huang, Harjeet S. Soor, Brandon White, Aleksandra Holownia, Yury Lebedev, Alan J. Lough, Travis Dudding, Andrei K. Yudin   +8 more
wiley   +2 more sources

Selective growth of NbO whisker.

Journal of the Ceramic Association, Japan, 1975
MOTOJIMA, Seiji, TAKAHASHI, Yasutaka, SUGIYAMA, Kozoh   +2 more
openaire   +2 more sources

Domain‐Knowledge‑Guided Rule Extraction for Governing Nepheline Amount in High‑Level Waste Glasses

International Journal of Applied Glass Science, Volume 17, Issue 4, October 2026.
ABSTRACT Nepheline crystallization during canister centerline cooling is one of the most constraining factors limiting waste loading in high‐level waste (HLW) borosilicate glasses. Existing predictive models treat nepheline formation as a binary outcome, yet durability degradation depends continuously on nepheline fraction.
Irmak Sargin
wiley   +1 more source

T‐Shaped Stibenium(III) Cation: Hydrostibination Without Sb─H Bond

Angewandte Chemie, Volume 138, Issue 38, 14 September 2026.
A cationic, structurally constrained stibenium platform mediates anti‐Markovnikov hydrostibination of alkenes via element–ligand cooperativity (ELC), thereby bypassing the need for weak Sb─H bonds. ABSTRACT The hydrostibination of alkenes represents a largely underdeveloped transformation, owing to the intrinsic lability of the required Sb─H reagents ...
Ekta Nag, Lars Ole Busse, Andreas Albers, Manuel Schmitt, Lutz Greb   +4 more
wiley   +2 more sources

Normobaric Oxygen Therapy for Scleral Ischemia or Melt

Journal of Ophthalmic & Vision Research, 2012
Purpose: To investigate the efficacy of normobaric oxygen (NBO) therapy for treatment of scleral ischemia or melt. Methods: This prospective interventional case series includes 9 eyes of 8 patients with scleral ischemia or melt of diverse etiologies ...
Farideh Sharifipour, Mahmoodreza Panahi-Bazaz, Esmaeil Idani, Mohammad Malekahmadi, Sepehr Feizi   +4 more
doaj  

Unveiling Float Glass Staining Induced by an Acid‐Cleaning Product

International Journal of Applied Glass Science, Volume 17, Issue 4, October 2026.
ABSTRACT Staining of glass facades is a recurring and significant problem worldwide. This study investigates the causes of staining observed on six laminated float glass samples from four manufacturers (α, β, γ, and δ). Samples from β, γ, and δ were new, whereas those from α (α1, α2, and α3) were taken from a building after service exposure.
Ricardo F. Lancelotti, Débora C. N. Fabris, Rafael B. Oliveira, Marcelo A. C. Kurtovic, Laís D. Silva, Guilherme S. Macena, Eduardo B. Ferreira, Valmor R. Mastelaro, Edgar D. Zanotto   +8 more
wiley   +1 more source

Optical Basicity of Glasses: Review and Application in Nuclear Glass Formulation

International Journal of Applied Glass Science, Volume 17, Issue 4, October 2026.
A self‐consistent set of optical basicity (OB) values was compiled and evaluated for 95 binary oxides using electronegativity, ionic–covalent, and optical‐property approaches, providing a robust basis for estimating the basicity of complex compounds and glasses.
John McCloy, John Bussey, Wyatt Kiff
wiley   +1 more source

Machine Learning Enabled Prediction and Interpretation of the Initial Dissolution Rates of Nuclear Waste Glasses

International Journal of Applied Glass Science, Volume 17, Issue 4, October 2026.
ABSTRACT Accurate prediction of chemical durability, such as dissolution rate, is crucial for glass materials used in diverse applications, including pharmaceutical packaging and nuclear waste disposal. In this work, machine learning‐based prediction models were developed using structural descriptors derived from molecular dynamics (MD) simulations and
Wenqing Xie, Jayani Kalahe, Kenneth Sanders, Manzila Islam Tuheen, Benjamin Parruzot, Joelle T. Reiser, Stéphane Gin, James J. Neeway, Nicholas A. Lumetta, John D. Vienna, Jincheng Du, Xiaonan Lu   +11 more
wiley   +1 more source

Breaking the Ceiling of Boron‐Boron Bonds: Understanding and Fine‐Tuning Basicity in Diborane(4) Complexes

Journal of Computational Chemistry, Volume 47, Issue 24, September 15, 2026.
Diborane(4) can form strong complexes with one or two nitrogen bases, and still behave as a boron base. Complexed with two nitrogen bases, diborane(4) may reach very high proton affinities, overcoming that of the typical 1,8‐bis(dimethylamino)naphthalene super sponge. However, understanding basicity trends is not straightforward, due to the loss of the
Manuel Yáñez, Otilia Mó, M. Merced Montero‐Campillo, Ibon Alkorta   +3 more
wiley   +1 more source

Substituent‐Driven Modulation of Electronic Properties in Acrylonitrile Derivatives: A Combined Study on NLO Response and DNA‐Binding Affinity via ECT Analysis

International Journal of Quantum Chemistry, Volume 126, Issue 18, September 15, 2026.
Theoretical (DFT) and experimental investigations elucidate the structural, electronic, and optical properties of a newly synthesized fluorinated organic semiconductor. The optimized frontier orbital alignment and robust molecular architecture demonstrate its suitability for advanced optoelectronic applications.
Furkan Özen, Bayram Gündüz, Günseli Turgut Cin, Leyla Babali Özen, Öner Ekici   +4 more
wiley   +1 more source